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CRC Press eBooks

Rotations and Tensor Operators

Gordon Baym

Published Mar 5, 2018• 0 citations
Publisher

Abstract

The addition theorem for spherical harmonics is just a special case of the law for the transformation of spherical harmonics under rotation of their arguments. Certain operators are scalars under rotation; this means that they commute with the total angular momentum and are unchanged by the transformation. The types of operators having simple transformation properties under rotation are known generally as tensor operators. The energy eigenstates of an atom, taking into account the spin-orbit interaction, are not usually eigenstates of the z component of the total orbital angular momentum, but are eigenstates of the total angular momentum, spin plus orbital. Sehwinger has looked at the theory of angular momentum from a point of view that enables one to carry out very elegant calculations of the various quantities occurring in the theory of angular momentum. The quanta of some different oscillators are simply the quarks that compose the strongly interacting particles.

DOI
10.1201/9780429499265-17

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As in classical mechanics, rotation in quantum mechanics is a transformation which deals with angular momentum. The difference with classical mechanics comes from the fact that angular momentum is a vector operator and not a usual vector and its components do not commute. As for any transformation in quantum mechanics, to each rotation we can associate an operator which acts in state space. The expression of this operator depends on whether the rotation is passive, that is we do a rotation of the coordinate axes and the physical system is left unchanged, or active, in which case the coordinate axes are unchanged and the rotation is performed on the physical system. In the first part (Chaps. 1 and 2) of this book, details concerning both aspects are given. Following the definition of the geometrical transformation associated with the most general rotation, we give the expression of the rotation operator for specific cases. Transformation laws for scalar fields, vector fields and spinor fields are given as well as transformation laws for scalar operators, vector operators and more generally, for operators of any rank. The second part (Chaps. 3 and 4) deals with angular momentum algebra. We define the coupling coefficients of 2, 3 and 4 angular momenta as well as the recoupling coefficients. The definition of the irreductible tensor operator, which is a generalisation of scalar and vector operators, is given as well as the Wigner-Eckart theorem. The application of this theorem to more complex cases is studied.

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The addition theorem for spherical harmonics is just a special case of the law for the transformation of spherical harmonics under rotation of their arguments. Certain operators are scalars under rotation; this means that they commute with the total angular momentum and are unchanged by the transformation. The types of operators having simple transformation properties under rotation are known generally as tensor operators. The energy eigenstates of an atom, taking into account the spin-orbit interaction, are not usually eigenstates of the z component of the total orbital angular momentum, but are eigenstates of the total angular momentum, spin plus orbital. Sehwinger has looked at the theory of angular momentum from a point of view that enables one to carry out very elegant calculations of the various quantities occurring in the theory of angular momentum. The quanta of some different oscillators are simply the quarks that compose the strongly interacting particles.
As in classical mechanics, rotation in quantum mechanics is a transformation which deals with angular momentum. The difference with classical mechanics comes from the fact that angular momentum is a vector operator and not a usual vector and its components do not commute. As for any transformation in quantum mechanics, to each rotation we can associate an operator which acts in state space. The expression of this operator depends on whether the rotation is passive, that is we do a rotation of the coordinate axes and the physical system is left unchanged, or active, in which case the coordinate axes are unchanged and the rotation is performed on the physical system. In the first part (Chaps. 1 and 2) of this book, details concerning both aspects are given. Following the definition of the geometrical transformation associated with the most general rotation, we give the expression of the rotation operator for specific cases. Transformation laws for scalar fields, vector fields and spinor fields are given as well as transformation laws for scalar operators, vector operators and more generally, for operators of any rank. The second part (Chaps. 3 and 4) deals with angular momentum algebra. We define the coupling coefficients of 2, 3 and 4 angular momenta as well as the recoupling coefficients. The definition of the irreductible tensor operator, which is a generalisation of scalar and vector operators, is given as well as the Wigner-Eckart theorem. The application of this theorem to more complex cases is studied.
Angular momentum theory provides a mathematical foundation for the rotation of the eigenvectors of the angular momentum operator, the spherical harmonics functions. A useful property of spherical harmonics is that their rotation in 3D space corresponds to rotation in the virtual space of their azimuthal degrees of freedom. In addition to that, spherical harmonics functions that have different orbital indices do not mix. Given that spherical harmonics functions have known rotation properties, and that any arbitrary function can be expanded in a series of spherical harmonics, this property allows the rotation of an electrostatic potential when it is expanded in the series of spherical harmonics. In this chapter, the exponential form of the rotation operator, the rotation matrix for a 3D rotation of the coordinate system, and the principles of rotation of vectors and functions are described. The chapter provides a detailed self-contained introduction to the theory of angular momentum, derives the commutative properties of the angular momentum operator, and explains shift operators, while minimizing references to quantum mechanics and entirely avoiding group theory.
Abstract This chapter presents orbital angular momentum as the generator or rotations in space. The operators which carry out rotations in space form a group, which is a symmetry group of the Hamiltonian when the interaction is spherically symmetric. In such a case, there are certain useful statements which we can make about the role of invariant and irreducible subspaces of the Hilbert space under the group operations and how to calculate matrix elements of tensor operators within such spaces, that is, the Wigner-Eckart theorem.
This chapter shows that the three operators are Hermitian and (in a rotationally invariant system) commute with the Hamiltonian; therefore they are observable constants of the motion. It finds out what their physical significance is. By knowing from classical mechanics, the constant of the motion arising from rotational invariance is the angular momentum. The angular momentum may split up into two parts: orbital and intrinsic. The orbital part can always be described by the dependence of a wave function, whereas the intrinsic part is by definition contained in the transformation property of the wave function. In the case of a single component (scalar), no intrinsic angular momentum exists. There are—apart from the vector addition and the scalar product—two other ways of combining two vectors: the direct sum and the direct product. Both occur in the theory of angular momentum, in fact whenever symmetry is involved.
Abstract In this chapter we introduce the concept of orbital angular momentum into the mathematical language of quantum mechanics. We discuss the commutation relations of the corresponding operators and their roles as generators of rotations in the context of the theory of Lie groups and Lie algebras, focusing on the three-dimensional rotation group SO(3). We further examine how scalar and vector-valued operators transform under spatial rotations. We then turn to the derivation of the eigenfunctions and eigenvalues of the angular-momentum operators, for which we follow a dual approach in analogy to that employed for the harmonic oscillator in Chapter 5. Using both the algebraic ladder-operator method and an analytical method using spherical polar coordinates we discover the relevant azimuthal and magnetic quantum numbers and their relation to the spherical harmonics and the Legendre polynomials
We develop a systematic approach to deriving addition theorems for, and some other bilocal sums of, spin spherical harmonics. In this first part we establish some necessary technical results. We discuss the factorization of orbital and spin degrees of freedom in certain products of Clebsch-Gordan coefficients, and obtain general explicit results for the matrix elements in configuration space of tensor products of arbitrary rank of the position and angular-momentum operators. These results are the basis of the addition theorems for spin spherical harmonics obtained in part II.