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Modèles de Hubbard unidimensionels généralisés

Victor Fomin

Published Sep 20, 2010• 0 citations
OpenAlex

Abstract

This thesis is devoted to the one-dimensional integrable Hubbard model and its generalizations. The Hubbard model is one of the fundamental models in condensed matter physics which describes interacting electrons on the lattice. It has very rich physical structure. Inspite of its construction simplicity it has been applied to diverse problems as high-Tc superconductivity, band magnetism and the metal-insulator transition. In one dimension the Hubbard model is an integrable model which has been intensively studied and served as a theoretical laboratory for the condensed matter physics. Recently, the integrable systems and in particular the Hubbard model, have surprisingly appeared in the AdS/CFT correspondence context. The intersection point between the fields is the Bethe equations: the ones of new integrable models and the generalizations of existing ones are relevant in the application in AdS/CFT duality. In the first part of the thesis, we present basis notions of the quantum integrability: the R-matrix formalism, the Yang-Baxter equation, integrable spin chains etc. In the second part we review several fundamental results of the one-dimensional Hubbard model: the Coordinate Bethe Ansatz solution, real solutions of the Lieb-Wu equations etc. Moreover, applications in the AdS/CFT duality are considered. However, it turns out that certain modifications of the integrable Hubbard model are necessary to reproduce the correct results of the AdS/CFT context. This is one of the main motivations of the studies of generalized Hubbard models. The fourth chapter is devoted to generalizations of the Hubbard model and we focus our attention on supersymmetric ones. The fifth chapter con- tains the results obtained in the framework of this thesis on the supersymmetric generalizations of the Hubbard models. Namely, the Coordinate Bethe Ansatz solution and real solutions of the Bethe equations in the thermodynamic limit are exposed. We point out that the obtained Bethe equations differs from the Lieb-Wu ones by phases which appearance is encouraging sign for the application in the AdS/CFT context. We also discuss possible applications in the AdS/CFT duality and in con- densed matter physics.

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Exact Results on Extended Hubbard Models on One-Dimensional Chains

Fabrizio Dolcini

This PhD thesis is concerned with the investigation of Extended Hubbard Models on one-dimensional lattices (chains); the approach used to such investigation is that of determining exact results. The extended Hubbard models are models of correlated electrons on lattices; they are the extensions of a model proposed by Hubbard in \\cite{HUB} to explain the metal-insulator transition in $d$-transition compounds as the effect of electronic correlations, usually neglected in band theories. Later on, a need for extensions of such model was first felt within the context of high-temperature superconductivity; indeed, the different behaviour of doped cuprates with respect to conventional superconductors suggested that a microscopic theory of this phenomenon could be formulated in terms of electron-electron interaction, without explicitly invoking the phonon coupling, like in BCS theory. Although an exhaustive microscopic formulation for cuprate superconductivity has not been achieved yet, the Extended Hubbard Models have been in the meanwhile applied to other problems in condensed matter; they are actually considered the reference paradigm for treating all those systems in which electronic correlations cannot be neglected. \\\\As observed above, this thesis focuses in particular on 1-D chains: indeed in last years the progress in technological synthesization and small-scale observations has shown that there are many classes of materials exhibiting a strong one-dimensional character, such as organic (super)conductors, linear-chain polymers, quantum wires, quantum-dot chains, one-dimensional cuprates. Many experimental results confirm that such materials exhibit a quite rich behaviour, with different phases, charge-spin separation, as well as a strong electronic correlations. However, a sufficient understanding of these phenomena on a theoretical point of view has not been reached yet. This is due to the fact the usual theoretical methods can be shown to fail in D=1, and theoreticians are thus forced to develop new schemes for approaching the problem of many interacting fermions in such dimension. The latter therefore represents a fascinating challenge. Some progress has been made and many aspects are nowadays more clear; nevertheless, due to the lack of traditional techniques, the need for a comparison with exact results is perhaps more urgent in D=1 than in higher dimensions. The aim of this thesis is to provide some results to the research in this field. The present work is organized as follows: the two first chapters are introductory, while chapters 3 and 4 mostly contain the author's original contribution. More explicitly, {\\bf chapter 1} is an introduction to the Hubbard models (both the ordinary and the Extended) and is meant for the reader who is non-familiar with these models. We tried to emphasize the motivation that historically led to their introduction and the physical contexts in which they are applied, not necessarily in one-dimension. \\\\{\\bf Chapter 2} is instead devoted to general problematics of one dimensional physics. We have tried to stress that there is a number of physically interesting materials that can be regarded as actual 1-D systems; we give a brief account of the difficulties leading the usual theoretical approaches, such as mean-field and Fermi Liquid, to fail in D=1. While briefly describing the important results of the proposed alternative formulations (Luttinger Liquid, Renormalization Group), we also point out the points that are still unsatisfactory, and emphasize the importance that exactly integrable models have in this field. \\\\Matching the subjects of chapter 1 and 2, the subsequent ones contain the results of our investigation of exactly solvable Extended Hubbard model on 1-D chains. \\\\We wish to emphasize to the reader non familiar with integrable systems that the literature on this subject is often strongly concerned with the mathematical aspects of the involved methods, leaving the determination of the physical features of the derived integrable models as a secondary issue. On the contrary, we believe that both aspects of the research deserve a relevant role in the study. For these reasons, while chapter 3 contains new results about the general formulation of integrability for fermionic systems, chapter 4 is devoted to the investigation of the physical features for some models whose integrability has been proved in the previous chapter. \\\\More explicitly, in {\\bf chapter 3} (apart from a preliminary introduction of sec.3.1) the theory of integrable {\\it fermionic} systems has been developed within the frame of the Quantum Inverse Scattering Method (QISM). The latter is a technique for obtaining integrable models, traditionally formulated with success for spin systems; its more recent application to electron systems was leaving many unsatisfactory aspects. To overcome this weaknesses, in sec.3.2 we both clarify the theory of matrix representation for fermionic operators, and describe a method for obtaining integrable models of fermions (straightforwardly readable in terms of fermion operators), starting from the the solutions of a $\\mathbb{C}$-number equation (known as Yang-Baxter Equation). In sec.3.3 we first work out a general method of search for solutions of such equation; secondly we explicitly find 96 solutions, corresponding to 96 integrable Extended Hubbard models (most of which are new) for which a set of mutually commuting operators is proved to exist. In sec.3.4 we formulate a general theorem concerning the symmetries of the integrable models in QISM, and widely discuss the symmetries and supersymmetries for the class of extended Hubbard Models.\\\\ {\\bf Chapter 4} is devoted to the investigation of the physical properties of the integrable Extended Hubbard models found in chapter 3. We introduce a technique, called Sutherland's species technique, that, when applicable, yields an effective reduction of the Hilbert space and considerably simplifies the problem of diagonalizing the Hamiltonian. In fact, such technique is proved to be applicable to all the 96 models found above, and is used to determine the exact ground state phase diagram and the thermodynamics of the models. In particular we both recover in a quite straightforward way the phase diagram of a known model, and that of two new models (Model 2 and Model 3) that were not known before. \\\\The phase diagram exhibit structured forms with respect to the filling (density of electrons) and the on-site Coulomb repulsion ($U$); the pressure and the compressibility in the ground state are also calculated. Model 2 exhibits a superconducting phase particularly enhanced towards positive values of $U$, as well as a band-controlled insulator-superconductor transition at half filling; model 3 is the first example of exactly solved model with an asymmetric shape with respect to half-filling, due to the absence of particle-hole invariance of the Hamiltonian; a filling controlled metal-insulator transition is found to occur for this model. Generalizations to the other cases are also discussed. \\\\As to the thermodynamics, we compute the exact partition function of Model 3, which we believe to be particular worth of interest due to the above asymmetry. We then derive the exact specific heat of the model as a function of the temperature, which exhibits an interesting two-peak behaviour as well as a nearly universal crossing point. These results are discussed and compared with similar ones present in the literature. The chapters are of course linked each to another according to the above scheme; nevertheless, it has been a purpose of the author to make them as independently readable as possible. In particular, the reader who is more interested in the physical aspects of the models rather than in the general formalism of fermionic QISM can skip chapter 3 (at least in a first-sight reading) and pass directly to chapter 4; apart from some references to previous formulas the understanding should not be affected.\\\\{\\it \\noindent \\underline{Notational Remark:}} The customary symbol to denote the electron filling is $n$; this has in fact been used throughout the two first introductory chapters. Nevertheless, in order to avoid possible misunderstanding with other extensive quantities, in chapter 3~and~4~the~symbol~has been changed into $\\rho$

•Jan 1, 2001•0 citations

Including a phase in the Bethe equations of the Hubbard model

Victor Fomin, L. Frappat, E. Ragoucy

We compute the Bethe equations of generalized Hubbard models, and study their thermodynamical limit. We argue how they can be connected to the ones found in the context of AdS/CFT correspondence, in particular with the so-called dressing phase problem. We also show how the models can be interpreted, in condensed matter physics, as integrable multi-leg Hubbard models.

arXiv:1002.1806•Journal of High Energy Physics•Apr 1, 2010•3 citations

Integrability of strongly correlated electron systems on open chains

Xiangyu Ge

Integrability of strongly correlated electron systems on open chains XIANG-YU GEIn recent years, there has been a strong increase of interest in models of strongly correlated electron systems in condensed matter physics, in particular in integrable onedimensional models.Examples of such models are the one-dimensional Hubbard model, the supersymmetric t-J model, the Hubbard-like model (Bariev's chain), the so-called extended Hubbard model (EKS model), the supersymmetric U model and the eight-state supersymmetric U model.The study of integrable open-boundary conditions for strongly correlated electron models is very important for physical applications, especially for gaining insights into the behaviour of more realistic systems.The important ingredient in Sklyanin's boundary quantum inverse scattering method (QISM), which has played a key role in recent advances in the study of lattice models with open-boundaries, is a new algebraic structure, the reflection equation algebra.In this thesis, a general graded reflection equation algebra is proposed and the corresponding graded (supersymmetry) boundary QISM is formulated.The formalism is applicable to all boundary lattice systems where an invertible i?-matrix exists.As applications, some important integrable boundary conditions for various strongly correlated electron models with quantum superalgebra symmetries are constructed, including:1. Presentation of integrable open-boundary conditions for the one-dimensional qdeformed supersymmetric Essler-Korepin-Schoutens (EKS) extended Hubbard model.Determination of three different diagonal boundary if-matrices and of nine classes of integrable open-boundary conditions.Construction of the exactly solvable Hamiltonian with open-boundary terms for quantum superalgebra U q (gl(2\2)) symmetry; 2. Establishment of the quantum integrability of open-boundary conditions for the one-dimensional ^-deformed supersymmetric U model with quantum superalgebra U q (gl(2\l)} symmetry.Determination of diagonal boundary if-matrices and of integrable open-boundary conditions.Solution of the boundary system by means of the coordinate space Bethe ansatz technique, and derivation of the Bethe ansatz equations;

Bulletin of the Australian Mathematical Society•Jun 1, 2001•0 citations

Bethe equations for generalized Hubbard models

Victor Fomin, L. Frappat, E. Ragoucy

We compute the eigenfunctions, energies and Bethe equations for a class of generalized integrable Hubbard models based on gl(n|m)\\oplus gl(2) superalgebras. The Bethe equations appear to be similar to the Hubbard model ones, up to a phase due to the integration of a subset of `simple' Bethe equations. We discuss relations with AdS/CFT correspondence, and with condensed matter physics.

•Jan 1, 2009•5 citations

The Bethe ansatz solution

Fabian H. L. Eßler, Holger Frahm, Frank Göhmann +2 more

The bare existence of this book is due to the amazing fact that the solution of the stationary Schrödinger equation for the one-dimensional Hubbard model can be reduced to a set of algebraic equations, which is tractable in the thermodynamic limit. These equations will be derived in this chapter. We will call them the Lieb-Wu equations to honour E. H. Lieb and F. Y. Wu, who first obtained them [298]. The derivation is based on a method, called the nested (coordinate) Bethe ansatz, which goes back to the seminal articles of C. N. Yang [493] and M. Gaudin [154], who generalized earlier work [60, 296] on exactly solvable models to models with internal degrees of freedom. The roots of the Lieb-Wu equations parameterize the eigenvalues and the eigenstates of the Hamiltonian of the one-dimensional Hubbard model. They encode the complete information about the model. These roots are not explicitly known in the general N -particle case. In the thermodynamic limit ( N →∞), however, only the distributions of the roots in the complex plane matter, and many physical quantities can be calculated as solutions of linear or non-linear Fredholm type integral equations. Moreover, it is sometimes possible to use the Lieb-Wu equations in an implicit way even for finite N , e.g., in the proof of the SO(4) highest weight properties of the eigenstates in Sections 3.D and 3.F of the appendix or in the calculation of their norm in Section 3.5.

Cambridge University Press eBooks•Feb 7, 2005•1 citation

New integrable 1D models of superconductivity

Marius de Leeuw, Anton Pribytok, Ana L. Retore +1 more

Abstract In this paper we find new integrable one-dimensional lattice models of electrons. We describe all such nearest-neighbour integrable models with s u ( 2 ) × s u ( 2 ) symmetry by classifying solutions of the Yang–Baxter equation following the procedure first introduced in [1]. We find 12 R-matrices of difference form, some of which can be related to known models such as the XXX spin chain and the free Hubbard model, and some are new models. In addition, integrable generalizations of the Hubbard model are found by keeping the kinetic term of the Hamiltonian and adding all terms which preserve fermion number. We find that most of the new models cannot be diagonalized using the standard nested Bethe Ansatz.

arXiv:1911.01439•Journal of Physics A Mathematical and Theoretical•Jul 22, 2020•25 citations
This thesis is devoted to the one-dimensional integrable Hubbard model and its generalizations. The Hubbard model is one of the fundamental models in condensed matter physics which describes interacting electrons on the lattice. It has very rich physical structure. Inspite of its construction simplicity it has been applied to diverse problems as high-Tc superconductivity, band magnetism and the metal-insulator transition. In one dimension the Hubbard model is an integrable model which has been intensively studied and served as a theoretical laboratory for the condensed matter physics. Recently, the integrable systems and in particular the Hubbard model, have surprisingly appeared in the AdS/CFT correspondence context. The intersection point between the fields is the Bethe equations: the ones of new integrable models and the generalizations of existing ones are relevant in the application in AdS/CFT duality. In the first part of the thesis, we present basis notions of the quantum integrability: the R-matrix formalism, the Yang-Baxter equation, integrable spin chains etc. In the second part we review several fundamental results of the one-dimensional Hubbard model: the Coordinate Bethe Ansatz solution, real solutions of the Lieb-Wu equations etc. Moreover, applications in the AdS/CFT duality are considered. However, it turns out that certain modifications of the integrable Hubbard model are necessary to reproduce the correct results of the AdS/CFT context. This is one of the main motivations of the studies of generalized Hubbard models. The fourth chapter is devoted to generalizations of the Hubbard model and we focus our attention on supersymmetric ones. The fifth chapter con- tains the results obtained in the framework of this thesis on the supersymmetric generalizations of the Hubbard models. Namely, the Coordinate Bethe Ansatz solution and real solutions of the Bethe equations in the thermodynamic limit are exposed. We point out that the obtained Bethe equations differs from the Lieb-Wu ones by phases which appearance is encouraging sign for the application in the AdS/CFT context. We also discuss possible applications in the AdS/CFT duality and in con- densed matter physics.
This PhD thesis is concerned with the investigation of Extended Hubbard Models on one-dimensional lattices (chains); the approach used to such investigation is that of determining exact results. The extended Hubbard models are models of correlated electrons on lattices; they are the extensions of a model proposed by Hubbard in \\cite{HUB} to explain the metal-insulator transition in ddd-transition compounds as the effect of electronic correlations, usually neglected in band theories. Later on, a need for extensions of such model was first felt within the context of high-temperature superconductivity; indeed, the different behaviour of doped cuprates with respect to conventional superconductors suggested that a microscopic theory of this phenomenon could be formulated in terms of electron-electron interaction, without explicitly invoking the phonon coupling, like in BCS theory. Although an exhaustive microscopic formulation for cuprate superconductivity has not been achieved yet, the Extended Hubbard Models have been in the meanwhile applied to other problems in condensed matter; they are actually considered the reference paradigm for treating all those systems in which electronic correlations cannot be neglected. \\\\As observed above, this thesis focuses in particular on 1-D chains: indeed in last years the progress in technological synthesization and small-scale observations has shown that there are many classes of materials exhibiting a strong one-dimensional character, such as organic (super)conductors, linear-chain polymers, quantum wires, quantum-dot chains, one-dimensional cuprates. Many experimental results confirm that such materials exhibit a quite rich behaviour, with different phases, charge-spin separation, as well as a strong electronic correlations. However, a sufficient understanding of these phenomena on a theoretical point of view has not been reached yet. This is due to the fact the usual theoretical methods can be shown to fail in D=1, and theoreticians are thus forced to develop new schemes for approaching the problem of many interacting fermions in such dimension. The latter therefore represents a fascinating challenge. Some progress has been made and many aspects are nowadays more clear; nevertheless, due to the lack of traditional techniques, the need for a comparison with exact results is perhaps more urgent in D=1 than in higher dimensions. The aim of this thesis is to provide some results to the research in this field. The present work is organized as follows: the two first chapters are introductory, while chapters 3 and 4 mostly contain the author's original contribution. More explicitly, {\\bf chapter 1} is an introduction to the Hubbard models (both the ordinary and the Extended) and is meant for the reader who is non-familiar with these models. We tried to emphasize the motivation that historically led to their introduction and the physical contexts in which they are applied, not necessarily in one-dimension. \\\\{\\bf Chapter 2} is instead devoted to general problematics of one dimensional physics. We have tried to stress that there is a number of physically interesting materials that can be regarded as actual 1-D systems; we give a brief account of the difficulties leading the usual theoretical approaches, such as mean-field and Fermi Liquid, to fail in D=1. While briefly describing the important results of the proposed alternative formulations (Luttinger Liquid, Renormalization Group), we also point out the points that are still unsatisfactory, and emphasize the importance that exactly integrable models have in this field. \\\\Matching the subjects of chapter 1 and 2, the subsequent ones contain the results of our investigation of exactly solvable Extended Hubbard model on 1-D chains. \\\\We wish to emphasize to the reader non familiar with integrable systems that the literature on this subject is often strongly concerned with the mathematical aspects of the involved methods, leaving the determination of the physical features of the derived integrable models as a secondary issue. On the contrary, we believe that both aspects of the research deserve a relevant role in the study. For these reasons, while chapter 3 contains new results about the general formulation of integrability for fermionic systems, chapter 4 is devoted to the investigation of the physical features for some models whose integrability has been proved in the previous chapter. \\\\More explicitly, in {\\bf chapter 3} (apart from a preliminary introduction of sec.3.1) the theory of integrable {\\it fermionic} systems has been developed within the frame of the Quantum Inverse Scattering Method (QISM). The latter is a technique for obtaining integrable models, traditionally formulated with success for spin systems; its more recent application to electron systems was leaving many unsatisfactory aspects. To overcome this weaknesses, in sec.3.2 we both clarify the theory of matrix representation for fermionic operators, and describe a method for obtaining integrable models of fermions (straightforwardly readable in terms of fermion operators), starting from the the solutions of a mathbbC\\mathbb{C}mathbbC-number equation (known as Yang-Baxter Equation). In sec.3.3 we first work out a general method of search for solutions of such equation; secondly we explicitly find 96 solutions, corresponding to 96 integrable Extended Hubbard models (most of which are new) for which a set of mutually commuting operators is proved to exist. In sec.3.4 we formulate a general theorem concerning the symmetries of the integrable models in QISM, and widely discuss the symmetries and supersymmetries for the class of extended Hubbard Models.\\\\ {\\bf Chapter 4} is devoted to the investigation of the physical properties of the integrable Extended Hubbard models found in chapter 3. We introduce a technique, called Sutherland's species technique, that, when applicable, yields an effective reduction of the Hilbert space and considerably simplifies the problem of diagonalizing the Hamiltonian. In fact, such technique is proved to be applicable to all the 96 models found above, and is used to determine the exact ground state phase diagram and the thermodynamics of the models. In particular we both recover in a quite straightforward way the phase diagram of a known model, and that of two new models (Model 2 and Model 3) that were not known before. \\\\The phase diagram exhibit structured forms with respect to the filling (density of electrons) and the on-site Coulomb repulsion (UUU); the pressure and the compressibility in the ground state are also calculated. Model 2 exhibits a superconducting phase particularly enhanced towards positive values of UUU, as well as a band-controlled insulator-superconductor transition at half filling; model 3 is the first example of exactly solved model with an asymmetric shape with respect to half-filling, due to the absence of particle-hole invariance of the Hamiltonian; a filling controlled metal-insulator transition is found to occur for this model. Generalizations to the other cases are also discussed. \\\\As to the thermodynamics, we compute the exact partition function of Model 3, which we believe to be particular worth of interest due to the above asymmetry. We then derive the exact specific heat of the model as a function of the temperature, which exhibits an interesting two-peak behaviour as well as a nearly universal crossing point. These results are discussed and compared with similar ones present in the literature. The chapters are of course linked each to another according to the above scheme; nevertheless, it has been a purpose of the author to make them as independently readable as possible. In particular, the reader who is more interested in the physical aspects of the models rather than in the general formalism of fermionic QISM can skip chapter 3 (at least in a first-sight reading) and pass directly to chapter 4; apart from some references to previous formulas the understanding should not be affected.\\\\{\\it \\noindent \\underline{Notational Remark:}} The customary symbol to denote the electron filling is nnn; this has in fact been used throughout the two first introductory chapters. Nevertheless, in order to avoid possible misunderstanding with other extensive quantities, in chapter 3~and~4~the~symbol~has been changed into rho\\rhorho
Integrability of strongly correlated electron systems on open chains XIANG-YU GEIn recent years, there has been a strong increase of interest in models of strongly correlated electron systems in condensed matter physics, in particular in integrable onedimensional models.Examples of such models are the one-dimensional Hubbard model, the supersymmetric t-J model, the Hubbard-like model (Bariev's chain), the so-called extended Hubbard model (EKS model), the supersymmetric U model and the eight-state supersymmetric U model.The study of integrable open-boundary conditions for strongly correlated electron models is very important for physical applications, especially for gaining insights into the behaviour of more realistic systems.The important ingredient in Sklyanin's boundary quantum inverse scattering method (QISM), which has played a key role in recent advances in the study of lattice models with open-boundaries, is a new algebraic structure, the reflection equation algebra.In this thesis, a general graded reflection equation algebra is proposed and the corresponding graded (supersymmetry) boundary QISM is formulated.The formalism is applicable to all boundary lattice systems where an invertible i?-matrix exists.As applications, some important integrable boundary conditions for various strongly correlated electron models with quantum superalgebra symmetries are constructed, including:1. Presentation of integrable open-boundary conditions for the one-dimensional qdeformed supersymmetric Essler-Korepin-Schoutens (EKS) extended Hubbard model.Determination of three different diagonal boundary if-matrices and of nine classes of integrable open-boundary conditions.Construction of the exactly solvable Hamiltonian with open-boundary terms for quantum superalgebra U q (gl(2\2)) symmetry; 2. Establishment of the quantum integrability of open-boundary conditions for the one-dimensional ^-deformed supersymmetric U model with quantum superalgebra U q (gl(2\l)} symmetry.Determination of diagonal boundary if-matrices and of integrable open-boundary conditions.Solution of the boundary system by means of the coordinate space Bethe ansatz technique, and derivation of the Bethe ansatz equations;
The bare existence of this book is due to the amazing fact that the solution of the stationary Schrödinger equation for the one-dimensional Hubbard model can be reduced to a set of algebraic equations, which is tractable in the thermodynamic limit. These equations will be derived in this chapter. We will call them the Lieb-Wu equations to honour E. H. Lieb and F. Y. Wu, who first obtained them [298]. The derivation is based on a method, called the nested (coordinate) Bethe ansatz, which goes back to the seminal articles of C. N. Yang [493] and M. Gaudin [154], who generalized earlier work [60, 296] on exactly solvable models to models with internal degrees of freedom. The roots of the Lieb-Wu equations parameterize the eigenvalues and the eigenstates of the Hamiltonian of the one-dimensional Hubbard model. They encode the complete information about the model. These roots are not explicitly known in the general N -particle case. In the thermodynamic limit ( N →∞), however, only the distributions of the roots in the complex plane matter, and many physical quantities can be calculated as solutions of linear or non-linear Fredholm type integral equations. Moreover, it is sometimes possible to use the Lieb-Wu equations in an implicit way even for finite N , e.g., in the proof of the SO(4) highest weight properties of the eigenstates in Sections 3.D and 3.F of the appendix or in the calculation of their norm in Section 3.5.
Abstract In this paper we find new integrable one-dimensional lattice models of electrons. We describe all such nearest-neighbour integrable models with s u ( 2 ) × s u ( 2 ) symmetry by classifying solutions of the Yang–Baxter equation following the procedure first introduced in [1]. We find 12 R-matrices of difference form, some of which can be related to known models such as the XXX spin chain and the free Hubbard model, and some are new models. In addition, integrable generalizations of the Hubbard model are found by keeping the kinetic term of the Hamiltonian and adding all terms which preserve fermion number. We find that most of the new models cannot be diagonalized using the standard nested Bethe Ansatz.