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Physical Review A

Enhancing ergotropy of a quantum battery with coherent chargers: The catalystlike role of indefinite causal order

Hai Li, Hsien-Chen Ma, Yaming Hao, Wen-Li Yu

Published Sep 30, 2025• 2 citations
Publisher

Abstract

In recent years, quantum battery (QB) models have emerged as crucial platforms for exploring the connections between quantum effects and energy within the framework of quantum thermodynamics. Inspired by the physical implementation of quantum switch (QS), we, in this work, present a simple QB model in which a two-level system as battery, under a series of coherent chargers, performs the indefinite causal order (ICO) charging by introducing a control qubit as QS. Within the energy-preserving collision interaction framework, we analyze the charging ICO and conventional definite causal order (DCO) dynamics, respectively, and discover the underlying connection between the final charged states of battery in ICO and DCO charging modes. That is, the ICO charged state can be understood as a split of the DCO charged state, accompanied by an offset caused by the interference component characterizing the ICO effect. That provides direct theoretical evidence that the ICO effect positively influences the ergotropy (i.e., the maximum extractable work) of QB only when quantum coherence is present in the charging process, and it is independent of the average stored energy of the QB. By combining numerical simulations, we examine that quantum coherence in our model is a strong quantum resource contributing to the ergotropy of QB, while the ICO effect plays a catalyst-like role, assisting quantum coherence in further enhancing the ergotropy of the battery. In addition, we also demonstrate that increasing the number of chargers also benefits the optimal ergotropy of QB. Finally, we reveal that, when the coherent chargers are subject to the dephasing channel, the ICO charging mode is more robust against dephasing noise than the DCO charging mode. This investigation deepens our understanding of quantum coherence and the ICO effect in the context of quantum thermodynamics.

DOI
10.1103/s6dl-zgkx

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In recent years, quantum battery (QB) models have emerged as crucial platforms for exploring the connections between quantum effects and energy within the framework of quantum thermodynamics. Inspired by the physical implementation of quantum switch (QS), we, in this work, present a simple QB model in which a two-level system as battery, under a series of coherent chargers, performs the indefinite causal order (ICO) charging by introducing a control qubit as QS. Within the energy-preserving collision interaction framework, we analyze the charging ICO and conventional definite causal order (DCO) dynamics, respectively, and discover the underlying connection between the final charged states of battery in ICO and DCO charging modes. That is, the ICO charged state can be understood as a split of the DCO charged state, accompanied by an offset caused by the interference component characterizing the ICO effect. That provides direct theoretical evidence that the ICO effect positively influences the ergotropy (i.e., the maximum extractable work) of QB only when quantum coherence is present in the charging process, and it is independent of the average stored energy of the QB. By combining numerical simulations, we examine that quantum coherence in our model is a strong quantum resource contributing to the ergotropy of QB, while the ICO effect plays a catalyst-like role, assisting quantum coherence in further enhancing the ergotropy of the battery. In addition, we also demonstrate that increasing the number of chargers also benefits the optimal ergotropy of QB. Finally, we reveal that, when the coherent chargers are subject to the dephasing channel, the ICO charging mode is more robust against dephasing noise than the DCO charging mode. This investigation deepens our understanding of quantum coherence and the ICO effect in the context of quantum thermodynamics.
In the standard quantum theory, the causal order of occurrence between events is prescribed, and must be definite. This has been maintained in all conventional scenarios of operation for quantum batteries. In this study we take a step further to allow the charging of quantum batteries in an indefinite causal order (ICO). We propose a nonunitary dynamics-based charging protocol and experimentally investigate this using a photonic quantum switch. Our results demonstrate that both the amount of energy charged and the thermal efficiency can be boosted simultaneously. Moreover, we reveal a counterintuitive effect that a relatively less powerful charger guarantees a charged battery with more energy at a higher efficiency. Through investigation of different charger configurations, we find that ICO protocol can outperform the conventional protocols and gives rise to the anomalous inverse interaction effect. Our findings highlight a fundamental difference between the novelties arising from ICO and other coherently controlled processes, providing new insights into ICO and its potential applications.
Ergotropy--a key figure of merit for quantum battery (QB) performance--plays a crucial role. However, the dynamics and physical mechanisms governing ergotropy evolution remain open challenges. Here, we investigate the ergotropy of a general QB model and find that the charging process is accompanied by the variation and inversion of the energy level populations. In the absence of population inversion, the ergotropy is fully consistent with coherent ergotropy; in local and global population inversion, it is determined by both coherent and incoherent ergotropy. Via random sampling of quantum states and Hamiltonians, we show that coherence and the participation ratio enhance coherent ergotropy, whereas incoherent ergotropy--whether enhanced, unchanged, or suppressed--depends on diagonal entropy, the participation ratio, and energy level population ordering. We demonstrate that the ergotropy lower bound is incoherent ergotropy, the upper bound is the QB stored energy, and enhanced QB purity suppresses locked energy and boosts charging efficiency. Furthermore, we use the Tavis-Cummings (TC) and Jaynes-Cummings (JC) batteries as paradigms to validate our findings. Our work elucidates ergotropy underlying mechanisms in general QBs and establishes a rigorous framework for optimizing ergotropy and charging efficiency, paving the way for high-performance quantum energy-storage devices.
With intensive studies of quantum thermodynamics, quantum batteries (QBs) have been proposed to store and transfer energy via quantum effects. Despite many theoretical models, decoherence remains a severe challenge and practical platforms are still rare. Here, we propose a QB based on the coherent Ising machine, in which the signal field acts as the core energy-storage unit. To clarify the role of quantum coherence in resisting dissipation, we decompose the ergotropy, i.e., the maximum extractable work from the QB, into its coherent and incoherent components. We find that the coherent part decays at a rate roughly half that of the incoherent part, exhibiting much stronger robustness against decoherence. More importantly, the coherent ergotropy and the average charging power reach their respective maxima at essentially the same moment, which defines the optimal instant to switch off the pump field. Finally, by coupling the QB to a two-level system as the load, we demonstrate an efficient energy discharge process of the proposed QB. Our work establishes a realistic and immediately-implementable QB architecture on a mature optical platform, laying a foundation for experimental exploration of quantum energy storage.
Operations performing on quantum batteries are extended to scenarios where we no longer force the existence of definite causal order of occurrence between distinct processes. In contrast to standard theories, the so called indefinite causal order is found to have the capability of accomplishing tasks that are not possible without it. Specifically, we show how this novel class of resource comes into play in quantum batteries by first, combining two static unitary chargers into a coherently superposed one to fully charge an empty battery even if in the presence of battery's local Hamiltonian. Then we demonstrate for a non-unitary charging protocol, the indefinite causal order version charger yields a charged battery with higher energy over its classical counterpart under any conditions. We also have a finding that runs counter to our intuition which, roughly speaking, has the implication that a relatively less powerful charger guarantees a charged battery with higher energy. Finally, to reduce the cost imposed by a measurement-based protection scheme, indefinite causal order shows its potential to fulfill this goal.
Enhancement of quantum battery performance is a popular subject in quantum thermodynamics. An interesting phenomenon is the quick charging effect [Phys. Rev. Res. 6, 023136 (2024)], which has been explored by utilizing a quantum interferometric technique known as superposition of trajectories. A similar technique used to boost quantum battery performance is indefinite causal order. Here, we propose a new charging protocol that utilizes cyclic indefinite causal order, whereby NNN charging sequences are superposed when utilizing NNN chargers. We observe charging efficiency bursts when implementing our cyclic indefinite charging protocol. The duration of these bursts increase with NNN. Additionally, we present a circuit model to implement our charging protocol for the two-charger scenario and perform proof-of-concept demonstrations on IonQ, Quantinuum and IBMQ quantum processors. The results validate the existence of charging efficiency bursts as shown by our theoretical analysis and numerical simulations.
Nonstabilizerness plays an essential role in the efficient simulation of quantum systems on quantum computers. In this work, we investigate its role in the context of quantum batteries (QBs). To this end, we consider a system of N spin-1/2 particles, with the left half serving as the charger and the right half as the battery. By studying different classes of interactions between the charger and the battery, we quantify the amount of nonstabilizerness required to store work in the QB. Our results reveal a strong correlation between the ergotropy stored in the battery and the total nonstabilizerness of the composite system whenever the Hamiltonian preserves a U(1) symmetry. In contrast, this correspondence is generally lost for more generic interactions. A similar behavior is observed for unitary circuit dynamics. Finally, we examine the complementary scenario in which the battery is initialized in a nonstabilizer state and subsequently charged through Clifford evolution. In this case, we find that the maximum average charging power is nonmonotonic in the initial nonstabilizerness. Remarkably, the highest average power can be achieved even when the initial state carries no magic (nonstabilizerness), demonstrating that initial magic is not a necessary ingredient for generating optimal charging power.