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Entropy

Thermal BCS-BEC Crossovers in Finite Systems

Angelo Plastino, F. Pennini, V. M. Apel

Published Oct 30, 2025• 0 citations
Publisher

Abstract

(2) complex model, drawing an analogy to the BCS-BEC crossover in interacting quantum gases. Unlike the conventional crossover, which is driven by tuning the interaction strength, our study suggests that temperature alone can induce a smooth transition from weakly bound Cooper pairs (BCS-like state) to tightly bound dimers (BEC-like state). Using an exactly solvable model with a finite number of fermions, we analyze the structure of eigenstates, pairing correlations, and thermodynamic response functions. We demonstrate that different multiplet structures, characterized by distinct quasi-spin quantum numbers, become thermally accessible, effectively mimicking the crossover behavior seen in ultracold Fermi gases. Our results provide new insights into the role of thermal fluctuations in quantum pairing phenomena and suggest alternative routes for exploring crossover physics in mesoscopic and strongly correlated systems.

DOI
10.3390/e27111116

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(2) complex model, drawing an analogy to the BCS-BEC crossover in interacting quantum gases. Unlike the conventional crossover, which is driven by tuning the interaction strength, our study suggests that temperature alone can induce a smooth transition from weakly bound Cooper pairs (BCS-like state) to tightly bound dimers (BEC-like state). Using an exactly solvable model with a finite number of fermions, we analyze the structure of eigenstates, pairing correlations, and thermodynamic response functions. We demonstrate that different multiplet structures, characterized by distinct quasi-spin quantum numbers, become thermally accessible, effectively mimicking the crossover behavior seen in ultracold Fermi gases. Our results provide new insights into the role of thermal fluctuations in quantum pairing phenomena and suggest alternative routes for exploring crossover physics in mesoscopic and strongly correlated systems.
The crossover from weak coupling Bardeen-Cooper-Schrieffer (BCS) pairing to a Bose-Einstein condensate (BEC) of tightly bound pairs, as a function of the attractive interaction in Fermi systems, has long been of interest to theoretical physicists. The past decade has seen a series of remarkable experimental developments in ultracold Fermi gases that has realized the BCS-BEC crossover in the laboratory, bringing with it fresh new insights into the very strongly interacting unitary regime in the middle of this crossover. In this review, we start with a pedagogical introduction to the crossover and then focus on recent progress in the strongly interacting regime. While our focus is on new theoretical developments, we also describe three key experiments that probe the thermodynamics, transport and spectroscopy of the unitary Fermi gas. We discuss connections between the unitary regime and other areas of physics -- quark-gluon plasmas, gauge-gravity duality and high temperature superconductivity -- and conclude with open questions about strongly interacting Fermi gases.
The problem of the evolution from BCS theory with cooperative Cooper pairing to the formation and condensation of composite bosons has attracted considerable attention for the past several decades. It has gained renewed impetus in the mid-eighties with the discovery of the high-Tc superconductors, which have a coherence length comparable to the interparticle spacing. More recently, this subject has spurred a great deal of research activity in connection with experiments involving dilute atomic gases of fermionic atoms. The initial objective of this work will be to use functional integral techniques to analyze the low-temperature BCS-to-BEC evolution of d-wave superconductors within the saddle point (mean field) approximation for a continuum model. Then, the same mathematical formalism will be applied to the problem of the BCS-to-BEC evolution of fully spin-polarized p-wave Fermi gases in two dimensions. We find that a quantum phase transition occurs for both systems as they are driven from the BCS-like regime of weakly interacting fermionic pairs to the opposite BEC-like regime of strongly interacting bosonic molecules. This is in contrast to the smooth crossover predicted and observed in systems that exhibit s-wave pairing symmetry. We calculate several spectroscopic and thermodynamic properties that signal the occurrence of this phase transition, and suggest some possible experimental realizations. Finally, fluctuations about the saddle point solution are included in the calculations, and the effects of such correction are analyzed in the low (T~0) and high (T~Tc) temperature limits. We conclude that, at high temperatures, the bosonic degrees of freedom that arise from two-particle bound states become essential to describe the strong coupling limit,\nas the saddle point approximation alone becomes unreliable.
Fermion pairing underlies collective quantum phenomena across widely different forms of matter. In extended systems such as ultracold Fermi gases, pairing is commonly understood through the BCS--BEC crossover, where the pair size evolves from large, overlapping Cooper pairs to tightly bound dimers. In finite systems such as atomic nuclei, superconducting grains and quantum dots, however, the same pairing tendency competes with confinement, shell filling and spatial inhomogeneity, making the microscopic structure of pairs much harder to access. Here, we image pair correlations in a finite, tunable system of few fermionic atoms with single-particle resolution and full counting statistics. We observe that confinement and shell structure re-organize pairing in real space: In the weakly interacting, confinement-dominated regime, closed-shell configurations suppress correlations in the high-density trap center. Pairing is mainly observed toward the low-density surface. Open-shell systems, however, support substantially stronger central pairing. Already for surprisingly small systems, increasing either interaction strength or particle number restores a locally bulk-like Cooper-pair profile in the trap center, whereas the edge retains dimer-like correlations. By resolving where pairs form and how their character changes from localized dimers to overlapping Cooper pairs, our measurements provide a microscopic view of pairing in finite fermionic matter and connect the physics of mesoscopic cold atoms to pairing phenomena in nuclei and superconducting nanostructures.
The crossover from weak-coupling Bardeen-Cooper-Schrieffer (BCS) pairing to a Bose-Einstein condensate (BEC) of tightly bound pairs, as a function of the attractive interaction in Fermi systems, has long been of interest to theoretical physicists. The past decade has seen a series of remarkable experimental developments in ultracold Fermi gases that have realized the BCS-BEC crossover in the laboratory, bringing with it fresh new insights into the very strongly interacting unitary regime in the middle of this crossover. In this review, we start with a pedagogical introduction to the crossover and then focus on recent progress in the strongly interacting regime. Although our focus is on new theoretical developments, we also describe three key experiments that probe the thermodynamics, transport, and spectroscopy of the unitary Fermi gas. We discuss connections between the unitary regime and other areas of physics—quark-gluon plasmas, gauge-gravity duality, and high-temperature superconductivity—and conclude with open questions about strongly interacting Fermi gases.
The study of ultracold trapped fermionic gases is a rapidly exploding subject [1-10] which is defining new directions in condensed matter and atomic physics. It has also captured the attention of physicists who study color superconducting quark matter as well as nuclear matter [11-13]. Indeed, it is hard, in recent times, to find a subfield of physics which appeals this broadly to the research community. As we come to understand the gases, experimentalists will move to address fermionic atoms in optical lattices; this will provide important insight to condensed matter physicists as analogue systems for “solving ” intractable many body problems. What makes these gases (and lattices) so important is their remarkable tunability and controllability. Using a Feshbach resonance, one can tune the attractive two-body interaction from weak to strong, and thereby make a smooth crossover from a BCS superfluid to a Bose-Einstein condensation (BEC) [14, 15]. Not only does this allow high transition temperatures Tc (relative to the Fermi energy EF) but it may also provide insights into the high temperature cuprate superconductivity [16-19]. Furthermore, one can tune the population of the two spin states, essentially at will, in this way, allowing exploration [20-22] of exotic polarized phases such as the FFLO [23-25] superfluids, of interest to condensed matter, nuclear and particle physicists. One will be able to tune the lattice parameters such as bandwidth, on-site repulsion, even random disorder, etc and thereby study the famous, and as yet, unsolved Hubbard model Hamiltonian. This paper will concentrate on those issues relating to the effects which are of current interest to experimentalists. In particular, we will study BCS-BEC crossover in atomic Fermi gases, looking at a wide range of different experiments. Our group has been principally interested in the effects of finite temperature [26, 17, 18] and in this review, we will discuss how temperature T enters into the standard crossover theory, and how temperature can be measured, and how temc○
The exact Richardson solution of the reduced BCS Hamiltonian is used to study the BCS-to-BEC crossover, as well as the nature of Cooper pairs, in superconducting and Fermi superfluid media. Based on the exact eigenstate we will discuss the Cooper-pair concept proposing a scenario for the BCS-to-BEC crossover in which a mixture of quasifree fermions and pair resonances (BCS) evolves to a system of weakly bound molecules (BEC). In this single unified scenario the Cooper-pair wavefunction has a unique functional form. We propose a new definition of the condensate fraction which, within the limits of the BCS model, gives a qualitative description of recent experiments in ultracold atomic Fermi gases. Finally, we will introduce a new integrable model for asymmetric superfluid systems able to describe different homogeneous and inhomogeneous competing phases such as, breached superconductivity, deformed Fermi superfluidity, and the elusive Larkin-Ovchinnikov-Flde-Ferrell (LOFF) state.