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BCS-to-BEC Quantum Phase Transition in High-Tc Superconductors and Fermionic Atomic Gases: A Functional Integral Approach

Sergio S. Botelho

Published Sep 12, 2005• 2 citations
OpenAlex

Abstract

The problem of the evolution from BCS theory with cooperative Cooper pairing to the formation and condensation of composite bosons has attracted considerable attention for the past several decades. It has gained renewed impetus in the mid-eighties with the discovery of the high-Tc superconductors, which have a coherence length comparable to the interparticle spacing. More recently, this subject has spurred a great deal of research activity in connection with experiments involving dilute atomic gases of fermionic atoms. The initial objective of this work will be to use functional integral techniques to analyze the low-temperature BCS-to-BEC evolution of d-wave superconductors within the saddle point (mean field) approximation for a continuum model. Then, the same mathematical formalism will be applied to the problem of the BCS-to-BEC evolution of fully spin-polarized p-wave Fermi gases in two dimensions. We find that a quantum phase transition occurs for both systems as they are driven from the BCS-like regime of weakly interacting fermionic pairs to the opposite BEC-like regime of strongly interacting bosonic molecules. This is in contrast to the smooth crossover predicted and observed in systems that exhibit s-wave pairing symmetry. We calculate several spectroscopic and thermodynamic properties that signal the occurrence of this phase transition, and suggest some possible experimental realizations. Finally, fluctuations about the saddle point solution are included in the calculations, and the effects of such correction are analyzed in the low (T~0) and high (T~Tc) temperature limits. We conclude that, at high temperatures, the bosonic degrees of freedom that arise from two-particle bound states become essential to describe the strong coupling limit,\nas the saddle point approximation alone becomes unreliable.

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The problem of the evolution from BCS theory with cooperative Cooper pairing to the formation and condensation of composite bosons has attracted considerable attention for the past several decades. It has gained renewed impetus in the mid-eighties with the discovery of the high-Tc superconductors, which have a coherence length comparable to the interparticle spacing. More recently, this subject has spurred a great deal of research activity in connection with experiments involving dilute atomic gases of fermionic atoms. The initial objective of this work will be to use functional integral techniques to analyze the low-temperature BCS-to-BEC evolution of d-wave superconductors within the saddle point (mean field) approximation for a continuum model. Then, the same mathematical formalism will be applied to the problem of the BCS-to-BEC evolution of fully spin-polarized p-wave Fermi gases in two dimensions. We find that a quantum phase transition occurs for both systems as they are driven from the BCS-like regime of weakly interacting fermionic pairs to the opposite BEC-like regime of strongly interacting bosonic molecules. This is in contrast to the smooth crossover predicted and observed in systems that exhibit s-wave pairing symmetry. We calculate several spectroscopic and thermodynamic properties that signal the occurrence of this phase transition, and suggest some possible experimental realizations. Finally, fluctuations about the saddle point solution are included in the calculations, and the effects of such correction are analyzed in the low (T0) and high (TTc) temperature limits. We conclude that, at high temperatures, the bosonic degrees of freedom that arise from two-particle bound states become essential to describe the strong coupling limit,\nas the saddle point approximation alone becomes unreliable.
This thesis focuses on the analysis of Bardeen-Cooper-Schrieffer (BCS) \nto Bose-Einstein condensation (BEC) evolution in ultracold superfluid \nFermi gases when the interaction between atoms is varied. The tuning of \nattractive interactions permits the ground state of the system to evolve from a weak \nfermion attraction BCS limit of loosely bound and largely overlapping Cooper pairs \nto a strong fermion attraction limit of tightly bound small bosonic molecules \nwhich undergo BEC. \nThis evolution is accompanied by anomalous behavior of many superfluid \nproperties, and reveals several quantum phase transitions. \nThis thesis has two parts: \nIn the first part, I analyze zero and nonzero orbital angular momentum \npairing effects, and show that a quantum phase transition occurs for \nnonzero angular momentum pairing, unlike the sss-wave case where the BCS \nto BEC evolution is just a crossover. \nIn the second part, I analyze two-species fermion mixtures with mass and \npopulation imbalance in continuum, trap and lattice models. In contrast with \nthe crossover physics found in the mass and population balanced mixtures, \nI demonstrate the existence of phase transitions between normal and \nsuperfluid phases, as well as phase separation between superfluid (paired) \nand normal (excess) fermions in imbalanced mixtures as a function of scattering \nparameter and mass and population imbalance.
This Thesis analyzes the role of a mean-field theory and of the fluctuations in two different fermionic systems: the BCS-BEC crossover and high-Tc superconducting cuprates. In the first part of the Thesis we introduce the mean-field theory and the Gaussian-level fluctuations for the BCS-BEC crossover, i.e. the continuous evolution observed in ultracold neutral fermionic systems, from a weakly-coupled regime where fermions form Cooper pairs, to a strongly-coupled regime where the fermions at first form bosonic molecular dimers, subsequently undergoing Bose-Einstein condensation for low enough temperatures. We then analyze some problems related to the crossover: the condensate fraction for a spin-unbalanced Fermi gas, the Beliaev decay for collective excitations and the case of a two-dimensional Fermi gas, for which we calculate the first sound velocity and the Berezinskii-Kosterlitz-Thouless critical temperature, in very good agreement with recent experimental data. Finally we analyze a regularization procedure for the equation of state in the deep-BEC limit, allowing one to analytically derive the correct ratio between the fermionic and bosonic scattering lengths. In the second part of the Thesis we introduce a gauge approach to superconductivity in cuprates in which the hole is decomposed as the product of a spinful neutral particle, the spinon, and a spinless charged particle, the holon. The statistics of each particle is modified by binding it to a gauge field providing a statistical flux, this approach being analogous to Chern-Simons bosonization. We thus obtain a model characterized by three characteristic temperatures corresponding, respectively, to the appearance of a finite density of incoherent holon pairs, of a finite density of incoherent spinon pairs and, finally, to the phase coherence leading to superconductivity. Specifically in the present Thesis within this model we study the superfluid density, demonstrating that the spinon and holon contributions sum according to a Ioffe-Larking-like rule, analogous to that they found for resistivity, showing excellent agreement with experimental data in the moderate underdoping up to optimal doping region. We also demonstrated that the formalism reproduces the quasi-universality observed in experimental data at different dopings and allows for an analytical derivation of a relation that approximates the Uemura relation for moderate dopings.
This article gives a detailed review of our current theoretical understanding of the crossover from cooperative Cooper pairing to independent bound-state formation and Bose–Einstein condensation in Fermi systems with increasing attractive interactions. Introduction There are two well-known paradigms for understanding the phenomena of superconductivity and superfluidity: (I) BCS theory [1], in which the normal state is a degenerate Fermi liquid that undergoes a pairing instability at a temperature T c ≪ ε f , the degeneracy scale. The formation of Cooper pairs and their condensation (macroscopic occupation of a single quantum state) both occur simultaneously at the transition temperature T c . (II) Bose–Einstein condensation (BEC) of bosons at a T c of the order of their degeneracy temperature. At a fundamental level these bosons (for example, 4 He or excitons) are invariably composite objects made up of an even number of fermions. The composite particles form at some very high temperature scale of the order of their dissociation temperature T dissoc , and these “pre-formed” bosons then condense at the BEC T c ≪ T dissoc . In most cases of experimental interest the system under consideration clearly falls into one category or the other. For instance, 3 He is a Fermi superfluid described by (I) whereas 4 He is a Bose superfluid (II). Essentially all cases of superconductivity in metals that we understand reasonably well are much closer to (I) than to (II), as evidenced by the existence of fermionic quasiparticles above T c .
(2) complex model, drawing an analogy to the BCS-BEC crossover in interacting quantum gases. Unlike the conventional crossover, which is driven by tuning the interaction strength, our study suggests that temperature alone can induce a smooth transition from weakly bound Cooper pairs (BCS-like state) to tightly bound dimers (BEC-like state). Using an exactly solvable model with a finite number of fermions, we analyze the structure of eigenstates, pairing correlations, and thermodynamic response functions. We demonstrate that different multiplet structures, characterized by distinct quasi-spin quantum numbers, become thermally accessible, effectively mimicking the crossover behavior seen in ultracold Fermi gases. Our results provide new insights into the role of thermal fluctuations in quantum pairing phenomena and suggest alternative routes for exploring crossover physics in mesoscopic and strongly correlated systems.
This review is written at the time of the twentieth anniversary of the discovery of high-temperature superconductors, which nearly coincides with the important discovery of the superfluid phases of ultracold trapped fermionic atoms. We show how these two subjects have much in common. Both have been addressed from the perspective of the BCS—Bose–Einstein condensation (BEC) crossover scenario, which is designed to treat short coherence length superfluids with transition temperatures which are “high” with respect to the Fermi energy. A generalized mean field treatment of BCS–BEC crossover at general temperatures T, based on the BCS–Leggett ground state, has met with remarkable success in the fermionic atomic systems. Here we summarize this success in the context of four different cold atom experiments, all of which provide indications, direct or indirect, for the existence of a pseudogap. This scenario also provides a physical picture of the pseudogap phase in the underdoped cuprates which is a central focus of high Tc research. We summarize successful applications of BCS–BEC crossover to key experiments in high Tc systems, including the phase diagram, specific heat, and vortex core STM data, along with the Nernst effect, and exciting recent data on the superfluid density in very underdoped samples.
The crossover from weak coupling Bardeen-Cooper-Schrieffer (BCS) pairing to a Bose-Einstein condensate (BEC) of tightly bound pairs, as a function of the attractive interaction in Fermi systems, has long been of interest to theoretical physicists. The past decade has seen a series of remarkable experimental developments in ultracold Fermi gases that has realized the BCS-BEC crossover in the laboratory, bringing with it fresh new insights into the very strongly interacting unitary regime in the middle of this crossover. In this review, we start with a pedagogical introduction to the crossover and then focus on recent progress in the strongly interacting regime. While our focus is on new theoretical developments, we also describe three key experiments that probe the thermodynamics, transport and spectroscopy of the unitary Fermi gas. We discuss connections between the unitary regime and other areas of physics -- quark-gluon plasmas, gauge-gravity duality and high temperature superconductivity -- and conclude with open questions about strongly interacting Fermi gases.