Quantum mechanics describes change as reversible and deterministic over unitary time, but we observe random change over nonunitary time. Thermocontextual mechanics (TCM) accommodates nonunitary time as fundamental by introducing two innovations. First, it defines states thermocontextually with respect to a measurement framework in equilibrium with the system’s actual surroundings, which always has a positive minimum temperature. This establishes ambient temperature, ambient heat, and exergy as objectively defined properties of state. Second, TCM’s “No hidden variables” law empirically defines states as measurable and definite. TCM’s second law is based on measurable changes in state before and after transitions between discrete measurable states. It codifies observations that a state only transitions in the direction of declining work potential on a fixed reference. It accommodates thermodynamics’ Second Law and statistical mechanics’ MaxEnt as distinct transition types. TCM’s third law codifies observations showing that networked transitions minimize irreversible losses. In the limit of reversibility, quantum processes are deterministic and unitary. By recognizing both unitary and nonunitary time, TCM explains previously unexplained observations strictly in terms of testable and empirically justified assumptions. These include the arrow of time, the measurement problem, nonlocality, and the spontaneous emergence of functional complexity.
Quantum mechanics describes change as reversible and deterministic over unitary time, but we observe random change over nonunitary time. Thermocontextual mechanics (TCM) accommodates nonunitary time as fundamental by introducing two innovations. First, it defines states thermocontextually with respect to a measurement framework in equilibrium with the system’s actual surroundings, which always has a positive minimum temperature. This establishes ambient temperature, ambient heat, and exergy as objectively defined properties of state. Second, TCM’s “No hidden variables” law empirically defines states as measurable and definite. TCM’s second law is based on measurable changes in state before and after transitions between discrete measurable states. It codifies observations that a state only transitions in the direction of declining work potential on a fixed reference. It accommodates thermodynamics’ Second Law and statistical mechanics’ MaxEnt as distinct transition types. TCM’s third law codifies observations showing that networked transitions minimize irreversible losses. In the limit of reversibility, quantum processes are deterministic and unitary. By recognizing both unitary and nonunitary time, TCM explains previously unexplained observations strictly in terms of testable and empirically justified assumptions. These include the arrow of time, the measurement problem, nonlocality, and the spontaneous emergence of functional complexity.
The thermocontextual interpretation (TCI) is an alternative to the existing interpretations of physical states and time. The prevailing interpretations are based on assumptions rooted in classical mechanics, the logical implications of which include determinism, time symmetry, and a paradox: determinism implies that effects follow causes and an arrow of causality, and this conflicts with time symmetry. The prevailing interpretations also fail to explain the empirical irreversibility of wavefunction collapse without invoking untestable and untenable metaphysical implications. They fail to reconcile nonlocality and relativistic causality without invoking superdeterminism or unexplained superluminal correlations. The TCI defines a system's state with respect to its actual surroundings at a positive ambient temperature. It recognizes the existing physical interpretations as special cases which either define a state with respect to an absolute zero reference (classical and relativistic states) or with respect to an equilibrium reference (quantum states). Between these special case extremes is where thermodynamic irreversibility and randomness exist. The TCI distinguishes between a system's internal time and the reference time of relativity and causality as measured by an external observer's clock. It defines system time as a complex property of state spanning both reversible mechanical time and irreversible thermodynamic time. Additionally, it provides a physical explanation for nonlocality that is consistent with relativistic causality without hidden variables, superdeterminism, or "spooky action".
The thermocontextual interpretation (TCI) defines the physical state with respect to a system’s actual surroundings at a positive ambient temperature. The TCI provides a clear distinction between the Second Law of thermodynamics and MaxEnt. The Second Law dictates irreversible dissipation of free energy to ambient heat, and it establishes the thermodynamic arrow of time. MaxEnt describes reversible changes in statistical mechanical entropy in response to changes in the system’s boundary constraints. We introduce new TCI postulates that establish the equality of thermal and statistical entropies and MaxEnt as a fundamental physical principle. We then apply MaxEnt to the double-slit experiment. Impacts of multiple particles symmetrically passing through parallel slits record a wave interference pattern over time. However, a which-slit detector eliminates wave interference. Richard Feynman called the double slit experiment the only mystery, at the heart of quantum mechanics. The TCI and MaxEnt offer a simple explanation. The which-slit detector breaks the system’s symmetry, and MaxEnt selects the higher-entropy asymmetrical state, enabling particles to pass through one slit or the other without wave interference.
The prevailing interpretations of physics are based on deeply entrenched assumptions, rooted in classical mechanics. Logical implications include: the denial of entropy as a fundamental physical property, and the inability to explain irreversible change, random quantum measurements, or nonlocality without untestable and implausible metaphysical implications. We propose a conceptual model that is based on empirically justifiable assumptions and consistent with observations. The WYSIWYG Conceptual Model (WCM) assumes no hidden properties: “What You can See Is What You Get.” The WCM contextually defines a system’s state with respect to its actual ambient background, and it extends existing models of physical reality by defining entropy and exergy as objective contextual properties of state. The WCM establishes the irreversible dissipation of exergy and the Second law of thermodynamics as a fundamental law of physics, it recognizes physical randomness, and it provides a physical explanation for nonlocality, consistent with Special Relativity, without hidden variables, superdeterminism, or “spooky action.”
All the laws of physics are time-reversible. Time arrow emerges only when ensembles of classical particles are treated probabilistically, outside of physics laws, and the entropy and the second law of thermodynamics are introduced. In quantum physics, no mechanism for a time arrow has been proposed despite its intrinsic probabilistic nature. In consequence, one cannot explain why an electron in an excited state will "spontaneously" transition into a ground state as a photon is created and emitted, instead of continuing in its reversible unitary evolution. To address such phenomena, we introduce an entropy for quantum physics, which will conduce to the emergence of a time arrow. The entropy is a measure of randomness over the degrees of freedom of a quantum state. It is dimensionless; it is a relativistic scalar, it is invariant under coordinate transformation of position and momentum that maintain conjugate properties and under CPT transformations; and its minimum is positive due to the uncertainty principle. To excogitate why some quantum physical processes cannot take place even though they obey conservation laws, we partition the set of all evolutions of an initial state into four blocks, based on whether the entropy is (i) increasing but not a constant, (ii) decreasing but not a constant, (iii) a constant, (iv) oscillating. We propose a law that in quantum physics entropy (weakly) increases over time. Thus, evolutions in the set (ii) are disallowed, and evolutions in set (iv) are barred from completing an oscillation period by instantaneously transitioning to a new state. This law for quantum physics limits physical scenarios beyond conservation laws, providing causality reasoning by defining a time arrow.
Quantum mechanics is widely recognised as being incomplete. It is not consistent with the second law of thermodynamics and does not provide a scientifically credible physical account of the measurement process, the means by which coherence is broken and classically observable states are recorded. This has led to many ad hoc assumptions being used to account for various properties of quantum systems, among which is the coherence time of quantum devices that determines their ability to perform computations. Here, we show that all these properties can be accommodated naturally and consistently in the context of mixing quantum systems which exhibit continuous spectra, as arises in the thermodynamic limit in quantum statistical mechanics and quantum gravity. In particular, for isolated systems we show that the time-reversal symmetry associated with unitary time evolution of the quantum state gives rise to time-symmetry breaking and a semi-group evolution which attains thermodynamic equilibrium at long times. Moreover, the emergence of this non-unitary time-asymmetry leads to microcanonical equilibrium states in which all quantum coherence is lost and is accompanied by the transformation of pure states into mixtures, leading in turn to an increase in entropy. Inclusion of a macroscopic measurement apparatus shows how the outcome of a measurement corresponds to the von Neumann projection postulate, arising with probabilities in conformance with the Born rule. The mathematical structure of the theory which applies to quantum systems with continuous spectra is closely analogous to the classical ergodic theory of dynamical systems and the conditions under which they attain equilibrium states.
The thermocontextual interpretation (TCI) establishes a system’s exergy, entropic energy, and thermal entropy as thermocontextual properties of state, defined with respect to its positive temperature surroundings. This work extends previous applications of the TCI to irreversible and statistical transitions. The TCI defines statistical entropy as a transactional process of derandomization and transition to a negative-entropy state. Statistical measurements of a confined quantum particle’s position are detailed in terms of reversible processes of instantiation and actualization. The TCI then formalizes the MaxEnt as a fundamental physical principle. We apply MaxEnt and statistical entropy measurements to the double-slit experiment. Particles passing through parallel slits record a wave interference pattern, but a “which-slit” detector eliminates wave interference. Richard Feynman called the double-slit experiment the only mystery, at the heart of quantum mechanics. The TCI offers a simple explanation. The which-slit detector breaks the system’s symmetry, enabling particles to pass through one slit or the other, and MaxEnt selects the asymmetrical transition, which has no wave interference and a higher statistical entropy.