Statistical Definition of Entropy

Robert H. Swendsen

Robert H. Swendsen

Differences of opinion concerning fundamental issues in statistical mechanics directly related to the thermodynamic entropy have persisted through more than a century of debate. One reason is the lack of consensus on the definitions of key terms, especially the terms “distinguishable,” “indistinguishable,” and “identical.” Several definitions occur in the literature, but are not always made explicit. The multiplicity of definitions has created confusion about the basic conditions under which entropy is to be defined. In this paper, I present an overview of definitions in current use for terms associated with distinguishability and relate them to various definitions that have been suggested for entropy. My hope is that consensus will be achievable if the definitions are clarified and agreed upon.

Lídia del Rio, Johan Åberg, Renato Renner +2 more

Osvaldo Civitarese, Manuel Gadella

The concept of entropy is central to the formulation of the quantum statistical mechanics, and it is linked to the definition of the density operator and the associated probabilities of occupation of quantum states. The extension of this scheme to accommodate for quantum decaying states is conceptually difficult, because of the nature of these states. Here we present a way to treat quantum unstable states in the context of statistical mechanics. We focuss on the definition of the entropy and avoid the use of complex temperatures.

Alexander Stotland, A. A. Pomeransky, Eitan Bachmat +1 more

It is well known that a Shannon based definition of information entropy leads in the classical case to the Boltzmann definition of entropy. It is tempting to regard the Von Neumann entropy as the corresponding quantum mechanical definition. But the latter has little to do with information theory. Consequently we introduce a new definition of entropy that reflects the inherent uncertainty of quantum mechanical states. We derive for it an explicit expression, and discuss some of its general properties. We distinguish between the minimum uncertainty entropy of pure states, and the excess statistical entropy of mixtures.

Renato Ascoli, R. Urigu