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arXiv:1605.05690 · Physica A Statistical Mechanics and its Applications

The definition of the thermodynamic entropy in statistical mechanics

Robert H. Swendsen

Published Oct 16, 2016• 11 citations
arXivHTMLPDF
DOI
10.1016/j.physa.2016.10.032

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Differences of opinion concerning fundamental issues in statistical mechanics directly related to the thermodynamic entropy have persisted through more than a century of debate. One reason is the lack of consensus on the definitions of key terms, especially the terms “distinguishable,” “indistinguishable,” and “identical.” Several definitions occur in the literature, but are not always made explicit. The multiplicity of definitions has created confusion about the basic conditions under which entropy is to be defined. In this paper, I present an overview of definitions in current use for terms associated with distinguishability and relate them to various definitions that have been suggested for entropy. My hope is that consensus will be achievable if the definitions are clarified and agreed upon.