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Systematic modulation of superconducting gap dynamics in YBCO|BNT|YBCO Josephson Junctions through THz field interaction and BNT ferroelectric barrier

Muthukkumaran Karthikeyan, Geoffrey Chanda, Thanayut Kaewmaraya, Pairot Moontragoon, Guoxing Sun, Zongjin Li, Anucha Watcharapasorn

Published Oct 1, 2025• 1 citation
Publisher

Abstract

Abstract The integration of ferroelectric barriers into high temperature Josephson junctions offers a pathway to tunable superconducting quantum devices. Here, we demonstrate robust Josephson coupling in YBa₂Cu₃O₇₋ₓ (YBCO) | Bi₀.₅Na₀.₅TiO₃ (BNT) | YBCO trilayer junctions incorporating a relatively thick (40 nm) ferroelectric BNT barrier. Epitaxial trilayers were fabricated using pulsed laser deposition on SrTiO₃ substrates and systematically investigated under broadband terahertz (THz) irradiation in the range of 0.5 to 2.5 THz. At 1.5 THz, which is close to the Josephson plasma resonance, the BNT polarization increased significantly, from 33.4 to 46.4 µC/cm² at 30 K, leading to enhanced superconducting transport. The junctions exhibited a well-defined zero voltage supercurrent branch, with critical current Ic​(T) remaining nearly constant up to 60 K and reaching a peak value of 468.2 µA under 1.5 THz excitation, evidencing strong phase coherence. Scanning tunneling spectroscopy revealed enhanced superconducting gaps in YBCO|BNT|YBCO (Δ = 1.3 meV) compared to pure YBCO (Δ = 1.05 meV), while optical conductivity measurements showed a systematic reduction in conductivity and gap with increasing temperature, consistent with BCS theory under THz excitation. To exclude defect mediated transport, atomic force microscopy and X ray reflectivity confirmed uniform morphology and sharp interfaces. Magnetic field modulation of Ic(B) exhibited a canonical Fraunhofer interference pattern, and resistance mapping revealed alternating lobes of high and low dissipation, both of which are strong indicators of coherent Josephson tunneling. These results establish that Josephson coupling is intrinsic to the YBCO|BNT|YBCO junctions, enabled by the dipolar character and dynamic THz response of the BNT barrier. This study positions BNT as a viable and tunable barrier material for next generation superconducting quantum devices based on high-Tc materials.

DOI
10.21203/rs.3.rs-7638991/v1

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We report on the fabrication and millikelvin char acterization of Nb/Al–AlOx/Nb Josephson junctions directly de posited on X-cut LiNbO3 substrates. Motivated by the strong electro-optic and piezoelectric properties of LiNbO3, such devices are of interest for future hybrid superconducting–electro-optic architectures. The junctions were fabricated using standard processes involving DC magnetron sputtering followed by controlled thermal oxidation of the aluminum layer to form an AlOx tunnel barrier with reproducible junction areas. Insulation of the junctions was achieved by anodization and SiOx deposition. Electrical measurements performed at 30 mK reveal high-quality Josephson tunnel junction behavior with a critical current density ofJc= 70 A/cm2and a characteristic voltage reaching values up toVm= 286 mV. Differential conductance measurements exhibit pronounced quasiparticle peaks corresponding to a sum gap energy of 2Δ = (2.73 ± 0.05) meV, confirming the good quality of the Nb electrodes. Magnetic-field-dependent measure ments yield a Josephson penetration depth of λJ= 45 μm, confirming operation in the small-junction regime, with deviations from the ideal Josephson interference pattern attributed to non-uniform current distribution across the junction area. Compared to our previous characterization at 4.2 K, this work demonstrates reliable Josephson junction operation on LiNbO3 at dilution-refrigerator temperatures relevant for quantum circuits, supporting the suitability of lithium niobate as a promising substrate for future hybrid superconducting–electro-optic device implementations.
We present comprehensive experimental and numerical studies of the subpicosecond switching dynamics of YBa2Cu3O7-x (YBCO) grain-boundary Josephson junctions, excited by single-picosecond electrical pulses. The test structures were patterned in 100-nm- thick YBCO films grown by pulsed laser deposition on (100) MgO bicrystal substrates. Each sample consisted of a coplanar strip (CPS) transmission line, a microbridge acting as the electrical pulse generator, and a single Josephson junction positioned between the CPS lines about 100 micrometer away from the bridge. The junctions were characterized by the nonhysteretic current-voltage characteristics with the characteristic voltage approximately equal to 2.0 mV at 20 K (temperature of our experiments). A train of 100- fs-wide optical pulses from a Ti:sapphire laser photo-excited the microbridge and generated 2-ps-wide electrical pulses, which were then applied to switch the junction. In addition to the input pulse, the junction was dc-biased at +0.7 Ic, -0.7 Ic, +1.5 Ic, -1.5 Ic, and zero-Ic, where Ic is junction critical current. Time-resolved dynamics of the junction response was studied with the help of our cryogenic electro-optic sampling system, which can be regarded as a sampling oscilloscope featuring < 200-fs time resolution and < 150-(mu) V voltage sensitivity. We obtained 0.7-ps-wide single-flux-quantum (SFQ) pulses generated as a result of the junction switching process. The measurements were compared to numerical computations based on the equivalent circuit containing a resistively shunted Josephson junction, and we have found a satisfactory agreement between our simulations and experimental data. We believe our findings provide experimental confirmation of the potential of YBCO Josephson gattes as building blocks of ultrafast (sub-THz) digital electronics.
Abstract We report the electrical transport of thin vertically-stacked Josephson tunnel junctions. The devices were fabricated using 16 nm thick GdBa 2 Cu 3 O 7− δ electrodes and 1–4 nm SrTiO 3 as an insulating barrier. The results show Josephson coupling for junctions with SrTiO 3 barriers of 1 and 2 nm. Subtracting the residual current in the Fraunhofer patterns, energies of 3.1 mV and 5.7 mV at 12 K are obtained for STO barriers of 1 nm and 2 nm, respectively. The residual current may be related to the contribution of pinholes and thickness fluctuations in the STO barrier. These values are promising for reducing the influence of thermal noise and increasing the frequency operation rate in superconducting devices using high-temperature superconductors.
Superconducting electrodes are an integral part of hybrid Josephson junctions used in many applications including quantum technologies. We report on the fabrication and characterization of superconducting hybrid Au/YBa2Cu3O7-x (YBCO) electrodes on vicinal substrates. In these structures, superconducting CuO2-planes face the gold film, resulting in a higher value and smaller variation of the induced energy gap compared to the conventional Au/YBCO electrodes based on films with the c-axis normal to the substrate surface. Using scanning tunneling microscopy, we observe an energy gap of about 10-17 meV at the surface of the 15- nm-thick gold layer deposited in situ atop the YBCO film. To study the origin of this gap, we fabricate nanoconstrictions from the Au/YBCO heterostructure and measure their electrical transport characteristics. The conductance of the nanoconstrictions shows a series of dips due to multiple Andreev reflections in YBCO and gold providing clear evidence of the superconducting nature of the gap in gold. We consider the Au/YBCO electrodes to be a versatile platform for hybrid Josephson devices with a high operating temperature.