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International Journal of Quantum Chemistry

Exploring Quantum Information Entropy in Double Hyperbolic Potentials Under the Fractional Schrödinger Framework

David Maya‐Franco, Emmanuel Martínez‐Guerrero, Guo-Hua Sun, Shi‐Hai Dong

Published Jul 23, 2025• 4 citations
Publisher

Abstract

ABSTRACT In this work, we investigate quantum information entropy for double hyperbolic well potentials within the framework of the fractional Schrödinger equation (FSE). Specifically, we analyze the position and momentum Shannon entropies for two hyperbolic potentials, and , as a function of the fractional derivative order . Our findings reveal that decreasing enhances wave function localization in position space, thereby reducing spatial uncertainty while simultaneously increasing momentum uncertainty. We confirm the validity of the Beckner–Bialynicki‐Birula–Mycielski inequality for both potentials, demonstrating its robustness across different degrees of nonlocality. Furthermore, we explore the behavior of Fisher information, observing that it increases in position space while decreases in momentum space as the well depths grow.

DOI
10.1002/qua.70086

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In this work we have studied the Shannon information entropy for two hyperbolic single-well potentials in the fractional Schrödinger equation (the fractional derivative number (0<n≤2) by calculating position and momentum entropy. We find that the wave function will move towards the origin as the fractional derivative number n decreases and the position entropy density becomes more severely localized in more fractional system, i.e., for smaller values of n, but the momentum probability density becomes more delocalized. And then we study the Beckner Bialynicki-Birula−Mycieslki (BBM) inequality and notice that the Shannon entropies still satisfy this inequality for different depth u even though this inequality decreases (or increases) gradually as the depth u of the hyperbolic potential U1 (or U2) increases. Finally, we also carry out the Fisher entropy and observe that the Fisher entropy increases as the depth u of the potential wells increases, while the fractional derivative number n decreases.
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Abstract The Shannon entropy (S) and the Fisher Information (I) entropies are investigated for a generalized hyperbolic potential in position and momentum spaces. First, the Schrodinger equation is solved exactly using the Nikiforov‐Uvarov‐Functional Analysis method to obtain the energy spectra and the corresponding wave function. By Fourier transforming the position space wave function, the corresponding momentum wave function was obtained for the low‐lying states corresponding to the ground and first excited states. The positions and momentum of Shannon entropy and Fisher Information entropies were calculated numerically. Finally, the Bialynicki‐Birula and Mycielski and the Stam‐Cramer‐Rao inequalities for the Shannon entropy and Fisher Information entropies, respectively, were tested and were found to be satisfied for all cases considered.
Fisher information (FI) and Shannon entropy (SP), as fundamental theoretical constructs, play crucial roles in quantum information, offering significant insights into communication systems. This work addresses the radial Schrödinger equation for a cotangent hyperbolic potential, solved using the parametric Nikiforov–Uvarov method. The derived wave functions are utilized to explore FI and SP within a one-dimensional system. The analysis focuses on the influence of the screening parameter and potential depth on these quantities, examining their behavior for the ground state and the first excited state. The study complies with key theoretical principles, including the Cramer–Rao inequality, the Beckner-Bialynicki-Birula-Mycielski (BBM) inequality, and the Heisenberg uncertainty principle. The results shed light on the dynamics of quantum states, emphasizing the relationship between quantum uncertainties and information measures. Significant variations in FI and SP emerge with changes in the screening parameter and potential depth, enhancing the understanding of quantum mechanics in confined systems. The findings also reveal the phenomenon of entropy squeezing, underscoring the complex nature of quantum uncertainties. The model demonstrates realistic behavior, with distinct transition points in SP as a function of potential depth, highlighting unique and intriguing characteristics. These contributions enrich the theoretical framework for investigating quantum systems, providing valuable perspectives on their intricate behaviors.