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International Journal of Quantum Chemistry

Theoretic quantum information entropies for the generalized hyperbolic potential

Akpan N. Ikot, Gaotsiwe Joel Rampho, P. O. Amadi, U. S. Okorie, M. J. Sithole, M. L. Lekala

Published Aug 27, 2020• 23 citations
Publisher

Abstract

Abstract The Shannon entropy (S) and the Fisher Information (I) entropies are investigated for a generalized hyperbolic potential in position and momentum spaces. First, the Schrodinger equation is solved exactly using the Nikiforov‐Uvarov‐Functional Analysis method to obtain the energy spectra and the corresponding wave function. By Fourier transforming the position space wave function, the corresponding momentum wave function was obtained for the low‐lying states corresponding to the ground and first excited states. The positions and momentum of Shannon entropy and Fisher Information entropies were calculated numerically. Finally, the Bialynicki‐Birula and Mycielski and the Stam‐Cramer‐Rao inequalities for the Shannon entropy and Fisher Information entropies, respectively, were tested and were found to be satisfied for all cases considered.

DOI
10.1002/qua.26410

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Abstract The Shannon entropy (S) and the Fisher Information (I) entropies are investigated for a generalized hyperbolic potential in position and momentum spaces. First, the Schrodinger equation is solved exactly using the Nikiforov‐Uvarov‐Functional Analysis method to obtain the energy spectra and the corresponding wave function. By Fourier transforming the position space wave function, the corresponding momentum wave function was obtained for the low‐lying states corresponding to the ground and first excited states. The positions and momentum of Shannon entropy and Fisher Information entropies were calculated numerically. Finally, the Bialynicki‐Birula and Mycielski and the Stam‐Cramer‐Rao inequalities for the Shannon entropy and Fisher Information entropies, respectively, were tested and were found to be satisfied for all cases considered.
A Schrödinger equation is solved for a cotangent hyperbolic potential using the elegant parametric Nikiforov–Uvarov method. The results obtained are used to calculate the Fisher information for position space and momentum space as well as the Shannon entropy for position space and momentum space at the ground state. The energies of the cotangent potential are observed to be fully bounded for different quantum states. The Fisher information satisfied the Fisher relation known as Cramer–Rao inequality for the Fisher product. Its result also obeyed the Heisenberg principle as its alternative for uncertainty measurement. However, the Shannon entropy only satisfied the Bialynick-Birula, Mycielski inequality for higher values of the screening parameter. Its relation to the Heisenberg principle failed as both the position space and the momentum space are parallel with high entropy squeezing. This potential has not been reported for any system to the best of our understanding.
The approximate solutions of the Schrödinger equation with the central generalized Hulthén and Yukawa potential are investigated within the framework of the functional method. The obtained wave function and the energy levels are used to study the Shannon entropy, Renyi entropy, Fisher information, Shannon Fisher complexity, Shannon power and Fisher-Shannon product in both position and momentum spaces for the ground and first excited states. The theoretic information theories such as Shannon entropies Sr,Sp, Fisher information Ip,Ip and Renyi entropies Rβ as well as the information entropy probability densities ρ(r),ϕ(p) are illustrated graphically. The Bialynicki-Birula – Mycielski (BBM) inequality for the Shannon entropies and the Cramer-Rao inequality for the Fisher information are satisfied for the potential model.
This study presents a comprehensive investigation of quantum information measures for the one-dimensional Ultra Generalized Exponential–Hyperbolic Potential (UGEHP) within the framework of the Schrödinger equation. Analytical solutions for the energy eigenvalues and corresponding wave functions are obtained using the Nikiforov–Uvarov method. These solutions serve as the basis for evaluating Shannon entropy and Fisher information in both position and momentum spaces. The numerical results show that the total Shannon entropy satisfies the Beckner–Białynicki-Birula–Mycielski (BBM) inequality, while the Fisher information adheres to the Stam–Cramér–Rao bounds, thereby confirming consistency with fundamental quantum uncertainty principles. In addition, the energy spectrum exhibits a pronounced dependence on the screening parameter and quantum numbers, indicating the tunable confinement properties of the potential. The combined analysis establishes a clear connection between energy quantization, wavefunction localization, and information-theoretic measures, offering deeper insight into the effectiveness of the UGEHP model in describing complex quantum systems.
The exact solutions to the Schrödinger equation with a hyperbolic potential are obtained. The position S x and momentum S p Shannon information entropies for the low-lying states are calculated. Some interesting features of the information entropy densities and as well as the probability densities and are demonstrated. We find that the choices of the values for those parameters have to satisfy the condition on . We also notice that the and are symmetric to the momentum p and the or is equal or greater than 1 at some positions r or momentum p . In addition, the Bialynicki-Birula–Mycielski inequality is tested from different cases and found to hold for these cases.
Fisher information (FI) and Shannon entropy (SP), as fundamental theoretical constructs, play crucial roles in quantum information, offering significant insights into communication systems. This work addresses the radial Schrödinger equation for a cotangent hyperbolic potential, solved using the parametric Nikiforov–Uvarov method. The derived wave functions are utilized to explore FI and SP within a one-dimensional system. The analysis focuses on the influence of the screening parameter and potential depth on these quantities, examining their behavior for the ground state and the first excited state. The study complies with key theoretical principles, including the Cramer–Rao inequality, the Beckner-Bialynicki-Birula-Mycielski (BBM) inequality, and the Heisenberg uncertainty principle. The results shed light on the dynamics of quantum states, emphasizing the relationship between quantum uncertainties and information measures. Significant variations in FI and SP emerge with changes in the screening parameter and potential depth, enhancing the understanding of quantum mechanics in confined systems. The findings also reveal the phenomenon of entropy squeezing, underscoring the complex nature of quantum uncertainties. The model demonstrates realistic behavior, with distinct transition points in SP as a function of potential depth, highlighting unique and intriguing characteristics. These contributions enrich the theoretical framework for investigating quantum systems, providing valuable perspectives on their intricate behaviors.
In this paper, we studied, at first, the influence of the energy-dependent potentials on the one-dimensionless Klein–Gordon oscillator. Then, the Shannon entropy and Fisher information of this system are investigated. The position and momentum information entropies for the low-lying states n = 0, 1, 2 are calculated. Some interesting features of both Fisher and Shannon densities, as well as the probability densities, are demonstrated. Finally, the Stam, Cramer–Rao and Bialynicki–Birula–Mycielski (BBM) inequalities have been checked, and their comparison with the regarding results have been reported. We showed that the BBM inequality is still valid in the form [Formula: see text], as well as in ordinary quantum mechanics.