The quantum states of a spin 12 (a qubit) are parametrized by the space CP1∼S2, the Bloch sphere. A spin j for a generic j (a 2j+1-state system) is represented instead by a point in a larger space, CP2j. Here we study the state of a single angular momentum/spin in the limit j→∞. A special class of states, |j,n⟩∈CP2j, with spin oriented towards definite spatial directions, n∈S2, i.e., (J^·n)|j,n⟩=j|j,n⟩, are found to behave as classical angular momenta, jn, in this limit. Vice versa, general spin states in CP2j do not become classical, even at a large j. We study these questions by analyzing the Stern–Gerlach processes, the angular momentum composition rule, and the rotation matrix. Our observations help to better clarify how classical mechanics emerges from quantum mechanics in this context (e.g., with the unique trajectories of a particle carrying a large spin in an inhomogeneous magnetic field) and to make the widespread idea that large spins somehow become classical more precise.
Quantum states of a spin
21 (a qubit) are parametrized by the space
CP1∼S2, the Bloch sphere. A spin
j for a generic
j (a
2j+1-state system) is represented instead by a point of a larger space,
CP2j. Here we study the state of a single angular momentum/spin in the limit,
j→∞. The special class of states $ | j, {\mathbf n}\rangle \in {\mathbf {CP}}^{2j} $, with spin oriented towards definite spatial directions
n∈S2, i.e., $({\mathbf J}\cdot {\mathbf n} ) \, | j, {\mathbf n}\rangle = j\, |j, {\mathbf n}\rangle $, are found to behave as classical angular momenta,
jn, in this limit. Vice versa, general spin states in
CP2j do not become classical, even at large
j. We discuss these questions, by analysing the Stern-Gerlach processes, the angular-momentum composition rule, and the rotation matrix. Our observations help to clarify better how classical mechanics emerges from quantum mechanics in this context (e.g., with unique trajectories for a particle carrying a large spin), and to make the widespread idea that large spins somehow become classical, more precise.
Quantization of spin and orbital angular momenta in standard quantum mechanics is rooted in the fundamental rotational symmetry of space in conjunction with the results of experiments on atomic and subatomic particles conducted with the Stern-Gerlach apparatus. We explain some of the most important features of spin and orbital angular momenta as inescapable consequences of elementary Stern-Gerlach experiments viewed in light of the rotational symmetry of space. The rotation operator is first derived for spin-½ particles, then extended to spin-1 particles by treating the case of a hydrogen atom in its ground state, where the spin of the proton combines with that of the electron to create a spin-1 triplet state. Along the way, we examine the evolution of a particle’s spin state under an applied magnetic field, where the interaction energy arises from the existence of a magnetic dipole moment for each particle in proportion to its spin angular momentum. Whereas a constant magnetic field B0 causes the particle’s magnetic moment to gyrate around the direction of B0, it will be seen that the presence of a small oscillating magnetic field perpendicular to B0 brings about the so-called Rabi oscillations, which involve periodic flippings of the particle’s spin orientation. In the case of a hydrogen atom in its ground state, the interaction between the magnetic dipole moments of the proton and the electron splits the ground state between a lower energy singlet having a net angular momentum of zero (spin-0 state), and a higher energy triplet having a total angular momentum of ħ (spin-1 state). This hyperfine splitting is the source of the well-known 21-cm line observed in the spectrum of the hydrogen atom, which arises from transitions between the atom’s singlet and triplet states. In the final section, we put forward an argument (originally made by Richard Feynman) that ties the rotational symmetry of space to the conservation of angular momentum in quantum mechanics. The argument is, in fact, quite general, enabling one to deduce other conservation laws from various inherent symmetries of quantum mechanical systems.
The standard description of the state of a spin in quantum mechanics presupposes externally fixed directions -- a classical background. Can a spin be fully described instead in relation to other quantum mechanical systems? Poulin suggested twenty years ago group averaging over rotations the joint state of a fundamental spin and a reference spin with large angular momentum which, however, yields a classical bit in a probabilistic mixture. We revisit this idea and show that when the quantum reference system is augmented to \emph{two} large spins, the standard quantum mechanical description of a spin is recovered in the limit of large quantum numbers for the reference system.
This chapter presents key results on angular momentum in quantum mechanics, beginning with a theorem on the simultaneous diagonalization of commuting operators. The eigenvalues and eigenstates of both the total angular momentum operator and its z-component are derived. For a quantum rotator in the p-state with zero magnetic quantum number, it is shown that the most probable trajectory lies in a plane containing the z-axis, and the angular momentum vector is perpendicular to it. The procedure for angular momentum addition is explained in detail, including the use of Clebsch–Gordan coefficients to perform the explicit decomposition of tensor products of irreducible representations. The Bloch sphere representation of qubit spin states is introduced. The chapter then provides an experimental background to the discovery of spin, introduces the Pauli matrices, and demonstrates how they act on spin states. It concludes with the formulation of the Pauli equation, which incorporates spin into the framework of nonrelativistic quantum mechanics. Metadata/Keywords: angular momentum, simultaneous diagonalization, magnetic quantum number, Clebsch–Gordan coefficients, spin, Pauli matrices, Bloch sphere, spin states, tensor product, Pauli equation
Abstract Angular momentum in classical mechanics is given by a vector. The plane perpendicular to this vector, in accordance to central field theory, determines the space in which particle motion takes place. No such simple picture exists in quantum mechanics. The states of a particle in a central field are proportional to spherical harmonics which do not define any plane of motion. In the first part of this paper we discuss the angular distribution of particle position and compare it to the classical probabilistic approach. In the second part, the matter of addition of angular momenta is discussed. In classical mechanics this means addition of vectors, while in quantum mechanics Clebsch–Gordan coefficients have to be used. We have found classical approximations to quantum coefficients and the limit of their applicability. This analysis gives a basis for the so-called ‘vector addition model’ used in some elementary textbooks on atomic physics. It can help to better understand the addition of angular momenta in quantum mechanics.
This chapter analyses the orbital angular momentum to three dimensions and introduces the spin angular momentum of the electron. The description of a localized particle in orbit requires a superposition of eigenfunctions analogous to the packet state that describes motion in one dimension. If the distance between molecules is fixed, all the energy changes are rotational kinetic energy changes, and the quantization of total angular momentum gives rise to discrete rotational energy levels. The analysis of orbital angular momentum is a powerful tool for describing molecular rotation. The Stern-Gerlach experiment and many other lines of evidence show that the measured magnetic moment associated with an electron spin is almost exactly one Bohr magneton. When orbital angular momentum and spin angular momentum both exist in the same atom, the magnetic moments that result from orbital and spin angular momenta interact to cause a splitting in the corresponding energy level.