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Entropy

Motion of Quantum Particles in Terms of Probabilities of Paths

Emilio Santos

Published Jul 6, 2025• 2 citations
Publisher

Abstract

The Feynman path integral formalism for non-relativistic quantum mechanics is revisited. A comparison is made with cases of light propagation (Huygens' principle) and Brownian motion. The difficulties for a physical model applying Feynman's formalism are pointed out. A reformulation is proposed, where the transition probability of a particle from one space-time point to another one is the sum of probabilities of the possible paths. As an application, Born approximation for scattering is derived within the formalism, which suggests an interpretation involving the stochastic motion of a particle rather than the square of a wavelike amplitude.

DOI
10.3390/e27070728

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The Feynman path integral formalism for non-relativistic quantum mechanics is revisited. A comparison is made with cases of light propagation (Huygens' principle) and Brownian motion. The difficulties for a physical model applying Feynman's formalism are pointed out. A reformulation is proposed, where the transition probability of a particle from one space-time point to another one is the sum of probabilities of the possible paths. As an application, Born approximation for scattering is derived within the formalism, which suggests an interpretation involving the stochastic motion of a particle rather than the square of a wavelike amplitude.
Abstract Feynman developed the path integral approach to quantum mechanics as an alternative to wave or matrix mechanics that has found fruitful implementation in quantum mechanics, quantum electrodynamics, and statistical physics. Despite its many successes, the usual Feynman path integral formalism suffers from a lack of mathematical rigor. Questions of mathematical rigor still exist, but Mark Kac provided a rigorous path integral approach to quantum mechanics. The Kac formulation for quantum systems is given in terms of Wiener measure for a path integral and employs the Brownian motion distribution. In this paper, we review the Feynman–Kac approach and other stochastic processes related to Brownian motion. We also give an account of the successes and difficulties we faced during our journey through numerical path integral problems involved in physics.
The conventional approach to quantum mechanics begins with the classical Hamiltonian and changes observables to noncommuting operators. Canonically conjugate observables have to be noncommuting operators in order to satisfy the Heisenberg uncertainty principle. The dynamics of a quantum mechanical system is given by the time-dependent Schrödinger equation. In the early 1940s Feynman realized that it would be possible to construct a quantum model using the classical Lagrangian approach (a method closely related to the action integral). Dirac had earlier pointed out that eit times the Lagrangian was analogous to a transformation function for the wave function in which the wave function at one instant could be related to the wave function at a next instant in a time interval of t by multiplying with such an exponential function. Feynman found the exponential phase factor to be the action S which is the time integral of the Lagrangian. Further, he noticed that it was necessary to perform integrals over all space variables at every instant of time to find the transition amplitudes. He developed a way for describing and evaluating the integration using the idea of integral over all paths. In Feynman’s approach, the particles are described using amplitudes calculated along the paths they may or may not follow. These amplitudes behave like waves, their phase changes as the quantum system moves along the path and the amplitudes for all paths superpose and interfere. This interference between all paths is called as sum-over-histories and the resulting amplitude is connected in the same way that the amplitude of a wave function is linked to probability as magnitude-squared.
In this thesis we are investigating a different formalism of non-relativistic quantum mechanics called the path integral formalism.It is a generalization of the classical least action principle.The introduction to this subject begins with the construction of the path integral in terms of the idea of probability amplitudes whose absolute square gives the probability of finding a system in a particular state.Then we show that if the Lagrangian is a quadratic form one needs only to calculate the classical action besides from a time-dependent normalization constant to find the explicit expression of the path integral.We look in to the subject of two kinds of slit-experiments: The square slit, the single-and the double-Gaussian slit.Also, the propagator for constrained paths is calculated and applied to the Aharonov-Bohm effect, which shows that the vector potential defined in classical electrodynamics have a physical meaning in quantum mechanics.It is also shown that the path integral formulation is equivalent to the Schrödinger description of quantum mechanics, by deriving the Schrödinger equation from the path integral.Further applications of the path integral are discussed.
In this thesis we are investigating a different formalism of non-relativistic quantum mechanics called the path integral formalism. It is a generalization of the classical least action principle. The introduction to this subject begins with the construction of the path integral in terms of the idea of probability amplitudes whose absolute square gives the probability of finding a system in a particular state. Then we show that if the Lagrangian is a quadratic form one needs only to calculate the classical action besides from a time-dependent normalization constant to find the explicit expression of the path integral. We look in to the subject of two kinds of slit-experiments: The square slit, the single- and the double-Gaussian slit. Also, the propagator for constrained paths is calculated and applied to the Aharonov-Bohm effect, which shows that the vector potential defined in classical electrodynamics have a physical meaning in quantum mechanics. It is also shown that the path integral formulation is equivalent to the Schrödinger description of quantum mechanics, by deriving the Schrödinger equation from the path integral. Further applications of the path integral are discussed.
We show that the quantum-mechanical probability distribution involving complex probability amplitudes can be derived from three natural conditions imposed on a relativistically invariant probability function describing the motion of a particle that can take multiple paths simultaneously. The conditions are: (i) pairwise Kolmogorov additivity, (ii) time symmetry, and (iii) Bayes' rule. The resulting solution, parameterized by a single constant, is the squared modulus of a sum of complex exponentials of the relativistic action, thereby recovering the Feynman path-integral formulation of quantum mechanics.
A path , in general, is defined by a determinate trajectory in time, from an initial to a final point. The classical trajectory is only one of the possible trajectories, and in quantum mechanics all the possible paths between the initial and final point come into play. Recall that the probability amplitude is a complex number that is assigned to each determinate path. Indeterminate paths are defined as a collection of determinate paths that are experimentally indistinguishable . In the Dirac–Feynman approach, the inherent indeterminacy of the quantum entity is realized by the degree of freedom – in undergoing time evolution – “taking” indeterminate paths [Baaquie (2013e)]. For a quantum degree of freedom evolving from an observed initial state to the observed final state – and with no other observations made – the Feynman path integral is a mathematical construction that computes the probability amplitudes by summing over all the allowed determinate paths of the degree of freedom – discussed in Feynman and Hibbs (1965), Zinn-Justin (1993), Zinn-Justin (2005) and Baaquie (2013e). Probability amplitude and time evolution Recall that the description of a quantum system, at a particular instant,isgiven by its state vector, namely |ψ>. To avoid confusion with the concept of a state vector, the term probability amplitude is used for describing a quantum entity undergoing transitions in time.