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Proceedings of the Indian National Science Academy

Reservoir approach, Bose’s derivation, and Einstein’s rate equation approximation

Julie Saikia, Manas Protim Saikia, Rajib Kumar Dubey, A. Dahal, K. G. Singha, Gauranga Dhar Baruah

Published Jul 4, 2025• 0 citations
Publisher
DOI
10.1007/s43538-025-00480-5

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Photo-excited excitons, i.e. closely bound electron-hole pairs, are in the low-density regime approximately bosons. For sufficiently low temperatures and sufficiently high densities of the exciton gas, a nonequilibrium phase transition in the form of a Bose-Einstein condensation (BEC) can be expected. Various levels of the description of the kinetics of relaxation and condensation due to the coupling of the excitons to a cold reservoir of acoustic phonons are discussed. For noninteracting excitons a rate equation approach with the exciton Boltzmann equation can be used. For interacting excitons the nonmarkovian quantum kinetics is required for the description of the BEC in order to incorporate the changes of the energy spectrum during the condensation self-consistently. Finally colored Langevin fluctuations can be used to calculate the phase diffusion of the condensate.
We study nonequilibrium cascades in which fragile bound or coherent structures are formed through intermediate states rather than by direct equilibration. Motivated by light-nuclei production in relativistic heavy-ion collisions and by Bose--Einstein condensation in cosmological settings, we analyze such processes within the Schwinger--Keldysh real-time formalism. We show that commonly used rate equations can be understood as a controlled Markovian approximation obtained by integrating out intermediate reservoirs in an underlying multi-component nonequilibrium dynamics. When the finite lifetime of these reservoirs is retained, non-Markovian memory effects naturally appear, leading to delayed and history-dependent formation dynamics. The associated memory time provides a quantitative criterion for the validity of reduced, rate-based descriptions far from equilibrium.