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Journal of Experimental and Theoretical Physics Letters

Quantum Entanglement in Quasi-Equilibrium States in the Multipulse Spin Locking of the Nuclear Magnetic Resonance

G. A. Bochkin, Sergey G. Vasil’ev, E. I. Kuznetsova, Edward B. Fel’dman

Published Apr 1, 2025• 1 citation
Publisher

Abstract

Quantum entanglement is studied NMR multipulse spin locking, when a system of spins coupled by the dipole–dipole interaction in a strong magnetic field is irradiated by a sequence of resonant high-frequency $$\varphi $$ -pulses with the same time delay $$2\tau $$ between successive pulses. For times $$t \sim {{T}_{2}}$$ ( $${{T}_{2}} \approx \omega _{{{\text{loc}}}}^{{ - 1}}$$ , $${{\omega }_{{{\text{loc}}}}}$$ is determined by the dipole–dipole interaction), quasi-equilibrium with a structure depending on the relation between the pulsed field $${{\omega }_{1}} = \varphi {\text{/}}2\tau $$ and $${{\omega }_{{{\text{loc}}}}}$$ is established in the system. For $${{\omega }_{1}} \lessapprox {{\omega }_{{{\text{loc}}}}}$$ , a one-temperature quasi-equilibrium state arises, while a quasi-equilibrium with the dipole and Zeeman temperatures appears for $${{\omega }_{1}} \gg {{\omega }_{{{\text{loc}}}}}$$ . The temperature dependence of entanglement is investigated for $${{\omega }_{1}} \lessapprox {{\omega }_{{{\text{loc}}}}}$$ . For $${{\omega }_{1}} \gg {{\omega }_{{{\text{loc}}}}}$$ , the further evolution of the system is determined by the Provotorov equations and leads to the equalization of the dipole and Zeeman temperatures. It is shown that the entanglement is absent in this case.

DOI
10.1134/s002136402560572x

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We investigate analytically and numerically the multiple-quantum (MQ) NMR dynamics in systems of nuclear spins 1∕21∕21∕2 coupled by the dipole-dipole interactions in the case of the dipolar ordered initial state. We suggest two different methods of MQ NMR. One of them is based on the measurement of the dipolar temperature in the quasiequilibrium state which is established after the time of order ${\ensuremath{\omega}}_{\mathit{loc}}^{\ensuremath{-}1}$ (${\ensuremath{\omega}}_{\mathit{loc}}$ is the dipolar local field) after the MQ NMR experiment. The other method uses an additional resonance ${(\ensuremath{\pi}∕4)}_{y}$ pulse after the preparation period of the standard MQ NMR experiment in solids. Many-spin clusters and correlations are created faster in such experiments than in the usual MQ NMR experiments and can be used for the investigation of many-spin dynamics of nuclear spins in solids.
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We investigate analytically and numerically the multiple-quantum (MQ) NMR dynamics in systems of nuclear spins 1/2 coupled by dipole-dipole interactions in the case of the dipolar-ordered initial state. We suggest a new method of MQ NMR based on the measurement of the dipolar temperature in the quasi-equilibrium state, which establishes after the time of order ω loc −1 (ωloc is the dipolar local field) after the MQ NMR experiment. Manyspin clusters and correlations are created faster in such an experiment than in usual MQ NMR experiments and can be used for the investigation of the many-spin dynamics of nuclear spins in solids.
In this paper we study the influence of pulse NMR on the usefulness of the entanglement in a two-qubit XXZ chain at different temperatures of the Zeeman and dipole-dipole reservoirs as resource for quantum teleportation via the standard teleportation protocol. We show that the nonzero entanglement produced at a high temperature and the initial polarization exceeding some threshold value after a (π/2)y pulse of RF field is an useful resource. We also report on the exact calculation of the necessary and sufficient conditions of entanglement for an ensemble of spin pairs under non-equilibrium states.