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Physical review. B./Physical review. B

Quantum phase transitions beyond critical exponents: Microscopic scales and universal role of the Planckian time

Andrey Rogachev

Published Apr 8, 2025• 1 citation
Publisher

Abstract

Over the past four decades, experimental studies of quantum phase transitions (QPTs) have been primarily focused on identifying these transitions in various materials and determining the critical exponents and universality classes associated with them. Since the critical exponents originate from the scale invariance, they are not explicitly tied to the microscopic physics of QPTs, which remains poorly understood for many systems. We have developed a model of QPTs, which addresses this deficiency. The model is based on the experimentally supported conjecture that the scaled data across a QPT depend, in a universal manner, on two system-specific length scales: the microscopic scale, ${L}_{0}$, typically known from general considerations (e.g., mean-free path, lattice constant) and the dephasing length, ${L}_{\ensuremath{\varphi}}(T)$. Using this model, we have found that experimental data in the quantum critical regime of 18 distinct material classes can be quantitatively described by assuming that ${L}_{\ensuremath{\varphi}}(T)$ is determined by the distance traveled by system-specific excitations during the Planckian time, ${\ensuremath{\tau}}_{P}=\ensuremath{\hbar}/{k}_{B}T$. In this work, we demonstrate how the model explains microscopic physics of QPTs in doped semiconductors and amorphous alloys, materials with Ising and Heisenberg spin chains, cold boson gases in optical traps, and the Mott transitions in organic semiconductors. The dynamics of excitations is determined by parameters such as the effective mass and diffusion coefficient, $D$, of the corresponding noninteracting or weakly renormalized system. For doped semiconductors and amorphous alloys, the noncritical behavior of $D$ in the quantum critical regime sharply contrasts with zero-temperature diffusion coefficient, which goes to zero at the transition. We also analyze the results of numerical studies of the Mott transition with dynamical mean-field theory, interpreting them as if they were experimental data. For these results, we find that, as expected, the microscopic scale matches the dimensionless lattice constant, ${L}_{0}\ensuremath{\sim}1$. Finally, we report that the metal-insulator transition in Si:P, Ge:Sb, and Ge:As can be explained using a noninteracting version of the model.

DOI
10.1103/physrevb.111.165111

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Over the past four decades, experimental studies of quantum phase transitions (QPTs) have been primarily focused on identifying these transitions in various materials and determining the critical exponents and universality classes associated with them. Since the critical exponents originate from the scale invariance, they are not explicitly tied to the microscopic physics of QPTs, which remains poorly understood for many systems. We have developed a model of QPTs, which addresses this deficiency. The model is based on the experimentally supported conjecture that the scaled data across a QPT depend, in a universal manner, on two system-specific length scales: the microscopic scale, L0{L}_{0}L0​, typically known from general considerations (e.g., mean-free path, lattice constant) and the dephasing length, L\ensuremathφ(T){L}_{\ensuremath{\varphi}}(T)L\ensuremathφ​(T). Using this model, we have found that experimental data in the quantum critical regime of 18 distinct material classes can be quantitatively described by assuming that L\ensuremathφ(T){L}_{\ensuremath{\varphi}}(T)L\ensuremathφ​(T) is determined by the distance traveled by system-specific excitations during the Planckian time, \ensuremathτP=\ensuremathℏ/kBT{\ensuremath{\tau}}_{P}=\ensuremath{\hbar}/{k}_{B}T\ensuremathτP​=\ensuremathℏ/kB​T. In this work, we demonstrate how the model explains microscopic physics of QPTs in doped semiconductors and amorphous alloys, materials with Ising and Heisenberg spin chains, cold boson gases in optical traps, and the Mott transitions in organic semiconductors. The dynamics of excitations is determined by parameters such as the effective mass and diffusion coefficient, DDD, of the corresponding noninteracting or weakly renormalized system. For doped semiconductors and amorphous alloys, the noncritical behavior of DDD in the quantum critical regime sharply contrasts with zero-temperature diffusion coefficient, which goes to zero at the transition. We also analyze the results of numerical studies of the Mott transition with dynamical mean-field theory, interpreting them as if they were experimental data. For these results, we find that, as expected, the microscopic scale matches the dimensionless lattice constant, L0\ensuremath∼1{L}_{0}\ensuremath{\sim}1L0​\ensuremath∼1. Finally, we report that the metal-insulator transition in Si:P, Ge:Sb, and Ge:As can be explained using a noninteracting version of the model.
In the vicinity of continuous quantum phase transitions (QPTs), quantum systems become scale-invariant and can be grouped into universality classes characterized by sets of critical exponents. We have found that despite scale-invariance and universality, the experimental data still contain information related to the microscopic processes and scales governing QPTs. We have found that for many systems, the scaled data near QPTs can be approximated by the generic exponential dependence introduced in the scaling theory of localization; this dependence includes as a parameter a microscopic seeding scale of the renormalization group, L0L_0L0​. We have also conjectured that for interacting systems, the temperature cuts the renormalization group flow at the length travelled by a system-specific elementary excitation over the life-time set by the Planckian time, τPτ_PτP​=ℏ/kBT\hbar/k_BTℏ/kB​T. We have adapted this approach for QPTs in several systems and showed that L0L_0L0​ extracted from experiment is comparable to physically-expected minimal length scales, namely (i) the mean free path for metal-insulator transition in doped semiconductor Si:B, (ii) the distance between spins in Heisenberg and Ising chains, (iii) the period of an optical lattice for cold atom boson gases, and (iv) the period of a moiré superlattice for the Mott QPT in dichalcogenide bilayers. The metal-insulator transition in Si:P has been explained using a non-interacting version of the model. In two companion papers, we show that in superconducting systems, L0L_0L0​ is comparable to superconducting coherence length, and in quantum Hall systems, to the magnetic length. The developed new method of data analysis identifies microscopic processes leading to QPTs and quantitatively explains and unifies a large body of experimental data.
Transformations between the plateau states of the quantum Hall effect (QHE) are an archetypical example of quantum phase transitions (QPTs) between phases with non-trivial topological order. These transitions appear to be well-described by the single-particle network theories. The long-standing problem with this approach is that it does not account for Coulomb interactions. In this paper, we show that experimental data in the quantum critical regime for both integer and fractional QHEs can be quantitatively explained by the recently developed phenomenological model of QPTs in interacting systems. This model assumes that all effects of interactions are contained in the life-time of fluctuations as set by the Planckian time τP=ℏ/kBTτ_P=\hbar/k_BTτP​=ℏ/kB​T. The dephasing length is taken as the distance traveled by a non-interacting particle along the bulk edge state over this time. We show that the model also provides quantitative description of QPTs between the ground states of anomalous QHE and axion and Chern insulators. These analyzed systems are connected in that the QPTs occur via quantum percolation. Combining the presented results with the results of two companion papers, we conclude that the Planckian time is the encompassing characteristic of QPTs in interacting systems, independent of dimensionality and microscopic physics.
Anatoli Polkovnikov Department of Physics, Boston University, 590 Commonwealth Ave., Boston, MA 02215, U.S.A. Vladimir Gritsev Physics Department, University of Fribourg, Chemin du Musee 3, 1700 Fribourg, Switzerland Continuous quantum phase transitions (QPTs) have been a subject of intense theoretical research in recent decades (see, e.g., Refs. [1-3] for overview). Unlike usual phase transitions driven by temperature, QPTs are driven entirely by quantum fluctuations. They are believed to occur in many situations as described later in this book. Quite recently a second order QPT was observed in a cold atom system of interacting bosons in an optical lattice. There a system of interacting bosons was driven in real time from the superfluid to the insulating phase [4], confirming an earlier theoretical prediction [5]. Up till now, Ref. [4] has provided probably the cleanest experimental confirmation of a QPT. The unifying property of all continuous (second order) phase transitions is the emergent universality and scale invariance of the long-distance low energy properties of the system near the quantum critical point (QCP) [1]. This universality implies that low-energy properties of the system can be described by very few parameters, like the correlation length or the gap, which typically have power-law scaling with the tuning parameter characterized by critical exponents. These exponents are not sensitive to the microscopic details of the Hamiltonian describing the system, but rather depend only on the universality class to which a given phase transition belongs [1].
The superconducting ground state in many two-dimensional materials can be created or destroyed through quantum phase transitions (QPTs) controlled by non-thermal parameters such as carrier density or magnetic field. While various mechanisms for these QPTs have been proposed, it remains unclear which, if any, are applicable to a specific two-dimensional superconducting system. Here, we find that a pair-breaking mechanism which suppresses the Cooper pair density gives a unifying description of magnetic-field-driven QPTs in amorphous MoGe, Pb and TaN films, and the high-temperature superconductor La1.92_{1.92}1.92​Sr0.08_{0.08}0.08​CuO4_{4}4​. This transition occurs within the superconducting subsystem and is masked by the dominant non-critical contribution of normal electrons. The discovery was enabled by the development of a QPT model that goes beyond the conventional determination of the critical exponents and incorporates into the analysis a microscopic length scale characterizing the transitions. We found that in the materials studied, and MoGe nanowires, this scale corresponds to the size of a Cooper pair. The model has also been successfully applied to QPTs in Josephson junction arrays and various non-superconducting materials. The observation that microscopic scales are encoded in the scaled experimental data of QPTs likely extends beyond equilibrium condensed matter physics and may reveal underlying principles of critical phenomena in a wide variety of systems.
Quantum phase transition arises in general as second order phase transition at zero temperature, tuned by a non-thermal parameter such as pressure, doping or a magnetic field. The point in the phase diagram of the material in which different phases meet is called a quantum critical point (QCP). Physics around QCPs are of extensive current interest because the critical quantum fluctuations influence the physical properties in a wide temperature range (quantum criticality), and are believed to be responsible for many emergent physical properties such as non-Fermi liquids and unconventional superconductivity. In this research we explore dynamics and thermodynamics near QCPs via investigating three classes of models, which all have real material correspondence. Specifically first, we study local dynamics in a perturbed quantum critical Ising chain with E8 symmetry, where we show the local dynamical spin susceptibility has a singular dependence on frequency, but differs from the diffusion form. The nuclear magnetic resonance (NMR) relaxation rate at low temperatures depends exponentially on the inverse temperature, whose prefactor we also determine. We propose NMR experiments as a means to further test the applicability of the E8 description for CoNb2O6. Second, we investigate the thermodynamic properties of itinerant ferromagnets near quantum critical points, described by the quantum Landau-Ginzburg theory. We provide a regularized perturbative renormalization group procedure to calculate the free energy. We further carry out numerical calculations on thermodynamic quantities, capturing not only the leading critical behaviors, but also the subleading and nonsingular contributions. We demonstrate various thermodynamic signatures of quantum criticality, including the entropy accumulation effect and the divergence of the specific heat coefficient. A detailed comparison to the recent experimental results on an itinerant ferromagnet Sr3Ru2O7 is also presented. Third, we explore Ising-nematic and magnetic phases and their transitions in iso-electronically doped iron pnictides by carrying out a large-N study of an effective low-energy Ginzburg-Landau model for these systems. We demonstrate that the magnetic and Ising orders transitions are concurrent at zero temperature, and both transitions are weakly first-order, which is consistent with RG-based prediction and experimental observations.
Classical and quantum spin systems are widely used models in both experimental and theoretical condensed matter physics. In many materials, the electronic interactions can be difficult to model exactly. However, in some insulators (Mott insulators), the magnetic (spin) interactions can be captured well with spin-only models. Several models are studied in this thesis. First, I report the solution of a long-standing issue in a classical frustrated spin model (i.e., where the quantum effects are neglected and the complexity is due to competing interactions): the nature of the thermal phase transition to a stripe state in the two dimensional (2D) J1-J2 model. Here J1 and J2 are nearest- and next-nearest-neighbor couplings. Monte Carlo simulations with single-spin updates are used for the calculations, and an extended-ensemble method, a generalization of the Wang-Landau algorithm, is also developed and tested. I focus on the study of "weak universality" behavior (continuously varying critical exponents, with one of the exponents staying fixed), for which I show a correspondence with a known class of conformal field theories with charge c = 1. Next, moving to quantum spins, to shed light on magnetic systems studied experimentally and to investigate new types of quantum states of interest in developing theories of quantum magnetism, I study the S = 1/2 Heisenberg model on the 2D square lattice with added six-spin interactions (the so-called J-Q3 model) as well as a set of 3D quantum antiferromagnets on dimerized lattices. Here I use the stochastic series expansion quantum Monte Carlo method. In the study of the J-Q3 model, I report on a similar weak-universality behavior as in the classical J1-J2 model, but with a mapping to a different known class of c = 1 conformal field theories. The critical behavior of the system again shows continuously changing exponents, in a way which corresponds to a gradual weakening of Z4 symmetry-breaking to an emergent U(1) symmetry. In the study of dimerized antiferromagnets, I report on a universal behavior of the Néel temperature TN, which can be related to ground state parameters independently of the microscopic interaction details in several different models.