Anatoli Polkovnikov Department of Physics, Boston University, 590 Commonwealth Ave., Boston, MA 02215, U.S.A. Vladimir Gritsev Physics Department, University of Fribourg, Chemin du Musee 3, 1700 Fribourg, Switzerland Continuous quantum phase transitions (QPTs) have been a subject of intense theoretical research in recent decades (see, e.g., Refs. [1-3] for overview). Unlike usual phase transitions driven by temperature, QPTs are driven entirely by quantum fluctuations. They are believed to occur in many situations as described later in this book. Quite recently a second order QPT was observed in a cold atom system of interacting bosons in an optical lattice. There a system of interacting bosons was driven in real time from the superfluid to the insulating phase [4], confirming an earlier theoretical prediction [5]. Up till now, Ref. [4] has provided probably the cleanest experimental confirmation of a QPT. The unifying property of all continuous (second order) phase transitions is the emergent universality and scale invariance of the long-distance low energy properties of the system near the quantum critical point (QCP) [1]. This universality implies that low-energy properties of the system can be described by very few parameters, like the correlation length or the gap, which typically have power-law scaling with the tuning parameter characterized by critical exponents. These exponents are not sensitive to the microscopic details of the Hamiltonian describing the system, but rather depend only on the universality class to which a given phase transition belongs [1].
Anatoli Polkovnikov Department of Physics, Boston University, 590 Commonwealth Ave., Boston, MA 02215, U.S.A. Vladimir Gritsev Physics Department, University of Fribourg, Chemin du Musee 3, 1700 Fribourg, Switzerland Continuous quantum phase transitions (QPTs) have been a subject of intense theoretical research in recent decades (see, e.g., Refs. [1-3] for overview). Unlike usual phase transitions driven by temperature, QPTs are driven entirely by quantum fluctuations. They are believed to occur in many situations as described later in this book. Quite recently a second order QPT was observed in a cold atom system of interacting bosons in an optical lattice. There a system of interacting bosons was driven in real time from the superfluid to the insulating phase [4], confirming an earlier theoretical prediction [5]. Up till now, Ref. [4] has provided probably the cleanest experimental confirmation of a QPT. The unifying property of all continuous (second order) phase transitions is the emergent universality and scale invariance of the long-distance low energy properties of the system near the quantum critical point (QCP) [1]. This universality implies that low-energy properties of the system can be described by very few parameters, like the correlation length or the gap, which typically have power-law scaling with the tuning parameter characterized by critical exponents. These exponents are not sensitive to the microscopic details of the Hamiltonian describing the system, but rather depend only on the universality class to which a given phase transition belongs [1].
Aim and Scope of this Book A plethora of systems exhibit phase transitions as the temperature or some other parameter is changed. Examples range from the ice-water phase transition observed in our daily life to the loss of ferromagnetism in iron or to the more sophisticated Mott insulator-superfluid phase transition observed in optical lattices [343]. The last five decades have witnessed a tremendous upsurge in the studies of phase transitions at finite temperature [727, 149, 333, 136, 494, 541, 556]. The success of Landau-Ginzburg theories and the concepts of spontaneous symmetry breaking and the renormalization group [27, 410, 821, 578] in explaining many of the finite temperature phase transitions occurring in nature has been spectacular. In this book, we will consider only a subclass of phase transitions called quantum phase transitions (QPTs) [154, 658, 725, 799, 185, 63, 62, 66, 141, 744] and we will discuss these mainly from the view point of recent studies of information and dynamics. QPTs are zero temperature phase transitions which are driven by quantum fluctuations and are usually associated with a non-analyticity in the ground state energy density of a quantum many-body Hamiltonian. We will focus on continuous QPTs where the order parameter vanishes continuously at the quantum critical point (QCP) at some value of the parameters which characterize the Hamiltonian. We will not discuss first order quantum phase transitions associated with an abrupt change in the order parameter. Usually, a first order phase transition is characterized by a finite discontinuity in the first derivative of the ground state energy density. A continuous QPT is similarly characterized by a finite discontinuity, or divergence, in the second derivative of the ground state energy density, assuming that the first derivative is continuous. This is of course the classical definition; we will later mention some QPTs where the ground state energy density is not necessarily singular.
Quantum Phase Transitions Quantum phase transitions, in contrast to temperature-driven critical phenomena, occur due to a competition between different parameters describing the basic interactions of the system. Their specific feature is the quantum character of the critical fluctuations. This implies, through the uncertainty principle, that energy fluctuations and time are coupled. Then at zero temperature time plays a crucial and fundamental role, the static properties being entangled with the dynamics (Continentino, 1994a; Sondhi et al ., 1997; Sachdev, 1999). In this book we are mainly interested in quantum phase transitions that occur in electronic many-body systems and how scaling concepts can be useful to understand their properties close to these transitions (Continentino, 1994a). Even though a similar approach has been used in the case of interacting bosons (Fisher et al ., 1989) the fermionic problem has its own idiosyncrasies and difficulties. For example, there is no natural order parameter associated with the localisation transition in the electronic case, while bosons at zero temperature are either localised or superfluid so that the superfluid order parameter can be used to distinguish between both phases. If the results of the study of quantum phase transitions were restricted to zero temperature, this would be an interesting but purely academic area of research. What is really exciting about this subject is the effect of quantum critical points (QCP) in the finite temperature phase diagram of actual physical systems, even far away from the QCP (Freitas, 2015). As we will show, there is a special line in this phase diagram, the quantum critical trajectory , where the temperature dependence of the thermodynamic and transport properties is governed by the quantum critical exponents, i.e. those associated with the QCP. This and the observed crossover effects induced by temperature in the non-critical side of the phase diagram of a material with a QCP are sufficient to make the study of quantum phase transitions an inevitable subject. We start this chapter by introducing the scaling theory of quantum critical phenomena, since scaling concepts are used throughout this book.
In the vicinity of continuous quantum phase transitions (QPTs), quantum systems become scale-invariant and can be grouped into universality classes characterized by sets of critical exponents. We have found that despite scale-invariance and universality, the experimental data still contain information related to the microscopic processes and scales governing QPTs. We have found that for many systems, the scaled data near QPTs can be approximated by the generic exponential dependence introduced in the scaling theory of localization; this dependence includes as a parameter a microscopic seeding scale of the renormalization group, L0. We have also conjectured that for interacting systems, the temperature cuts the renormalization group flow at the length travelled by a system-specific elementary excitation over the life-time set by the Planckian time, τP=ℏ/kBT. We have adapted this approach for QPTs in several systems and showed that L0 extracted from experiment is comparable to physically-expected minimal length scales, namely (i) the mean free path for metal-insulator transition in doped semiconductor Si:B, (ii) the distance between spins in Heisenberg and Ising chains, (iii) the period of an optical lattice for cold atom boson gases, and (iv) the period of a moiré superlattice for the Mott QPT in dichalcogenide bilayers. The metal-insulator transition in Si:P has been explained using a non-interacting version of the model. In two companion papers, we show that in superconducting systems, L0 is comparable to superconducting coherence length, and in quantum Hall systems, to the magnetic length. The developed new method of data analysis identifies microscopic processes leading to QPTs and quantitatively explains and unifies a large body of experimental data.
Over the past four decades, experimental studies of quantum phase transitions (QPTs) have been primarily focused on identifying these transitions in various materials and determining the critical exponents and universality classes associated with them. Since the critical exponents originate from the scale invariance, they are not explicitly tied to the microscopic physics of QPTs, which remains poorly understood for many systems. We have developed a model of QPTs, which addresses this deficiency. The model is based on the experimentally supported conjecture that the scaled data across a QPT depend, in a universal manner, on two system-specific length scales: the microscopic scale, L0, typically known from general considerations (e.g., mean-free path, lattice constant) and the dephasing length, ${L}_{\ensuremath{\varphi}}(T)$. Using this model, we have found that experimental data in the quantum critical regime of 18 distinct material classes can be quantitatively described by assuming that ${L}_{\ensuremath{\varphi}}(T)$ is determined by the distance traveled by system-specific excitations during the Planckian time, ${\ensuremath{\tau}}_{P}=\ensuremath{\hbar}/{k}_{B}T$. In this work, we demonstrate how the model explains microscopic physics of QPTs in doped semiconductors and amorphous alloys, materials with Ising and Heisenberg spin chains, cold boson gases in optical traps, and the Mott transitions in organic semiconductors. The dynamics of excitations is determined by parameters such as the effective mass and diffusion coefficient, D, of the corresponding noninteracting or weakly renormalized system. For doped semiconductors and amorphous alloys, the noncritical behavior of D in the quantum critical regime sharply contrasts with zero-temperature diffusion coefficient, which goes to zero at the transition. We also analyze the results of numerical studies of the Mott transition with dynamical mean-field theory, interpreting them as if they were experimental data. For these results, we find that, as expected, the microscopic scale matches the dimensionless lattice constant, ${L}_{0}\ensuremath{\sim}1$. Finally, we report that the metal-insulator transition in Si:P, Ge:Sb, and Ge:As can be explained using a noninteracting version of the model.
Properties of systems near quantum critical points (QCPs) have been studied extensively. A QCP is a point across which the symmetry of (e) the ground state of a quantum system changes (e&eb) in a fundamental way; such a point can be accessed by (e) changing some parameter, say λ, in the Hamiltonian governing the system. The change in the ground state across a QCP is mediated by (e&eb) quantum fluctuations. Unlike conventional thermal critical points, thermal fluctuations do not (e) play a crucial role in such transitions. Similar to its thermal counterparts, the low-energy physics near a QCP is associated with (e&*eb) a number of critical exponents which characterize (eb) the universality class of such a transition. Among these exponents,....... The full paper: http://www.iiste.org/PDFshare/APTA-PAGENO-414213-418614.pdf
Quantum phase transition arises in general as second order phase transition at zero temperature, tuned by a non-thermal parameter such as pressure, doping or a magnetic field. The point in the phase diagram of the material in which different phases meet is called a quantum critical point (QCP). Physics around QCPs are of extensive current interest because the critical quantum fluctuations influence the physical properties in a wide temperature range (quantum criticality), and are believed to be responsible for many emergent physical properties such as non-Fermi liquids and unconventional superconductivity. In this research we explore dynamics and thermodynamics near QCPs via investigating three classes of models, which all have real material correspondence. Specifically first, we study local dynamics in a perturbed quantum critical Ising chain with E8 symmetry, where we show the local dynamical spin susceptibility has a singular dependence on frequency, but differs from the diffusion form. The nuclear magnetic resonance (NMR) relaxation rate at low temperatures depends exponentially on the inverse temperature, whose prefactor we also determine. We propose NMR experiments as a means to further test the applicability of the E8 description for CoNb2O6. Second, we investigate the thermodynamic properties of itinerant ferromagnets near quantum critical points, described by the quantum Landau-Ginzburg theory. We provide a regularized perturbative renormalization group procedure to calculate the free energy. We further carry out numerical calculations on thermodynamic quantities, capturing not only the leading critical behaviors, but also the subleading and nonsingular contributions. We demonstrate various thermodynamic signatures of quantum criticality, including the entropy accumulation effect and the divergence of the specific heat coefficient. A detailed comparison to the recent experimental results on an itinerant ferromagnet Sr3Ru2O7 is also presented. Third, we explore Ising-nematic and magnetic phases and their transitions in iso-electronically doped iron pnictides by carrying out a large-N study of an effective low-energy Ginzburg-Landau model for these systems. We demonstrate that the magnetic and Ising orders transitions are concurrent at zero temperature, and both transitions are weakly first-order, which is consistent with RG-based prediction and experimental observations.