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CRC Press eBooks

Free-Electron Fermi Gas

D. C. Johnston

Published Mar 13, 2025• 1 citation
Publisher

Abstract

A free-electron Fermi gas is a gas of electrons with spin https://www.w3.org/1998/Math/MathML" display="inline"> S = 1 / 2 https://www.w3.org/1999/xlink" xlink:href=" https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003606857/19698a40-dbd9-4f9a-9cb7-890a1d39adce/content/math8_1.tif "/> . A fermion is a particle with half-integer spin S such as the electron. A boson is a particle with integer spin https://www.w3.org/1998/Math/MathML" display="inline"> S ≥ 0 https://www.w3.org/1999/xlink" xlink:href=" https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003606857/19698a40-dbd9-4f9a-9cb7-890a1d39adce/content/math8_2.tif "/> . By a gas is meant that there are no interactions between the particles making up the gas. Thus a Fermi gas can exhibit no phase transitions by itself. On the other hand, a free boson gas can exhibit an interesting quantum phase transition into a superfluid state, qualitatively similar to that of the superconducting state of a metal, called Bose-Einstein condensation . In contrast, an electron Fermi liquid would be a system containing electrons that do interact with each other. We will see in the last two chapters of this book that when such interactions occur, magnetic or superconducting transitions associated with the electrons can happen.

DOI
10.1201/9781003606857-8

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A free-electron Fermi gas is a gas of electrons with spin https://www.w3.org/1998/Math/MathML" display="inline"> S = 1 / 2 https://www.w3.org/1999/xlink" xlink:href=" https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003606857/19698a40-dbd9-4f9a-9cb7-890a1d39adce/content/math8_1.tif "/> . A fermion is a particle with half-integer spin S such as the electron. A boson is a particle with integer spin https://www.w3.org/1998/Math/MathML" display="inline"> S ≥ 0 https://www.w3.org/1999/xlink" xlink:href=" https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003606857/19698a40-dbd9-4f9a-9cb7-890a1d39adce/content/math8_2.tif "/> . By a gas is meant that there are no interactions between the particles making up the gas. Thus a Fermi gas can exhibit no phase transitions by itself. On the other hand, a free boson gas can exhibit an interesting quantum phase transition into a superfluid state, qualitatively similar to that of the superconducting state of a metal, called Bose-Einstein condensation . In contrast, an electron Fermi liquid would be a system containing electrons that do interact with each other. We will see in the last two chapters of this book that when such interactions occur, magnetic or superconducting transitions associated with the electrons can happen.
The ground state of a free electron gas corresponds to complete filling of the one-electron energy levels of wavevector k and energy ħ 2 k 2 /2m up to a certain energy E F = ћ 2 k F 2 / 2 m https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9780429497032/d2b0510a-8f84-4d3a-8776-dff0770e5b14/content/eq458.tif"/> (the Fermi energy). However, in the presence of an attractive interaction, no matter how weak, this state becomes unstable (Cooper, 1957). The instability can be understood by considering two particular electrons of coordinates r 1 and r 2 , the other electrons still being treated as a free electron gas. The only effect of this electron gas is to forbid the two electrons to occupy all states k < k F by the exclusion principle. Let ψ ( r 1 , r 2 ) be the wavefunction of the two electrons. Consider only states where the center of gravity of the pair ( r 1 , r 2 ) is at rest; ψ is then only a function of r 1 – r 2 . Expand ψ in plane waves ( 4-1 ) ψ ( r 1 − r 2 ) = ∑ k g ( k ) e i k ⋅ ( r 1 − r 2 ) https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9780429497032/d2b0510a-8f84-4d3a-8776-dff0770e5b14/content/eq459.tif"/>
The n -puzzle is a classical problem for modeling algorithms. For n -puzzle there are https://www.w3.org/1998/Math/MathML" display="inline"> n + 1 https://www.w3.org/1999/xlink" xlink:href=" https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003374404/4745344c-4074-4386-85e6-ca8a3849de1f/content/math10_1.tif "/> different objects: n cells and one empty cell. Each object can be coded by https://www.w3.org/1998/Math/MathML" display="inline"> ρ = ⌈ log 2 ⁡ n + 1 ⌉ https://www.w3.org/1999/xlink" xlink:href=" https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003374404/4745344c-4074-4386-85e6-ca8a3849de1f/content/math10_2.tif "/> qubits and a configuration of https://www.w3.org/1998/Math/MathML" display="inline"> n + 1 https://www.w3.org/1999/xlink" xlink:href=" https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003374404/4745344c-4074-4386-85e6-ca8a3849de1f/content/math10_3.tif "/> objects can be represented by a register of https://www.w3.org/1998/Math/MathML" display="inline"> z := ρ ⋅ ( n + 1 ) https://www.w3.org/1999/xlink" xlink:href=" https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003374404/4745344c-4074-4386-85e6-ca8a3849de1f/content/math10_4.tif "/> qubits https://www.w3.org/1998/Math/MathML" display="inline"> | x ⟩ https://www.w3.org/1999/xlink" xlink:href=" https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003374404/4745344c-4074-4386-85e6-ca8a3849de1f/content/math10_5.tif "/> . The function https://www.w3.org/1998/Math/MathML" display="inline"> g ( x ) https://www.w3.org/1999/xlink" xlink:href=" https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003374404/4745344c-4074-4386-85e6-ca8a3849de1f/content/math10_6.tif "/> is represented a unitary operator T . T acts on the https://www.w3.org/1998/Math/MathML" display="inline"> z + 1 https://www.w3.org/1999/xlink" xlink:href=" https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003374404/4745344c-4074-4386-85e6-ca8a3849de1f/content/math10_7.tif "/> qubits with https://www.w3.org/1998/Math/MathML" display="inline"> x ∈ B z https://www.w3.org/1999/xlink" xlink:href=" https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003374404/4745344c-4074-4386-85e6-ca8a3849de1f/content/math10_8.tif "/> and https://www.w3.org/1998/Math/MathML" display="inline"> c ∈ B 1 https://www.w3.org/1999/xlink" xlink:href=" https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003374404/4745344c-4074-4386-85e6-ca8a3849de1f/content/math10_9.tif "/> https://www.w3.org/1998/Math/MathML" display="block"> T ⋅ | x ⟩ | c ⟩ = | x ⟩ | f ( x ) ⊕ c ⟩ . https://www.w3.org/1999/xlink" xlink:href=" https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003374404/4745344c-4074-4386-85e6-ca8a3849de1f/content/math10_10.tif "/>
In the previous chapter we identified a component of angular momentum that was orthogonal to the two-dimensional configuration space that had emerged from a degenerate two-category bosonic system. This implied that we needed a third dimension of configuration space to complete our configuration space picture. This suggests we explore a bosonic three-category system. So, we now let https://www.w3.org/1998/Math/MathML" display="inline"> N ^ https://www.w3.org/1999/xlink" xlink:href=" https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003377504/0865e0f9-b6f9-4666-9620-3b3ea10ce510/content/math8_1.tif "/> be 8.1 https://www.w3.org/1998/Math/MathML" display="block"> N ^ = N ^ 1 + N ^ 2 + N ^ 3 , https://www.w3.org/1999/xlink" xlink:href=" https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003377504/0865e0f9-b6f9-4666-9620-3b3ea10ce510/content/math8_2.tif "/>
In this chapter, the simplest quantum measurement situation, i.e., where the state is an eigenvector of the observable to be measured, is considered. The states are therefore non-superimposed and measurement Axiom 3.2 of Section 13.7 in the previous chapter is applicable. We consider states in https://www.w3.org/1998/Math/MathML" display="inline"> ℂ 2 , ℂ 2 ⊗ ℂ 2 https://www.w3.org/1999/xlink" xlink:href=" https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003264569/7139ce19-0d58-4a0c-820f-b76fb033e438/content/math14_1.tif "/> and https://www.w3.org/1998/Math/MathML" display="inline"> ℂ 2 ⊗ ℂ 2 ⊗ ℂ 2 https://www.w3.org/1999/xlink" xlink:href=" https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003264569/7139ce19-0d58-4a0c-820f-b76fb033e438/content/math14_2.tif "/> . The generalisation to https://www.w3.org/1998/Math/MathML" display="inline"> ⊗ n ℂ 2 https://www.w3.org/1999/xlink" xlink:href=" https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003264569/7139ce19-0d58-4a0c-820f-b76fb033e438/content/math14_3.tif "/> is then clear.