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Cambridge University Press eBooks

Physical Interpretation: Postulates of Quantum Mechanics

Rocco Schiavilla

Published Dec 5, 2024• 0 citations
Publisher

Abstract

Applications of the postulates are discussed in a number of problems; the interaction representation is defined.
DOI
10.1017/9781009473637.008

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•May 15, 2023•0 citations
Three postulates are discussed: first that well-defined properties cannot be assigned to an isolated system, second that quantum unitary evolution is atemporal, and third that some physical processes are never reversed. It is argued that these give useful insight into quantum behaviour. The first postulate emphasizes the fundamental role in physics of interactions and correlations, as opposed to internal properties of systems. Statements about physical interactions can only be framed in a context of further interactions. This undermines the possibility of objectivity in physics. However, quantum mechanics retains objectivity through the combination of the second and third postulates. A rule is given for determining the circumstances in which physical evolution is non-unitary. This rule appeals to the absence of spacetime loops in the future evolution of a set of interacting systems. A single universe undergoing non-unitary evolution is a viable interpretation.
Interpreting quantum mechanics is a hard problem basically because it means explaining why and how the mathematics exploited to formulate wave-particle duality are related to observations or reality in classical physics. Consequently, interpretation of quantum mechanics and its formalism should involve proper physical mathematics, physical logic and classical physics, which is not the case from the Copenhagen interpretation. Here, we shall revisit all the postulates of quantum mechanics with proper physics and physical logic and reconstruct them to establish the less-complex interpretation of quantum mechanics with additional new postulates from classical physics. A new quantum mechanical postulate (Postulate 9) is also introduced to understand the meaning of the forbidden gap between discrete energy levels and/or electron orbitals in atoms that is valid for molecules and condensed matter based on quantum mechanics that is technically well-defined and experimentally observable. Here, we tackle all the problems arise from the Copenhagen interpretation systematically by revising and/or extending them with proper classical and quantum physics without violating established experiments and without proposing ideas that violate physical reality.
Interpreting quantum mechanics is a hard problem basically because it means explaining why and how the mathematics exploited to formulate wave-particle duality are related to observations or reality in classical physics (due to Newtonian mechanics, special relativity, gravity and entropy). Here, we first prove the limitation of the Heisenberg uncertainty principle by invoking the wave-particle duality and apply it to revise and/or extend the Copenhagen postulates. In particular, even though the said uncertainty exists due to non-commuting operators, but these operators do not commute simply because one of the operators is well-defined in classical physics (particle-like), while the other is wave-like (well-defined in quantum mechanics), or the eigenvalue is not at all defined in classical physics. We also construct a new quantum mechanical postulate (Postulate 9) to deduce why the forbidden gap between discrete energy levels should exist in atoms, molecules and condensed matter phases. In fact, we tackle all the problems arising from the Copenhagen interpretation without violating established experiments and without proposing ideas that violate physical reality.