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arXiv:physics/0602145

The Postulates of Quantum Mechanics

V. Dorobantu

Published Feb 21, 2006• 0 citations
arXivHTMLPDF

Abstract

As a starting point in understanding Quantum Mechanics, the postulates of Quantum Mechanics are presented, and few of the main eigenvalue problems, as well.
DOI
10.48550/arxiv.physics/0602145

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Basic scientific theories usually start with a set of hypotheses or “postulates.” There is generally no logical reason, apart from internal consistency, that can be given to justify such postulates absolutely. They come from ‘revelations’ in the minds of ‘geniuses,’ most likely with hints from Nature based on extensive careful observations. Their general validity can only be established through experimental verification. If numerous rigorously derived logical consequences of a very small set of postulates all agree with experimental observations without exception, one is inclined to accept these postulates as correct descriptions of the laws of Nature and use them confidently to explain and predict other natural phenomena. Quantum mechanics is no exception. It is based on a few postulates. For the purpose of the present discussion, we begin with three basic postulates involving: the “state functions,” “operators,” and “equations of motion.” In this chapter, this set of basic postulates and some of the corollaries and related definitions of terms are introduced and discussed. We will first simply state these postulates and introduce some of the related mathematical tools and concepts that are needed to arrive at their logical consequences later. To those who have not been exposed to the subject of quantum mechanics before, each of these postulates taken by itself may appear puzzling and meaningless at first. It should be borne in mind, however, that it is the collection of these postulates as a whole that forms the foundations of quantum mechanics.
This chapter starts with the definition of postulates. Here, in quantum mechanics, the postulates concern the atomic and molecular properties, which are quite far removed from everyday experience. The postulates described here make no claim to those happy mathematical adjectives such as ‘rigorous’, ‘complete’, or irreducible. The ‘proof’ of the postulates is their ability to explain the adequate experimental observations. Here, we have incorporated six postulates. The first postulate opines that ‘the state of quantum mechanical objects is described by a wavefunction’, whereas the second postulate says that ‘every physical observable is expressed by a linear operator’. It also describes how a quantum mechanical operator is constructed. The third postulate gives an idea that the measurement of a physical observable will yield a result, which is one of the Eigen values of the corresponding operator for that observable. The fourth postulate gives how the average of a sequence of measurement is connected with an operator. The fifth postulate is called the time-dependent postulate. Here, it gives a relationship between the time-dependent wave function and an operator, whereas the sixth postulate says that the wave function must be antisymmetric (or symmetric) for the exchange of identical fermions. It must be noted that each and every postulate has been explained clearly. The references, solved problems, and questions on concepts have been given at the end of the chapter.
This book is a comprehensive text in the field of quantum mechanics, covering fundamental concepts including the state of a quantum mechanical system, operators, superposition principle and measurement postulate. The notion of an operator and the algebra of operators are introduced with the help of elementary concepts of mathematical analysis. Mathematical tools developed will help readers in understanding the difficulties encountered in classical physics while trying to explain the experimental results involving atomic spectra and other phenomena. The differential equations that arise while solving eigenvalue problems are solved rigorously, to make the text self-sufficient. The solutions are then physically interpreted and explained. The text offers solved examples, analogous and homework problems to help students in solving practical problems of physics requiring quantum mechanical treatment.
In this paper a didactic approach is described which immediately leads to an understanding of those postulates of quantum mechanics used most frequently in quantum computation. Moreover, an interpretation of quantum mechanics is presented which is motivated by retaining the point of view of classical mechanics as much as possible, and which is consistent with relativity theory. Everything can be written down in terms of well-known mathematical formulations that can be found in every textbook about quantum mechanics. Therefore, in this version, almost no formulas are used.
With some simple examples behind us, we are now ready to list the rules of quantum mechanics: that is, the rules that we need. Unfortunately, there are more than the three laws of classical mechanics (Newton's laws) or the four laws of thermodynamics. But the rules we need can be written on one page. The remainder of the chapter illustrates the meaning of some of these rules, using simple wave functions that we have already derived. The best way to understand these rules is by practicing their application. For this reason, more end-of-chapter problems are present here than in any other chapter.