At the verge of the second quantum revolution, understanding and exploiting the phenomena resulting from the interplay between the intrinsic non-locality of quantum mechanics and purely non-local interactions is of crucial importance for the development of novel quantum technologies. In this thesis, we will mostly focus on the non-local effects introduced by topological frustration (TF), a form of weak frustration that was first introduced in the context of antiferromagnetic quantum spin chains by applying the so called frustrated boundary conditions, realized as a combination of periodic boundary conditions and odd number of spins. Our goal is double. From one side, we will further improve the theoretical understanding of topologically frustrated phases. Beyond these theoretical implications, this work will demonstrate that TF spin chains exhibit compelling technological potential, proposing them as competitive candidates for the development of robust and efficient quantum batteries.
At the verge of the second quantum revolution, understanding and exploiting the phenomena resulting from the interplay between the intrinsic non-locality of quantum mechanics and purely non-local interactions is of crucial importance for the development of novel quantum technologies. In this thesis, we will mostly focus on the non-local effects introduced by topological frustration (TF), a form of weak frustration that was first introduced in the context of antiferromagnetic quantum spin chains by applying the so called frustrated boundary conditions, realized as a combination of periodic boundary conditions and odd number of spins. Our goal is double. From one side, we will further improve the theoretical understanding of topologically frustrated phases. Beyond these theoretical implications, this work will demonstrate that TF spin chains exhibit compelling technological potential, proposing them as competitive candidates for the development of robust and efficient quantum batteries.
Frustration in many-body spin systems is a situation where the spins cannot orient themselves to fully minimize the interactions with their neighbors. It is caused, in general, by competing interactions or by the lattice structure, as in the antiferromagnets on non-bipartite lattices. Over the years frustrated systems have been studied substantially, since frustration can destabilize the antiferromagnetic order, lead to different phases of matter and induce various exotic properties. Frustration can be caused also by a choice of boundary conditions, i.e. the lattice topology. For instance, a ring with an odd number of sites is non-bipartite, which makes antiferromagnets in this setting frustrated. The subject of this thesis are zero-temperature one-dimensional quantum systems exactly in this setting. The major content is discussing how such a simple setting can influence the antiferromagnetic order, by studying spin-1/2 chains with discrete symmetries, whose breaking is related to the onset of the order. After reviewing the known results on topological frustration, dealing with non-thermodynamic quantities, we develop an approach for studying symmetry breaking, that is both suitable for exact analytical computations and meaningful for discussing the order also in a finite system. It consists of the realization that many spin-1/2 chains without external magnetic fields, such as the quantum XY chain, possess anticommuting global symmetries when the number of lattice sites is an odd number, implying the ground-state degeneracy already in a finite system. In this framework, we discover that topological frustration, despite being induced only by the choice of boundary conditions and even/odd system size choice, can affect the magnetization in the thermodynamic limit and system's quantum phase transitions. We find that topological frustration can destroy local order, create a site-dependent magnetization that varies in space with an incommensurate pattern, induce a first-order quantum phase transition that is not present without frustration and modify the nature of a second-order transition, by destroying local order at both sides of the transition and preserving only non-local string order parameters. All these results indicate the incompleteness of the approach to quantum many-body systems, based on the Ginzburg-Landau theory, that tries to capture the properties of the system by taking the system size to infinity before computing the observables and neglects the influence of the chain length as a relevant scale. We find that topological frustration can affect also non-equilibrium properties, by considering a local quantum quench setup. Namely, we study the Loschmidt echo and find it displays qualitatively and quantitatively different behavior for antiferromagnetic rings with an even and odd number of sites. Most of all, the differences become clearer for large system sizes, thus allowing to distinguish in a simple out-of-equilibrium experiment a system made by a certain, large, number of spins from the one with a single additional spin. The thesis also contains a mathematical part. In studying order parameters of models mappable to free fermions, Toeplitz determinants with symbols that possess a part proportional to the delta function arise. We derive asymptotic formulas for this type of determinants.
Spin 1/2 quantum spin chains represent the prototypical model for coupled two-level systems. Consequently, they offer a fertile playground for both fundamental and technological applications ranging from the theory of thermalization to quantum computation. Recently, it has been shown that interesting phenomena are associated to the boundary conditions imposed on the quantum spin chains via the so-called topological frustration. In this work, we analyze the effects of such frustration on a few-spin system, with a particular focus on the strong even–odd effects induced in the ground-state energy. We then implement a topologically frustrated quantum spin chain on a quantum computer to show that our predictions are visible on current quantum hardware platforms.
We propose to use a quantum spin chain as a device to store and release energy coherently and we investigate the interplay between its internal correlations and outside decoherence. We employ the quantum Ising chain in a transverse field and our charging protocol consists of a sudden global quantum quench in the external field to take the system out of equilibrium. Interactions with the environment and decoherence phenomena can dissipate part of the work that the chain can supply after being charged, measured by the ergotropy. We find that overall, the system shows remarkably better performance, in terms of resilience, charging time, and energy storage, when topological frustration is introduced by setting antiferromagnetic interactions with an odd number of sites and periodic boundary conditions. Moreover, we show that in a simple discharging protocol to an external spin, only the frustrated chain can transfer work and not just heat. Published by the American Physical Society 2024
Abstract Landau theory’s implicit assumption that microscopic details cannot affect the global phases has been challenged only recently in systems such as antiferromagnetic quantum spin chains with periodic boundary conditions. The new paradigm of topological frustration has been accordingly put forward. In this context, the quantum phases exhibit a dependence on the boundary conditions. In this work, we show that topological frustration modifies the zero temperature phase diagram of the XY chain in a transverse magnetic field by inducing new boundary quantum phase transitions. Here, by boundary quantum phase transitions we mean non-analyticities that are non-extensive in the number of particles. Such transitions are both of first and second order. Moreover, we come across the first case of second order boundary quantum phase transition characterized by a quartic dispersion relation. Our analytical results are supported by both analytical calculations and numerical investigations, and lay the foundation for understanding the phase diagram of frustrated model.
Although in general boundary conditions do not affect the bulk properties of a system, some of them are special and defy such expectation. This is the case, for instance, of those inducing geometrical frustration in a classical magnet. Recently, the study of such settings in quantum systems (dubbed topological frustration) has uncovered peculiar features, interesting both from a fundamental and technological point of view. In this work, we present and discuss the behavior of several quantum resources in presence of TF, namely the (disconnected) entanglement entropy and the non-stabilizerness Renyi entropy. We will show that, compared to their non-frustrated counterparts, TF adds a distinct contribution to these resources, due to a stable, delocalized, topological excitation. Remarkably, this contribution can be calculated analytically, due to its similarities with that of a W-state.
(English) In recent years, the evolution of quantum technologies has resulted in an unprecedented control over individual quantum particles and many-body systems. This remarkable progress has given rise to a new era, marked by the convergence of classical and quantum methodologies to investigate fundamental questions concerning the nature of quantum matter, improving our understanding of the role of entanglement in solid-state systems or the mechanisms behind high-energy physics. From analog quantum simulators to digital quantum computers, these advancements hold potential across diverse domains. This thesis explores the interplay between classical and quantum methods in understanding topological phases of matter. We concentrate on three distinct directions: non-conventional topological superconductors, interaction-induced topological phases in ultracold atom quantum simulators, and applications of variational quantum algorithms. Each trajectory relies on the combination of different techniques with the aim of understanding and characterizing topological phenomena in different settings. Exploring non-conventional topological superconductors involves extending the paradigmatic Kitaev chain model by incorporating additional terms in the Hamiltonian such as long-range interactions and quasi-periodic potentials. This investigation is relevant to better understand the impact of real-world conditions on the both the topological and localization properties of systems hosting non-local Majorana modes, which are promising candidates for topological quantum computation. In the realm of interacting systems, we explore the realization of interaction-induced topological phases in systems of ultracold atoms in optical lattices, both in one and two dimensions. The remarkable control and versatility of such platforms enable the simulation of both theoretical topological models and strongly correlated physics. Notably, the interplay between interactions and topology can give rise to intriguing phenomena, such as delocalized fractional charges and gapless topological phases,challenging existing intuition. We employ advanced numerical methods based on tensor networks to benchmark the experimental proposals that open the door to the realization and detection of novel many-body phases of matter, including topological quantum critical points and a higher-order topological Peierls insulator in Bose-Hubbard models with long-range interactions. Variational quantum algorithms, conversely, have the potential to efficiently tackle a wide range of problems, including ground state search, phase classification or accessing topological invariants. Despite current limitations in trainability and scalability, these hybrid classical-quantum algorithms provide practical insights into current quantum hardware capabilities and can inspire future architectures. We explore the application of variational quantum algorithms to shed light on topological phenomena, raising questions about their ability to discern topological phase transitions and compute topological invariants in situations where classical approaches fail. This thesis presents a comprehensive exploration of distinct approaches to topological quantum matter by leveraging quantum technologies and quantum-inspired classical algorithms. Our results not only advance our understanding of quantum systems but also pave the way for the realization and discovery of novel physics extending to quantum information processing, materials science, and beyond.