Spin 1/2 quantum spin chains represent the prototypical model for coupled two-level systems. Consequently, they offer a fertile playground for both fundamental and technological applications ranging from the theory of thermalization to quantum computation. Recently, it has been shown that interesting phenomena are associated to the boundary conditions imposed on the quantum spin chains via the so-called topological frustration. In this work, we analyze the effects of such frustration on a few-spin system, with a particular focus on the strong even–odd effects induced in the ground-state energy. We then implement a topologically frustrated quantum spin chain on a quantum computer to show that our predictions are visible on current quantum hardware platforms.
Spin 1/2 quantum spin chains represent the prototypical model for coupled two-level systems. Consequently, they offer a fertile playground for both fundamental and technological applications ranging from the theory of thermalization to quantum computation. Recently, it has been shown that interesting phenomena are associated to the boundary conditions imposed on the quantum spin chains via the so-called topological frustration. In this work, we analyze the effects of such frustration on a few-spin system, with a particular focus on the strong even–odd effects induced in the ground-state energy. We then implement a topologically frustrated quantum spin chain on a quantum computer to show that our predictions are visible on current quantum hardware platforms.
At the verge of the second quantum revolution, understanding and exploiting the phenomena resulting from the interplay between the intrinsic non-locality of quantum mechanics and purely non-local interactions is of crucial importance for the development of novel quantum technologies. In this thesis, we will mostly focus on the non-local effects introduced by topological frustration (TF), a form of weak frustration that was first introduced in the context of antiferromagnetic quantum spin chains by applying the so called frustrated boundary conditions, realized as a combination of periodic boundary conditions and odd number of spins. Our goal is double. From one side, we will further improve the theoretical understanding of topologically frustrated phases. Beyond these theoretical implications, this work will demonstrate that TF spin chains exhibit compelling technological potential, proposing them as competitive candidates for the development of robust and efficient quantum batteries.
Frustration in many-body spin systems is a situation where the spins cannot orient themselves to fully minimize the interactions with their neighbors. It is caused, in general, by competing interactions or by the lattice structure, as in the antiferromagnets on non-bipartite lattices. Over the years frustrated systems have been studied substantially, since frustration can destabilize the antiferromagnetic order, lead to different phases of matter and induce various exotic properties. Frustration can be caused also by a choice of boundary conditions, i.e. the lattice topology. For instance, a ring with an odd number of sites is non-bipartite, which makes antiferromagnets in this setting frustrated. The subject of this thesis are zero-temperature one-dimensional quantum systems exactly in this setting. The major content is discussing how such a simple setting can influence the antiferromagnetic order, by studying spin-1/2 chains with discrete symmetries, whose breaking is related to the onset of the order. After reviewing the known results on topological frustration, dealing with non-thermodynamic quantities, we develop an approach for studying symmetry breaking, that is both suitable for exact analytical computations and meaningful for discussing the order also in a finite system. It consists of the realization that many spin-1/2 chains without external magnetic fields, such as the quantum XY chain, possess anticommuting global symmetries when the number of lattice sites is an odd number, implying the ground-state degeneracy already in a finite system. In this framework, we discover that topological frustration, despite being induced only by the choice of boundary conditions and even/odd system size choice, can affect the magnetization in the thermodynamic limit and system's quantum phase transitions. We find that topological frustration can destroy local order, create a site-dependent magnetization that varies in space with an incommensurate pattern, induce a first-order quantum phase transition that is not present without frustration and modify the nature of a second-order transition, by destroying local order at both sides of the transition and preserving only non-local string order parameters. All these results indicate the incompleteness of the approach to quantum many-body systems, based on the Ginzburg-Landau theory, that tries to capture the properties of the system by taking the system size to infinity before computing the observables and neglects the influence of the chain length as a relevant scale. We find that topological frustration can affect also non-equilibrium properties, by considering a local quantum quench setup. Namely, we study the Loschmidt echo and find it displays qualitatively and quantitatively different behavior for antiferromagnetic rings with an even and odd number of sites. Most of all, the differences become clearer for large system sizes, thus allowing to distinguish in a simple out-of-equilibrium experiment a system made by a certain, large, number of spins from the one with a single additional spin. The thesis also contains a mathematical part. In studying order parameters of models mappable to free fermions, Toeplitz determinants with symbols that possess a part proportional to the delta function arise. We derive asymptotic formulas for this type of determinants.
Abstract In quantum many-body systems with local interactions, the effects of boundary conditions are considered to be negligible, at least for sufficiently large systems. Here we show an example of the opposite. We consider a spin chain with two competing interactions, set on a ring with an odd number of sites. When only the dominant interaction is antiferromagnetic, and thus induces topological frustration, the standard antiferromagnetic order (expressed by the magnetization) is destroyed. When also the second interaction turns from ferro to antiferro, an antiferromagnetic order characterized by a site-dependent magnetization which varies in space with an incommensurate pattern, emerges. This modulation results from a ground state degeneracy, which allows to break the translational invariance. The transition between the two cases is signaled by a discontinuity in the first derivative of the ground state energy and represents a quantum phase transition induced by a special choice of boundary conditions.
Although in general boundary conditions do not affect the bulk properties of a system, some of them are special and defy such expectation. This is the case, for instance, of those inducing geometrical frustration in a classical magnet. Recently, the study of such settings in quantum systems (dubbed topological frustration) has uncovered peculiar features, interesting both from a fundamental and technological point of view. In this work, we present and discuss the behavior of several quantum resources in presence of TF, namely the (disconnected) entanglement entropy and the non-stabilizerness Renyi entropy. We will show that, compared to their non-frustrated counterparts, TF adds a distinct contribution to these resources, due to a stable, delocalized, topological excitation. Remarkably, this contribution can be calculated analytically, due to its similarities with that of a W-state.
Recently it was highlighted that one-dimensional antiferromagnetic spin models with frustrated boundary conditions, i.e. periodic boundary conditions in a ring with an odd number of elements, may show very peculiar behavior. Indeed the presence of frustrated boundary conditions can destroy the local magnetic orders presented by the models when different boundary conditions are taken into account and induce novel phase transitions. Motivated by these results, we analyze the effects of the introduction of frustrated boundary conditions on several models supporting (symmetry protected) topological orders, and compare our results with the ones obtained with different boundary conditions. None of the topological order phases analyzed are altered by this change. This observation leads naturally to the conjecture that topological phases of one-dimensional systems are in general not affected by topological frustration.
It has been recently shown that the presence of topological frustration, induced by periodic boundary conditions in an antiferromagnetic XY chain made of an odd number of spins, prevents the realization of a perfectly staggered local order. Starting from this result and exploiting a recently introduced approach that enables the direct calculation of the expectation value of any operator with support over a finite range of lattice sites, in this work, we investigate the possible fates of local orders. We show that, regardless of the variety of possible situations, they can be all arranged in two different cases. A system admits a finite local order only if the ground state is degenerate, with at least two elements whose momenta differ, in the thermodynamic limit, by $\ensuremath{\pi}$, and this order breaks translational symmetry. In all other cases, any local order decays to zero, algebraically (or faster) in the chain length. Moreover, we show that, in some cases, which of the two possibilities is realized, may depend on the sequence of chain lengths with which the thermodynamic limit is reached. These results are established both analytically and by exact diagonalization and illustrated through examples.