In quantum sensing of magnetic fields, ensembles of nitrogen-vacancy centers in diamond offer high sensitivity, high bandwidth and outstanding spatial resolution while operating in harsh environments. Moreover, the orientation of defect centers along four crystal axes forms an intrinsic coordinate system, enabling vector magnetometry within a single diamond crystal. While most vector magnetometers rely on a known bias magnetic field for full recovery of three-dimensional (3D) field information, employing external 3D Helmholtz coils or permanent magnets results in bulky, laboratory-bound setups, impeding miniaturization of the device. Here, a novel approach is presented that utilizes a fiber-integrated microscale coil at the fiber tip to generate a localized uniaxial magnetic field. The same fiber-tip coil is used in parallel for spin control by combining dc and microwave signals in a bias tee. To implement vector magnetometry using a uniaxial bias field, the orientation of the diamond crystal is preselected and then fully characterized by rotating a static magnetic field in three planes of rotation. The measurement of vector magnetic fields in the full solid angle is demonstrated with a shot-noise-limited sensitivity of 19.4 nT/Hz 1 / 2 and microscale spatial resolution while achieving a fiber sensor head cross section of less than 1 mm 2 . Published by the American Physical Society 2024
In quantum sensing of magnetic fields, ensembles of nitrogen-vacancy centers in diamond offer high sensitivity, high bandwidth and outstanding spatial resolution while operating in harsh environments. Moreover, the orientation of defect centers along four crystal axes forms an intrinsic coordinate system, enabling vector magnetometry within a single diamond crystal. While most vector magnetometers rely on a known bias magnetic field for full recovery of three-dimensional (3D) field information, employing external 3D Helmholtz coils or permanent magnets results in bulky, laboratory-bound setups, impeding miniaturization of the device. Here, a novel approach is presented that utilizes a fiber-integrated microscale coil at the fiber tip to generate a localized uniaxial magnetic field. The same fiber-tip coil is used in parallel for spin control by combining dc and microwave signals in a bias tee. To implement vector magnetometry using a uniaxial bias field, the orientation of the diamond crystal is preselected and then fully characterized by rotating a static magnetic field in three planes of rotation. The measurement of vector magnetic fields in the full solid angle is demonstrated with a shot-noise-limited sensitivity of 19.4 nT/Hz 1 / 2 and microscale spatial resolution while achieving a fiber sensor head cross section of less than 1 mm 2 . Published by the American Physical Society 2024
In quantum sensing of magnetic fields, ensembles of nitrogen-vacancy centers in diamond offer high sensitivity, high bandwidth and outstanding spatial resolution while operating in harsh environments. Moreover, the orientation of defect centers along four crystal axes forms an intrinsic coordinate system, enabling vector magnetometry within a single diamond crystal. While most vector magnetometers rely on a known bias magnetic field for full recovery of three-dimensional (3D) field information, employing external 3D Helmholtz coils or permanent magnets results in bulky, laboratory-bound setups, impeding miniaturization of the device. Here, a novel approach is presented that utilizes a fiber-integrated microscale coil at the fiber tip to generate a localized uniaxial magnetic field. The same fiber-tip coil is used in parallel for spin control by combining dc and microwave signals in a bias tee. To implement vector magnetometry using a uniaxial bias field, the orientation of the diamond crystal is preselected and then fully characterized by rotating a static magnetic field in three planes of rotation. The measurement of vector magnetic fields in the full solid angle is demonstrated with a shot-noise-limited sensitivity of 19.4 nT/Hz 1/2 and microscale spatial resolution while achieving a fiber sensor head cross section of less than 1 mm2
The nitrogen-vacancy (NV) center in diamond is a prime candidate for quantum sensing technologies. Here, we present a fully integrated and mechanically robust fiber-based endoscopic sensor with a tip diameter of 1.25 mm . On its tip, a direct laser-writing process is used to secure a diamond containing NV centers above the fiber’s core inside a polymer structure. Additionally, a metallic direct laser-written antenna structure next to the fiber facet allows efficient microwave manipulation of NV-center spins. The sensor achieves a shot-noise-limited magnetic-field sensitivity of 5.9 nT / Hz using a 15 − μ m -sized microdiamond at a microwave power of 50 mW and an optical power of 2.15 mW . Using lock-in techniques, we measure a sensitivity of 51.8 nT / Hz . Furthermore, we introduce a dual-fiber concept that enables, in combination with a direct laser-written structure, independent guiding of excitation and fluorescence light and thus reduces background autofluorescence. Moreover, controlled guiding of excitation light to the diamond while avoiding sample illumination may enable operation in light-sensitive environments such as biological tissue. While the demonstrated sensitivity is achieved using a single-fiber configuration, the dual-fiber approach provides a path toward integrating smaller diamonds, where autofluorescence would otherwise limit performance. We demonstrate the capability of vector magnetic-field measurements in the type of magnetic field used in state-of-the-art ultracold quantum gas experiments, opening a potential arena in which high resolution and high sensitivity are required.
Sensing vector magnetic fields is important to many applications in fundamental physics, bioimaging, and materials science. Sensors exploiting nitrogen-vacancy (N-V) centers typically interrogate N-V ensembles oriented in all directions, thwarting nanoscale spatial resolution. Utilizing the level anticrossing in the triplet ground state, the authors demonstrate a $m\phantom{\rule{0}{0ex}}i\phantom{\rule{0}{0ex}}c\phantom{\rule{0}{0ex}}r\phantom{\rule{0}{0ex}}o\phantom{\rule{0}{0ex}}w\phantom{\rule{0}{0ex}}a\phantom{\rule{0}{0ex}}v\phantom{\rule{0}{0ex}}e\ensuremath{-}f\phantom{\rule{0}{0ex}}r\phantom{\rule{0}{0ex}}e\phantom{\rule{0}{0ex}}e$ vector magnetometer that simultaneously measures all Cartesian components of the field, offering wide-band operation and high, equal sensitivity in all directions. This technique may work for single N-V centers as well as ensembles, extending vector measurements to the nanoscale, at ambient temperatures.
Accurate measurement of vector magnetic fields is critical for applications including navigation, geoscience, and space exploration. Nitrogen-vacancy ( N V ) center spin ensembles offer a promising solution for high-sensitivity vector magnetometry, as their different orientations in the diamond lattice measure different components of the magnetic field. However, the bias magnetic field typically used to separate signals from each N V orientation introduces inaccuracy from drifts in permanent magnets or coils. Here, we present a novel bias-field-free approach that labels the N V orientations via the direction of the microwave (MW) field in a variable-pulse-duration Ramsey sequence used to manipulate the spin ensemble. Numerical simulations demonstrate the possibility to isolate each orientation’s signal with subnanotesla accuracy in most terrestrial fields, even without precise MW field calibration, at only a moderate cost to sensitivity. We also provide proof-of-principle experimental validation, observing relevant features that evolve as expected with the applied magnetic field. Looking forward, by removing a key source of drift, the proposed protocol lays the groundwork for future deployment of N V magnetometers in high-accuracy or long-duration missions.
In modern-day quantum metrology, quantum sensors are widely employed to detect weak magnetic fields or nanoscale signals. Quantum devices, exploiting quantum coherence, are inevitably connected to physical constants and can achieve accuracy, repeatability, and precision approaching fundamental limits. As a result, these sensors have shown utility in a wide range of research domains spanning both science and technology. A rapidly emerging quantum sensing platform employs atomic-scale defects in crystals. In particular, magnetometry using nitrogen-vacancy (NV) color centers in diamond has garnered increasing interest. NV systems possess a combination of remarkable properties, optical addressability, long coherence times, and biocompatibility. Sensors based on NV centers excel in spatial resolution and magnetic sensitivity. These diamond-based sensors promise comparable combination of high spatial resolution and magnetic sensitivity without cryogenic operation. The above properties of NV magnetometers promise increasingly integrated quantum measurement technology, as a result, they have been extensively developed with various protocols and find use in numerous applications spanning materials characterization, nuclear magnetic resonance (NMR), condensed matter physics, paleomagnetism, neuroscience and living systems biology, and industrial vector magnetometry. In this chapter, NV centers are explored for magnetic sensing in a number of contexts. In general, we introduce novel regimes for magnetic-field probes with NV ensembles. Specifically, NV centers are developed for sensitive magnetometers for applications where microwaves (MWs) are prohibitively invasive and operations need to be carried out under zero ambient magnetic field. The primary goal of our discussion is to improve the utility of these NV center-based magnetometers.
We demonstrate 4π-steradian vector magnetic field sensing using an ensemble of nitrogen-vacancy (NV) centers in a single-crystal diamond coupled to a microwave (MW) cavity. The MW cavity enhances the spin-photon coupling which enables efficient, high-contrast spin-state readout via MW interrogation and removes the need for bulky optical collection components. An applied AC bias magnetic field lifts the zero-field degeneracy of the four crystallographic NV orientations, allowing each orientation to be individually addressed and used for vector reconstruction of the magnetic field. The resulting magnetometer has a 40\% contrast (20x higher than typical for optical spin-ensemble readout) and achieves a single-axis sensitivity of 250 pT/Hz which is flat from DC to 1 kHz. Noise models of the composite spin-cavity system establish MW amplitude noise as the dominant noise source and predict a thermal noise limit of 2 pT/Hz.