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Journal of Applied Physics

Light narrowing over broad temperature range with paraffin-coated vapor cells

Shuyuan Chen, Xingqing Jin, Wentian Xiang, Wei Xiao, Changping Du, Xiang Peng, Hong Mei Guo

Published Sep 9, 2024• 7 citations
Publisher

Abstract

This letter reports light narrowing in paraffin-coated vapor cells from room temperature 27℃ to 59℃, where spin-exchange relaxation is suppressed. By means of a coating lock and eliminating the reservoir effect, an ultra-narrow magnetic resonance linewidth of 0.36 Hz and an atomic coherence lifetime of T₂ = 0.9 s are achieved. In cells free of buffer gas, the narrow linewidth over this broad temperature range is a result of enhanced spin polarization, which is facilitated by the effective suppression of radiation trapping benefiting from the stability of the vapor density. Using such cells in atomic magnetometers, the photon shot noise limit is estimated as 0.2 fT/rtHz and the spin-projection noise limit is estimated as 1.1 fT/rtHz. Also, a magnetometer system with the stable coated cell is identified, which demonstrates the potential for achieving relatively stable magnetometer sensitivity without precisely controlling the cell temperature. The long coherence lifetime and broad operating temperature range expand the potential applications of quantum memory and other quantum sensors such as atomic clocks.

DOI
10.1063/5.0230602

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This letter reports light narrowing in paraffin-coated vapor cells from room temperature 27℃ to 59℃, where spin-exchange relaxation is suppressed. By means of a coating lock and eliminating the reservoir effect, an ultra-narrow magnetic resonance linewidth of 0.36 Hz and an atomic coherence lifetime of T₂ = 0.9 s are achieved. In cells free of buffer gas, the narrow linewidth over this broad temperature range is a result of enhanced spin polarization, which is facilitated by the effective suppression of radiation trapping benefiting from the stability of the vapor density. Using such cells in atomic magnetometers, the photon shot noise limit is estimated as 0.2 fT/rtHz and the spin-projection noise limit is estimated as 1.1 fT/rtHz. Also, a magnetometer system with the stable coated cell is identified, which demonstrates the potential for achieving relatively stable magnetometer sensitivity without precisely controlling the cell temperature. The long coherence lifetime and broad operating temperature range expand the potential applications of quantum memory and other quantum sensors such as atomic clocks.
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Abstract We have manufactured more than 250 nominally identical paraffin-coated Cs vapor cells (30 mm diameter bulbs) for multi-channel atomic magnetometer applications. We describe our dedicated cell characterization apparatus. For each cell we have determined the intrinsic longitudinal, Γ01, and transverse, Γ02, relaxation rates. Our best cell shows Γ01/2π ≈ 0.5 Hz, and Γ02/2π ≈ 2 Hz. We find a strong correlation of both relaxation rates which we explain in terms of reservoir and spin exchange relaxation. For each cell we have determined the optimal combination of rf and laser powers which yield the highest sensitivity to magnetic field changes. Out of all produced cells, 90 % are found to have magnetometric sensitivities in the range of 9 to 30 fT / √ Hz. Noise analysis shows that the magnetometers operated with such cells have a sensitivity close to the fundamental photon shot noise limit. 1
Nowadays, quantum sensor research is a very interesting and popular topic. High-sensitivity magnetic field measurements using quantum sensors have evolved into the most sensitive magnetic field sensor category today with the invention of atomic magnetometers operating in the spin-exchange relaxation-free (SERF) regime. This letter was prepared to investigate the magnetic field sensitivity changes depending on the buffer gas, temperature, and laser intensity using indigenously produced atomic vapor cells. In addition, the aim was to determine the optimum operating conditions of the atomic magnetometer operating in the SERF regime. As a result, the resonance linewidth and signal-to-noise ratio were measured, and the minimum detectable magnetic field was calculated. According to the obtained results, the lowest magnetic field for Cells I–III was measured as 5.12, 4.21, and 4.81 pT, respectively. The lowest magnetic field of all conditions was obtained in vapor cell (Cell-II) at 100 °C with 5 mW laser intensity. As a result, it has been experimentally proven that under the same conditions, increasing the buffer gas pressure in vapor cells can narrow the resonance linewidth, and the magnetic field sensitivity can be improved by increasing the laser intensity applied to the vapor cells.
Vapor cells with antirelaxation coating are widely used in modern atomic physics experiments due to the coating's ability to maintain the atoms' spin polarization during wall collisions. We characterize the performance of vapor cells with different coating materials by measuring longitudinal spin relaxation and vapor density at temperatures up to 95 °C. We infer that the spin-projection-noise-limited sensitivity for atomic magnetometers with such cells improves with temperature, which demonstrates the potential of antirelaxation coated cells in applications of future high-sensitivity magnetometers.
We describe a Cs atomic magnetometer operating in the spin-exchange-relaxation-free (SERF) regime. With a vapor cell temperature of $103\text{ }\ifmmode^\circ\else\textdegree\fi{}\text{C}$ we achieve intrinsic magnetic resonance widths $\ensuremath{\Delta}B=17\text{ }\ensuremath{\mu}\text{G}$ corresponding to an electron spin-relaxation rate of $300\text{ }{\text{s}}^{\ensuremath{-}1}$ when the spin-exchange rate is ${\ensuremath{\Gamma}}_{\text{SE}}=14\text{ }000\text{ }{\text{s}}^{\ensuremath{-}1}$. We also observe an interesting narrowing effect due to diffusion. Signal-to-noise measurements yield a sensitivity of about 400 pG/Hz400\text{ }\text{pG}/\sqrt{\text{Hz}}400 pG/Hz​. Based on photon shot noise, we project a sensitivity of 40 pG/Hz40\text{ }\text{pG}/\sqrt{\text{Hz}}40 pG/Hz​. A theoretical optimization of the magnetometer indicates sensitivities on the order of 2 pG/Hz2\text{ }\text{pG}/\sqrt{\text{Hz}}2 pG/Hz​ should be achievable in a 1 cm31\text{ }{\text{cm}}^{3}1 cm3 volume. Because Cs has a higher saturated vapor pressure than other alkali metals, SERF magnetometers using Cs atoms are particularly attractive in applications requiring lower temperatures.
Alkali metal vapor cells are fundamental components in quantum sensors, and their relaxation characteristics critically influence both sensitivity and system stability. In Spin-Exchange Relaxation-Free (SERF) atomic magnetometers, although spin-exchange collisions are effectively suppressed, wall-collision-induced relaxation remains the primary limiting factor. A coating-enabled buffer-gas-free vapor cell (CBF-VC) is proposed as a novel sensor unit, realized through multilayer octadecyltrichlorosilane (OTS) selfassembled molecular coatings. The CBF-VC is integrated into a single-beam SERF atomic magnetometer, and experimental validation is conducted. The results indicate a significant extension of the wall collision relaxation time from 40.19 ms. This extended relaxation time directly enhances the magnetometer sensitivity by 48%, confirming the feasibility of CBF-VCs as a measurement-oriented vapor cell architecture. The findings demonstrate not only the effectiveness of anti-relaxation coatings, but also a new instrumentation pathway for advancing next-generation quantum sensing.