CRC Press eBooks

Quantum Entropy

Jonathan Allday, Simon Hands

Published Sep 3, 2024• 0 citations

Abstract

From a classical perspective, a quantum state is a surprising mixture of information and ignorance. If a system is sitting in an eigenstate of an observable, we can predict with confidence that a measurement result will yield the appropriate eigenvalue. With a superposition, certainty is not granted to us. Unlike the closest possible classical case, where a superposition represents a genuine blending of classical states, the quantum superposition is a strange overlapping of states simultaneously occupied by the system. On measurement, this ontologically curious animal collapses into one of the overlapping states, a process that is not well understood to this day. The collapse is random, a-causal, but governed by quantum amplitudes. Heading into a measurement, we do not know what we are going to get out. Given the evident link between entropy and information, the probabilities and uncertainties baked into a quantum state may well be a fertile ground for another form of entropy. The density matrix gives us a flexible tool for studying the properties of quantum ensembles of any kind. In this chapter, we will see how von Neumann helped develop and use the density matrix to study the problem of measurement and the information/entropy content of quantum states .

DOI: 10.1201/9781003121053-15

Related papers

The Density Matrix

Jonathan Allday, Simon Hands

The quantum state contains all accessible information about a system. However, for various reasons, the information is less complete than we might expect given the classical states we are used to. This suggests the possibility that the state itself contains a measure of entropy (lack of information), which could potentially arise in two ways. Firstly, quantum states contain an inherent uncertainty with respect to the measurement outcomes of conjugate variables. Secondly, due to limitations in the preparation process, we may not be sure which state a system is occupying. The best we can do in this situation is to assign each potential state a classical probability and construct a specialist mathematical representation to deal with the situation. This is known as the density matrix. It turns out to be a rather handy tool in general and crucial for the exploration of quantum entropy. So, in this chapter, we are going to extend our technical understanding of quantum theory and the representation of states. This will arm us sufficiently to venture into the physics of the measurement problem and the entropy of quantum systems, which we will tackle in Chapter 12 .

CRC Press eBooksSep 3, 20240 citations

Quantum measurements

E. Desurvire

This chapter is concerned with the measure of quantum states . This requires one to introduce the subtle notion of quantum measurement , an operation that has no counterpart in the classical domain. To this effect, we first need to develop some new tools, starting with Dirac notation , a formalism that is not only very elegant but is relatively simple to handle. The introduction of Dirac notation makes it possible to become familiar with the inner product for quantum states, as well as different properties for operators and states concerning projection , change of basis , unitary transformations , matrix elements , similarity transformations , eigenvalues and eigenstates , spectral decomposition and diagonal representation , matrix trace and density operator or matrix . The concept of density matrix makes it possible to provide a very first and brief hint of the analog of Shannon's entropy in the quantum world, referred to as von Neumann's entropy , to be further developed in Chapter 21. Once we have all the required tools, we can focus on quantum measurement and analyze three different types referred to as basis-state measurements , projection or von Neumann measurements , and POVM measurements. In particular, POVM measurements are shown to possess a remarkable property of unambiguous quantum state discrimination (UQSD), after which it is possible to derive “absolutely certain” information from unknown system states. The more complex case of quantum measurements in composite systems described by joint or tensor states is then considered.

Cambridge University Press eBooksFeb 19, 20090 citations

Quantum information I

Vlatko Vedral

Abstract Information is often considered classical in a definite state rather than in a superposition of states. It seems rather strange to consider information in superpositions. Some people would, on the basis of this argument, conclude that quantum information can never exist and we can only have access to classical information. It turns out, however, that quantum information can be quantified in the same way as classical information using Shannon's prescription. There is a unique measure (up to a constant additive or multiplicative term) of quantum information such that S (the von Neumann entropy) is purely a function of the probabilities of outcomes of measurements made on a quantum system (that is, a function of a density operator); S is a continuous function of probability; S is additive. This chapter discusses the fidelity of pure quantum states, Helstrom's discrimination, quantum data compression, entropy of observation, conditional entropy and mutual information, relative entropy, and statistical interpretation of relative entropy.

Sep 28, 20060 citations

Entropy in Quantum Probability I

Dėnes Petz

The notion of entropy was introduced by Clausius in order to discuss the thermal behavior of physical systems. After the work of Clausius, Boltzmann, Gibbs and others, the beginning of the exact treatment of entropy was due to von Neumann and Shannon. Their starting point was very di erent, von Neumann was motivated by quantum mechanics and Shannon founded communication theory. The entropy of a state describing a physical system is a quantity expressing the uncertainty or randomness of the system. Shannon regarded this uncertainty attached to a physical system as the amount of information carried by the system, so that the entropy of a state can be read as the information carried by the state. His idea comes from the following consideration: If a physical system has a large uncertainty and one receives information on the system by some procedure, then the so obtained information is more valuable than that received from a system having less uncertainty. It is understood in probability theory that the notion of (Shannon or measure theoretic) entropy has successful applications in a variety of subjects because it determines the asymptotic behavior of certain probabilities in the course of independent trials. First we will discuss this phenomena for nite quantum systems. By a nite quantum system we mean an algebra of matrices which is stable under taking adjoint. (In other words, a nite quantum system is a nite dimensional C*algebra.) If A is such an algebra then there is a linear functional Tr which takes the value 1 at each minimal projection. It is "tracial " in the sense that Tr ab = Tr ba (a; b 2 A) Every functional! on A is determined by a density operator D! 2 A in the form!(a) = Tr D! a (a 2 A): The entropy S(!) of a functional! is de ned by means of its density operator as S(!) = Tr (D!): This notion was introduced by von Neumann in 1927 and we term it von Neumann's entropy or shortly entropy (cf. [1]). In fact, von Neumann de ned the entropy such

QP-PQ, quantum probability and white noise analysisJul 1, 19922 citations

Quantum Statistical Mechanics. I. Decoherence, Wave Function Collapse, and the von Neumann Density Matrix

Phil Attard

The probability operator is derived from first principles for an equilibrium quantum system. It is also shown that the superposition states collapse into a mixture of states giving the conventional von Neumann trace form for the quantum average. The mechanism for the collapse is found to be quite general: it results from the conservation law for a conserved, exchangeable variable (such as energy) and the entanglement of the total system wave function that necessarily follows. The relevance of the present results to the einselection mechanism for decoherence, to the quantum measurement problem, and to the classical nature of the macroscopic world are discussed.

arXiv:1401.1786Nov 25, 20131 citation

Entropy of Quantum States

Paolo Facchi A, Giovanni Gramegna, Arturo Konderak

Given the algebra of observables of a quantum system subject to selection rules, a state can be represented by different density matrices. As a result, different von Neumann entropies can be associated with the same state. Motivated by a minimality property of the von Neumann entropy of a density matrix with respect to its possible decompositions into pure states, we give a purely algebraic definition of entropy for states of an algebra of observables, thus solving the above ambiguity. The entropy so-defined satisfies all the desirable thermodynamic properties and reduces to the von Neumann entropy in the quantum mechanical case. Moreover, it can be shown to be equal to the von Neumann entropy of the unique representative density matrix belonging to the operator algebra of a multiplicity-free Hilbert-space representation.

arXiv:2104.12611EntropyMay 21, 202110 citations