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arXiv:2104.12611 · Entropy

Entropy of Quantum States

Paolo Facchi A, Giovanni Gramegna, Arturo Konderak

Published May 21, 2021• 10 citations
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Abstract

Given the algebra of observables of a quantum system subject to selection rules, a state can be represented by different density matrices. As a result, different von Neumann entropies can be associated with the same state. Motivated by a minimality property of the von Neumann entropy of a density matrix with respect to its possible decompositions into pure states, we give a purely algebraic definition of entropy for states of an algebra of observables, thus solving the above ambiguity. The entropy so-defined satisfies all the desirable thermodynamic properties and reduces to the von Neumann entropy in the quantum mechanical case. Moreover, it can be shown to be equal to the von Neumann entropy of the unique representative density matrix belonging to the operator algebra of a multiplicity-free Hilbert-space representation.

DOI
10.3390/e23060645

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Given the algebra of observables of a quantum system subject to selection rules, a state can be represented by different density matrices. As a result, different von Neumann entropies can be associated with the same state. Motivated by a minimality property of the von Neumann entropy of a density matrix with respect to its possible decompositions into pure states, we give a purely algebraic definition of entropy for states of an algebra of observables, thus solving the above ambiguity. The entropy so-defined satisfies all the desirable thermodynamic properties and reduces to the von Neumann entropy in the quantum mechanical case. Moreover, it can be shown to be equal to the von Neumann entropy of the unique representative density matrix belonging to the operator algebra of a multiplicity-free Hilbert-space representation.
A method for representing probabilistic aspects of quantum systems by means of a density function on the space of pure quantum states is introduced. In particular, a maximum entropy argument allows us to obtain a natural density function that only reflects the information provided by the density matrix. This result is applied to derive the Shannon entropy of a quantum state. The information theoretic quantum entropy thereby obtained is shown to have the desired concavity property, and to differ from the conventional von Neumann entropy. This is illustrated explicitly for a two-state system.
A method for representing probabilistic aspects of quantum systems by means of a density function on the space of pure quantum states is introduced. In particular, a maximum entropy argument allows us to obtain a natural density function that only reflects the information provided by the density matrix. This result is applied to derive the Shannon entropy of a quantum state. The information theoretic quantum entropy thereby obtained is shown to have the desired concavity property, and to differ from the conventional von Neumann entropy. This is illustrated explicitly for a two-state system. (C) 2000 American Institute of Physics. S0022-2488(00)03305-3.
In quantum mechanics, states can exhibit entanglement. Entanglement is a property referring to correlations between the measurement outcomes associated with different parts of a quantum system. The usual von Neumann entanglement entropy quantifies this property using a tensor product factorization of the Hilbert space, but such a factorization is not naturally available in many physical systems. Algebraic entanglement entropy generalizes this construction by defining the accessible part of a system through a von Neumann algebra of observables which, in general, induces a direct sum of tensor products. This thesis develops the mathematical and operational framework for algebraic entanglement entropy and applies it to the finite-𝑁 single Hermitian matrix model, with particular attention given to the singlet and adjoint sectors. Explicit computations for several 𝑁 = 2 matrix quantum harmonic oscillator eigenstates demonstrate that the method applies consistently to both sectors and produces distinct entanglement entropies for their different wavefunction structures
For a quantum state undergoing unitary Schrodinger time evolution, the von Neumann entropy is constant. Yet the second law of thermodynamics, and our experience, show that entropy increases with time. Ingarden introduced the quantum operator entropy, which is the Shannon entropy of the probability distribution for the eigenvalues of a Hermitian operator. These entropies characterize the missing information about a particular observable inherent in the quantum state itself. The von Neumann entropy is the quantum operator entropy for the case when the operator is the density matrix. We examine pure state unitary evolution in a simple model system comprised of a set of highly-interconnected topologically disordered states and a time-independent Hamiltonian. An initially confined state is subject to free expansion into available states. The time development is completely reversible with no loss of quantum information and no course graining is applied. The positional entropy increases in time in a way that is consistent with both the classical statistical mechanical entropy and the second law.
Quantum Field Theory (QFT) represents a vast generalization of Quantum Mechanics (QM), as it deals with systems that have an infinite number of degrees of freedom. The Stone-von Neumann theorem, which establishes the equivalence of irreducible representations of the canonical commutation relations (CCR) in QM, does not extend to QFT. Consequently, QFT admits multiple inequivalent irreducible representations, leading to a much richer algebraic structure. This essay aims to explore the physics of QFT from the operator algebra perspective, particularly focusing on entanglement entropy. We discuss the role of von Neumann algebras of different types in QFT, describe the local operator algebra approach to QFT, and explain how entanglement entropy can be defined in terms of the algebra of observables. Additionally, we explore the benefits of this approach in concrete applications, specifically in quantum field theory on curved spacetime.
Von Neumann proposed two quantum entropies, one in 1927 and the other in 1929. He intended to define thermodynamic entropy for quantum states in both cases. The 1927 entropy is the well-known von Neumann entropy, which is zero for all pure states. The 1929 entropy, which is nonzero for almost all pure states, has largely been ignored. After reviewing the history and properties of both entropies, we argue that the 1927 entropy is not thermodynamic entropy and should be used simply as a measure of entanglement, whereas the 1929 entropy is the true thermodynamic entropy for quantum states.