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Physical review. E

Statistics of quantum heat in the Caldeira-Leggett model

Ze-Zhou Zhang, Qing-Shou Tan, Wei Wu

Published Jun 14, 2024• 2 citations
Publisher

Abstract

Nonequilibrium fluctuation relation lies at the heart of the quantum thermodynamics. Many previous studies have demonstrated that the heat exchange between a quantum system and a thermal bath initially prepared in their own Gibbs states at different temperatures obeys the famous Jarzynski-Wójcik fluctuation theorem. However, this conclusion is obtained under the assumption of Born-Markovian approximation. In this paper, going beyond the Born-Markovian limitation, we investigate the statistics of quantum heat in an exactly non-Markovian relaxation process described by the well-known Caldeira-Leggett model. It is revealed that the Jarzynski-Wójcik fluctuation theorem breaks down in the strongly non-Markovian regime. Moreover, we find the steady-state quantum heat within the non-Markovian framework can be widely tunable by using the quantum reservoir-engineering technique. These results are sharply contrary to the common Born-Markovian predictions. Our results presented in this paper may update the understanding of the quantum thermodynamics in strongly coupled and low-temperature systems. Moreover, the controllable heat may have some potential applications in improving the performance of a quantum heat engine.

DOI
10.1103/physreve.109.064134

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Nonequilibrium fluctuation relation lies at the heart of the quantum thermodynamics. Many previous studies have demonstrated that the heat exchange between a quantum system and a thermal bath initially prepared in their own Gibbs states at different temperatures obeys the famous Jarzynski-Wójcik fluctuation theorem. However, this conclusion is obtained under the assumption of Born-Markovian approximation. In this paper, going beyond the Born-Markovian limitation, we investigate the statistics of quantum heat in an exactly non-Markovian relaxation process described by the well-known Caldeira-Leggett model. It is revealed that the Jarzynski-Wójcik fluctuation theorem breaks down in the strongly non-Markovian regime. Moreover, we find the steady-state quantum heat within the non-Markovian framework can be widely tunable by using the quantum reservoir-engineering technique. These results are sharply contrary to the common Born-Markovian predictions. Our results presented in this paper may update the understanding of the quantum thermodynamics in strongly coupled and low-temperature systems. Moreover, the controllable heat may have some potential applications in improving the performance of a quantum heat engine.
The nonequilibrium fluctuation relation is a cornerstone of quantum thermodynamics. It is widely believed that the system-bath heat exchange obeys the famous Jarzynski-Wójcik fluctuation theorem. However, this theorem is established in the Born-Markovian approximation under the weak-coupling condition. Via studying the energy exchange between a harmonic oscillator and its coupled bath in the non-Markovian dynamics, we establish a generalized quantum fluctuation theorem for energy exchange being valid for arbitrary coupling strength. The Jarzynski-Wójcik fluctuation theorem is recovered in the weak-coupling limit. We also find the average energy exchange exhibits rich nonequilibrium characteristics when different numbers of system-bath bound states are formed, which suggests a useful way to control the quantum heat. Deepening our understanding of the fluctuation relation in quantum thermodynamics, our result lays the foundation to design high-efficiency quantum heat engines.
We investigate the heat statistics in a relaxation process of quantum Brownian motion described by the Caldeira-Leggett model. By employing the normal mode transformation and the phase-space formulation approach, we can analyze the quantum heat distribution within an exactly dynamical framework beyond the traditional paradigm of Born-Markovian and weak-coupling approximations. It is revealed that the exchange fluctuation theorem for quantum heat generally breaks down in the strongly non-Markovian regime. Our results may improve the understanding about the nonequilibrium thermodynamics of open quantum systems when the usual Markovian treatment is no longer appropriate.
The quantum exchange fluctuation theorem relates the probabilities of observing heat transfer along and against the temperature gradient between thermal baths at different temperatures. We investigate how this relation generalizes when the baths exhibit non-Markovian dynamics. Using a microscopic collisional model, bath memory is generated through interactions between successive bath auxiliaries before each heat-exchange collision. We derive exchange fluctuation theorems for both direct bath-bath interactions and probe-mediated heat exchange in the steady-state regime. As an illustrative example, we consider heat baths with qubit auxiliaries and show that non-Markovian memory enhances the probability of heat-transfer events against the temperature gradient, modifying the predictions made by the conventional Jarzynski-Wójcik exchange fluctuation theorem. Our results establish a microscopic connection between environmental memory and non-equilibrium heat-exchange statistics.
We introduce a non-equilibrium version of the Caldeira-Leggett model in which a quantum particle is strongly coupled to a set of engineered reservoirs. The reservoirs are composed by collections of squeezed and displaced thermal modes, in contrast to the standard case in which the modes are assumed to be at equilibrium. The model proves to be very versatile. Strongly displaced/squeezed reservoirs can be used to generate an effective time dependence in the system Hamiltonian and can be identified as sources of pure work. In the case of squeezing, the time dependence is stochastic and breaks the fluctuation-dissipation relation, this can be reconciled with the second law of thermodynamics by correctly accounting for the energy used to generate the initial non-equilibrium conditions. To go beyond the average description and compute the full heat statistics, we treat squeezing and displacement as generalized Hamiltonians on a modified Keldysh contour. As an application of this technique, we show the quantum-classical correspondence between the heat statistics in the non-equilibrium Caldeira-Leggett model and the statistics of a classical Langevin particle under the action of squeezed and displaced colored noises. Finally, we discuss thermodynamic symmetries of the heat generating function, proving a fluctuation theorem for the energy balance and showing that the conservation of energy at the trajectory level emerges in the classical limit.
Two fundamental ingredients play a decisive role in the foundations of fluctuation relations-the principle of micro-reversibility and the fact that thermal equilibrium is described by Gibbs canonical ensemble. Here we investigate the statistics of heat exchange between quantum finite system coupled to two reservoirs at temperatures Th and Tc in the transient regime. We have obtained an analytical result for quantum heat fluctuation theorem in the transient regime. We consider a composite system consisting of two different heat baths at different temperatures with an intervening medium(system of interest). The system of interest is driven by an external protocol. For our study we invoke von Neumann two point projective measurement in quantum mechanics. Our result is a generalisation of Jarzynski-Wojcik heat fluctuation theorem.
For a system in which free quantum Brownian particles interact with a non-Markovian heat bath with product initial states, the quantum heat-fluctuation theorems and the Jarzynski relation of the reduced system are derived using the path integral technique. They are not a direct generalization of the classical case. The validity of the second law of quantum thermodynamics is shown. The forms of these theorems and relations have to do with the specified nonequilibrium initial states, and are dependent on the structure of the bath (ergodic or nonergodic) in the quantum case as well as the classical case under some initial states.