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Custom Integrated Circuits Conference

A CMOS-Integrated Color Center Pulse-Sequence Control and Detection System

Jinchen Wang, Isaac Harris, Xibi Chen, Dirk Englund, Ruonan Han

Published Apr 21, 2024• 6 citations
Publisher

Abstract

Color centers are defects within crystals that trap charge carriers in optically accessible levels. In diamonds, these color centers hold great potential for use in quantum sensing and quantum information. The utilization of the nitrogen vacancy (NV) center situated within diamond has allowed demonstrations of magnetic field, electric field, strain, and temperature sensors [1]. In more recent times, the investigation of color centers employing group-IV elements, such as SiV, GeV, and SnV, has gained interests [2]. This interest is attributed to their zero electric dipole moment and diminished optical transition fluctuations, as shown in Fig. 1. However, the manipulation and detection of color centers requires unwieldy and discrete commercial apparatus, leading to a large overall footprint and imposing constraints upon its practical utility. To address this issue, a CMOS-integrated quantum sensor based on loop inductors [3], and a quantum magnetometer using scalable inductor array and photonic filter [4] have been proposed for NV operating at room temperature (RT). In [3], the on-chip photonic filter attenuates the influence of the green laser excitation at a ratio of 10dB, concurrently with the on-chip photodiode (PD) detection of the red fluorescence stemming from the NV center excitation. [4] subsequently enhances this suppression to 25dB for green light. Nevertheless, both [3] and [4] suffer from the red fluorescence emitted by the top passivation on the CMOS chip, which is also excited by the laser (Fig. 2). The photonic filter cannot eliminate this undesired passivation layer's fluorescence because it shares the same frequency as the color center fluorescence. Thus, the top passivation layer must be etched before taking measurements. However, etching the passivation can introduce more defects in the underlying layers, leading to increased randomness and making it more challenging to control the fluorescence. Besides, the scope of effectiveness attributed to on-chip photonic filters encounters constraints in the context of other variants of color centers. The NV can be excited using an off-resonant 532 nm laser, and the intensity of the broad emission from 637 to 780nm is spin state dependent, allowing the scattered excitation light to be spectrally filtered during spin readout. The group IV emitters do not allow off-resonant readout of the spin state, so resonant excitation that matches the frequency of must be used, making spectral filtering more challenging, as shown in Fig. 1. This paper introduces a CMOS-integrated control and detection system capable of functioning at both room and cryogenic temperatures.

DOI
10.1109/cicc60959.2024.10529078

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Color centers are defects within crystals that trap charge carriers in optically accessible levels. In diamonds, these color centers hold great potential for use in quantum sensing and quantum information. The utilization of the nitrogen vacancy (NV) center situated within diamond has allowed demonstrations of magnetic field, electric field, strain, and temperature sensors [1]. In more recent times, the investigation of color centers employing group-IV elements, such as SiV, GeV, and SnV, has gained interests [2]. This interest is attributed to their zero electric dipole moment and diminished optical transition fluctuations, as shown in Fig. 1. However, the manipulation and detection of color centers requires unwieldy and discrete commercial apparatus, leading to a large overall footprint and imposing constraints upon its practical utility. To address this issue, a CMOS-integrated quantum sensor based on loop inductors [3], and a quantum magnetometer using scalable inductor array and photonic filter [4] have been proposed for NV operating at room temperature (RT). In [3], the on-chip photonic filter attenuates the influence of the green laser excitation at a ratio of 10dB, concurrently with the on-chip photodiode (PD) detection of the red fluorescence stemming from the NV center excitation. [4] subsequently enhances this suppression to 25dB for green light. Nevertheless, both [3] and [4] suffer from the red fluorescence emitted by the top passivation on the CMOS chip, which is also excited by the laser (Fig. 2). The photonic filter cannot eliminate this undesired passivation layer's fluorescence because it shares the same frequency as the color center fluorescence. Thus, the top passivation layer must be etched before taking measurements. However, etching the passivation can introduce more defects in the underlying layers, leading to increased randomness and making it more challenging to control the fluorescence. Besides, the scope of effectiveness attributed to on-chip photonic filters encounters constraints in the context of other variants of color centers. The NV can be excited using an off-resonant 532 nm laser, and the intensity of the broad emission from 637 to 780nm is spin state dependent, allowing the scattered excitation light to be spectrally filtered during spin readout. The group IV emitters do not allow off-resonant readout of the spin state, so resonant excitation that matches the frequency of must be used, making spectral filtering more challenging, as shown in Fig. 1. This paper introduces a CMOS-integrated control and detection system capable of functioning at both room and cryogenic temperatures.
Metamaterials and metasurfaces can be seen as a novel approach for constructing practical quantum photonic systems. In this talk, we present our recent advances in controlling single-photon emission from nitrogen-vacancy (NV) color centers in nanodiamonds using CMOS-compatible hyperbolic metamaterials. Further, we discuss how an increased photonic density of states affects the optical readout of the NV center spin-state. These results can be useful for engineering on-chip room-temperature quantum registers.
Point defects in diamond, particularly nitrogen-vacancy (NV) centers, have emerged as powerful tools for a broad range of quantum technologies. These defects are promising candidates for quantum information science, serving as deterministic single-photon sources and solid-state quantum memories. They have also been employed as nanoscale quantum sensors to detect various physical quantities, including magnetic fields, electric fields, and temperature, owing to their long spin coherence time at room temperature. Development of these diamond-based quantum technologies has been rapidly boosted by a recent quantum leap in nanofabrication technologies for high-quality single-crystal diamond. Incorporating these color centers into diamond nanostructures with mature integrated photonics provides a promising route to build scalable and practical systems for quantum applications. This review discusses recent progress and challenges in the hybrid integration of diamond color centers on cutting-edge photonic platforms. Nitrogen-vacancy centers in diamond have emerged as powerful tools for a broad range of quantum technologies. This review discusses recent progress and challenges in the hybrid integration of diamond color centers on cutting-edge photonic platforms.
We report progress toward a CMOS-integrated quantum diamond biosensing platform that combines nitrogen-vacancy (NV) centers in diamond with a custom 40 nm CMOS Single-Photon Avalanche Diode (SPAD) array. The system integrates on-chip active quenching and digital readout with external FPGA-based photon counting, compact microwave delivery, and practical optical excitation and collection schemes to support widefield optically detected magnetic resonance (ODMR). System-level design considerations spanning fluorescence collection efficiency, detector count-rate capability, and microwave homogeneity are analyzed with biological compatibility and scalability in mind. Using superparamagnetic iron oxide nanoparticle (SPION)-labeled HEK293T cells as a representative use case, simple dipole-field estimates indicate that sub-μμμT sensitivity is required to resolve ODMR shifts within typical ensemble linewidths. Based on the proposed architecture and efficiency analysis, a magnetic field sensitivity of approximately 90 nT/Hz\sqrt{\mathrm{Hz}}Hz​ per pixel is estimated. These results outline a practical path from optics-heavy quantum diamond microscopes toward compact, CMOS-integrated NV-based biosensors for quantitative magnetic imaging in complex biological environments.
Optical quantum sensors relying on spin resonance in nitrogen vacancy (NV)-diamond centers achieve exceptional sensitivity for measuring magnetic fields and other parameters at room temperature. Their increased precision enables previously impossible applications. However, current quantum sensors typically rely on bulky external lasers, microwave sources and complex optical configurations, constraining portable and large-scale deployments. This paper introduces a universal platform for optical quantum sensing that adapts CMOS compatible processes traditionally used in OLED-on-silicon fabrication to integrate complete optical quantum sensor elements into a CMOS microchip. By embedding light sources, antennas, and photodiodes in a layered structure, the system enables significant miniaturization, lower power consumption and enhanced robustness due to its solid-state architecture. The proposed concept enables a high degree of modularity and the realization of both single-sensor and array configurations. The envisioned architecture allows large-scale wafer-level production at relatively low cost and therefore broadens the potential use cases for optical quantum sensors.
The nitrogen-vacancy (NV) color center in diamond is a promising solid-state quantum system at room temperature. However, its sensitivity is limited by its low fluorescence collection efficiency, and its coherence time is limited by spin interference of impurity electrons around the NV color center. Here, we innovatively fabricated a one-dimensional photonic crystal on the surface of diamond, which greatly improved the fluorescence intensity of the NV color centers and increased the sensitivity of NV ensembles by a factor of 2.92. In addition, the laser reflected by the photonic crystal excites impurity electrons around the NV color centers, improving the electric field environment around the NV color centers, which exponentially prolongs the dephasing time (from 209 to 841 ns), opening avenues for NV color-center ensemble sensors.
The physical properties of diamond crystals, such as color or electrical conductivity, can be controlled via impurities. In particular, when doped with nitrogen, optically active nitrogen-vacancy centers (NV), can be induced. The center is an outstanding quantum spin system that enables, under ambient conditions, optical initialization, readout, and coherent microwave control with applications in sensing and quantum information. Under optical and radio frequency excitation, the Zeeman splitting of the degenerate states allows the quantitative measurement of external magnetic fields with high sensitivity. This study provides a pedagogical introduction to the properties of the NV centers as well as a step-by-step process to develop and test a simple magnetic quantum sensor based on color centers with significant potential for the development of highly compact multisensor systems.