Abstract In this contribution, the role of epistemology in understanding quantum chemistry is discussed. Quantum chemistry is the study of the behavior of atoms and molecules using the principles of quantum mechanics. Epistemology helps us evaluate claims to knowledge, distinguish between justified and unjustified beliefs, and assess the reliability of scientific methods. In quantum chemistry, the epistemology of knowledge is heavily influenced by the mathematical nature of quantum mechanics, and models can be tested, proven, and validated through experimentation. This paper also discusses key concepts used in quantum chemistry, such as the wave-particle duality of matter and the uncertainty principle. This work utilizes Kant’s philosophy of science to frame debates and discussions in quantum chemistry, particularly with regard to the interplay between empirical observation and theory. Additionally, the text explores how Kant’s ideas about the role of the mind in constructing our understanding of the world can help us comprehend the counterintuitive phenomena of quantum mechanics and its applications in quantum chemistry theory.
Abstract In this contribution, the role of epistemology in understanding quantum chemistry is discussed. Quantum chemistry is the study of the behavior of atoms and molecules using the principles of quantum mechanics. Epistemology helps us evaluate claims to knowledge, distinguish between justified and unjustified beliefs, and assess the reliability of scientific methods. In quantum chemistry, the epistemology of knowledge is heavily influenced by the mathematical nature of quantum mechanics, and models can be tested, proven, and validated through experimentation. This paper also discusses key concepts used in quantum chemistry, such as the wave-particle duality of matter and the uncertainty principle. This work utilizes Kant’s philosophy of science to frame debates and discussions in quantum chemistry, particularly with regard to the interplay between empirical observation and theory. Additionally, the text explores how Kant’s ideas about the role of the mind in constructing our understanding of the world can help us comprehend the counterintuitive phenomena of quantum mechanics and its applications in quantum chemistry theory.
The concept of atomic and molecular orbitals has been a fundamental pillar in modern chemistry, shedding light on the structures and reactivity of chemical compounds. This article examines the evolution and significance of orbital theory, its applications in chemistry, and the ongoing debate about the existence of orbitals from both physics and chemistry perspectives. Philosophical aspects related to the ontology of orbitals are explored, emphasizing the complex interplay between mathematical abstractions and tangible reality. The multifaceted nature of orbitals, their role in quantum mechanics, and their implications for understanding the quantum realm are discussed. While the debate surrounding the ontological status of orbitals remains ongoing, it highlights the profound nature of inquiries into the fundamental essence of reality. This exploration underscores the significance of continuous research and discourse in advancing our understanding of these fundamental constituents of the quantum world.
Kant’s philosophy of science has been applied to quantum physics since the time when Niels Bohr formulated his interpretation of quantum physics. In recent years various Kantian interpretations of quantum physics have been put forward. One aspect that still needs further exploration is what a Kantian approach to the epistemic status of quantum entities would entail. In this paper a new kind of judgment consistent with Kant’s system, called a transcendental judgment, able to account for the real existence of quantum entities in the pre-measurement phase is discussed. The advantage of this kind of judgment is that it allows for a fine-tuning of the Kantian system to account for the discovery of quantum entities that are known to exist but whose existence can epistemologically not be accounted for in traditional Kantian philosophy. With this new kind of judgment, a wider range of possible judgments becomes available which can determine the epistemological status of concepts/ideas/theories quite carefully, discriminating between different kinds of knowledge claims.
Abstract Chemistry is about the atom and molecule, motion of which follows quantum mechanics established 100 years ago by Werner Heisenberg, inspired by a number of milestone findings including Max Planck’s first quanta concept for black body radiation, Albert Einstein’s photon concept for photoelectric effect and oscillator quanta for heat capacity of solid, and Niels Bohr’s quantum model for atomic structure. Independently, inspired by Louis de Broglie’s particle-wave duality, Erwin Schrödinger established wave mechanics, which is shown to be equivalent to Heisenberg’s mechanics by Paul Dirac. The latter further established the relativistic quantum mechanics, and then claimed that the underlying physical laws necessary for the mathematical theory of a large part of physics and the whole of chemistry are thus completely known, and the difficulty is only that the exact application of these laws lead to equations much too complicated to be soluble. In the occasion of celebrating The International Year of Quantum Science and Technology (IYQ 2025, quantum2025.org), we will present a heuristic review of the development of quantum theory and its application to chemistry, namely, quantum chemistry (QC). Then, we will discuss some of the current challenges and the future developments, especially on the quantum computing for quantum chemistry (QCQC).
ABSTRACT The paper aims to bridge the history of quantum theory with its philosophical implications. The focus is not only on the scientific underpinnings of quantum mechanics (these theories emerged as ‘ad hoc’ responses to experimental anomalies) but also on the philosophical ramifications of its probabilistic nature and indeterminacy, which differ from classical realism. The paper examines Dirac's, Bell's, and modern views, focusing on how quantum mechanics (QM) challenges traditional notions of causality, objectivity, and truth while embracing epistemological and metaphysical perspectives. Debates over collapse theories and hidden variables are discussed, as well as Putnam's philosophical outlook, which includes his trenchant involvement with realism, logic, and the measurement problem. Finally, the paper proposes that QM represents a philosophical revolution that renews our understanding of reality, knowledge, and scientific explanation, rather than simply serving as a physical theory for assessing the prospects of quantum philosophy by connecting it to broader aspects such as relativity, causality, and scientific realism.
This paper will present questions from three perspectives about Quantum Mechanics (QM): physics, epistemological, and metaphysical.The quantum phenomena do not fit with the parameters of classical physics, so a daily intuition on macroscopic world is dispensable when it is the quantum object investigated.This physical domain induces a new thinking, which requires also new concepts to describe such object.The QM is disturbing and stimulates epistemological reflections, as the issues of access about what is known; and metaphysical theme are not to be left behind with regard to QM: What would the quantum object to?What is apprehended when this object is perceived, once considered the disturbing characteristics that constitute its physical description: interference and non-separability?What is its nature?This paper focuses briefly on the analysis of B. d'Espagnat in Veiled Reality, which would represent the physical perspective of QT; for epistemological questions, one will resort to the Kantian conception of knowledge; and with regard to the metaphysical perspective, we will rely on an article by Professor J. B. Arenhart.It is necessary to note that the question that pervades in this paper is about if the experience in QM is built.Thus, we will try to seek clarity on the philosophical issues through QT, regarding the problems about the possibility of knowledge of the quantum object and its nature, and whether experience in this case is built.But furthermore, the QM instigates us to think whether metaphysics proceeds on the investigation of nature when it comes to the QM.And such a question is more than to have as problem as the scope of the description of physical data, but rather whether it makes sense or whether metaphysical research is pertinent to the QM.
Quantum chemistry is the use of quantum mechanics to model molecules and their dynamics. In this article we will seek to understand quantum chemical practice via the lens of `de-idealization' based upon a selection of examples together with a more general survey of relevant scientific literature. We will offer some general remarks regarding the problem of modelling molecules and the different approach quantum chemists have developed. We will then consider features of two particular models relating to diatomic molecules and environmental interaction before returning to a more general discussion of the different dimensions of de-idealization relevant to quantum chemistry. Our discussion will support the general claim of continuity between the various families of models in quantum chemistry show and other areas of quantum matter modelling and of the commonness of de-idealization approach under which a model can be modified to be more realistic model in the sense of empirical adequacy without necessarily involving constructing representations that are more veridical.