We present a detailed analysis of near zero-energy Feshbach resonances in ultracold collisions of atom and molecule, taking the He–PH system as an example, subject to superimposed electric and magnetic static fields. We find that the electric field can induce Feshbach resonance which cannot occur when only a magnetic field is applied, through couplings of the adjacent rotational states of different parities. We show that the electric field can shift the position of the magnetic Feshbach resonance, and change the amplitude of resonance significantly. Finally, we demonstrate that, for narrow magnetic Feshbach resonance as in most cases of ultracold atom–molecule collision, the electric field may be used to modulate the resonance, because the width of resonance in electric field scale is relatively larger than that in magnetic field scale.
1. Introduction. Atomic Processes in Astrophysics 2. Radiative Transitions in an Atomic Potential 3. Polarization of Atoms. Polarization Radiation and Light Scattering 4. Atom in a Static Electric Field 5. Atom in a Magnetic Field and Crossed F-B Fields 6. Atom in a Variable Electric Field 7. Atom under Influence of Stochastic Peturbations 8. Relaxation and Decay of Atomic States 9. Excited Hydrogen-Like Atom in Electric Fields of Charged Particles. Foundation of Classical and Quantum Spectral Line Broadening Theory 10. Quasiclassical Theory of Atom - Charge Particle Collisions 11. Collision of the Atom with Atomic Particles in External Fields 12. Atomic Kinetics References Index
We have observed resonant-energy-transfer collisions between K Rydberg atoms. We have tuned the
ns1/2+(n-2)
dj\ensuremath{\rightarrow}${\mathrm{np}}_{\mathrm{j}\ensuremath{'}}$+(n-1)${\mathrm{p}}_{\mathrm{j}\mathrm{\ensuremath{''}}}$ collisional process into resonance with a static electric field. The measured resonance field positions from n=24 to 29 agree well with the calculated positions. We show that the dipole-dipole selection rule, \ensuremath{\Delta}
mj=0,\ifmmode\pm\else\textpm\fi{}1, is valid for these resonances but that \ensuremath{\Delta}J=0,\ifmmode\pm\else\textpm\fi{}1 is not, due to the presence of the electric field. In addition, the polarization of the lasers used to excite the Rydberg states can suppress many of the resonances.