On the Concept of Quantum-Unstable States in Statistical Mechanics: The Case of the Entropy

Osvaldo Civitarese, Manuel Gadella

Osvaldo Civitarese, Manuel Gadella

The concept of entropy is central to the formulation of the quantum statistical mechanics, and it is linked to the definition of the density operator and the associated probabilities of occupation of quantum states. The extension of this scheme to accommodate for quantum decaying states is conceptually difficult, because of the nature of these states. Here we present a way to treat quantum unstable states in the context of statistical mechanics. We focuss on the definition of the entropy and avoid the use of complex temperatures.

Norman Margolus

In statistical mechanics, it is well known that finite-state classical lattice models can be recast as quantum models, with distinct classical configurations identified with orthogonal basis states. This mapping makes classical statistical mechanics on a lattice a special case of quantum statistical mechanics, and classical combinatorial entropy a special case of quantum entropy. In a similar manner, finite-state classical dynamics can be recast as finite-energy quantum dynamics. This mapping translates continuous quantities, concepts and machinery of quantum mechanics into a simplified finite-state context in which they have a purely classical and combinatorial interpretation. For example, in this mapping quantum average energy becomes the classical update rate. Interpolation theory and communication theory help explain the truce achieved here between perfect classical determinism and quantum uncertainty, and between discrete and continuous dynamics.

Rudolf Haag, Nicolaas Marinus Hugenholtz, Marinus Winnink

Phil Attard

Entropy Beyond the Second Law presents a coherent formulation of all aspects of thermodynamics and statistical mechanics with entropy as the unifying theme. This includes formulating equilibrium theory and explaining the role of the Second Law in establishing the equilibrium state. It also establishes the foundations of non-equilibrium theory by generalizing the concept of entropy in an appropriate way. Finally, it addresses the relationship between classical and quantum statistical mechanics by invoking the collapse of the wave function into entropy states. A secondary purpose is to increase the understanding of entropy and the Second Law, and to correct misapprehensions and errors that have arisen over the years.