Abstract It is already evident from the basic physical picture developed in Chapter l that mainly two parameters determine radiation trapping: the strength of the absorption and the spectral shape of the absorption. The strength of the absorption is characterized by the opacity of the atomic vapour, which is proportional to the absorption cross-section of the atoms and to the density of atoms. Hence, before we enter the mathematics of the trapping problem, we first have to determine the absorption cross-section and lineshape. We will not go into details (these are beyond the scope of this book), but only review the facts needed to approach our problem. In addition, there is another motivation for this chapter. It is not only nice but absolutely necessary to have all required formulas compiled in one consistent notation. One has to take really great care not to become completely lost by widely differing notation in the literature—the cgs-system and esu-units versus the SI-system, frequency versus angular frequency, atomic constants referenced to photon density, to energy density or to light intensity, the ubiquitous factor of two for polarization, and the like.
Abstract It is already evident from the basic physical picture developed in Chapter l that mainly two parameters determine radiation trapping: the strength of the absorption and the spectral shape of the absorption. The strength of the absorption is characterized by the opacity of the atomic vapour, which is proportional to the absorption cross-section of the atoms and to the density of atoms. Hence, before we enter the mathematics of the trapping problem, we first have to determine the absorption cross-section and lineshape. We will not go into details (these are beyond the scope of this book), but only review the facts needed to approach our problem. In addition, there is another motivation for this chapter. It is not only nice but absolutely necessary to have all required formulas compiled in one consistent notation. One has to take really great care not to become completely lost by widely differing notation in the literature—the cgs-system and esu-units versus the SI-system, frequency versus angular frequency, atomic constants referenced to photon density, to energy density or to light intensity, the ubiquitous factor of two for polarization, and the like.
Abstract Radiation from spectral lines can be absorbed and re- emitted many times in atomic vapours before it reaches the boundaries of the container encasing the vapour. This effect is known as radiation trapping. It plays an important role practically everywhere where atomic vapours occur, e.g. in spectroscopy, in gas lasers, in atomic line filters, in the determination of atomic lifetimes, in measurements of atomic interaction potentials, and in electric discharge lamps. This book for the first time assembles all the information necessary for a treatment of practical problems, emphasizing both physical insights and mathematical methods. After an introduction that reviews resonance radiation and collisional processes in atomic vapours, physical effects and mathematical methods for various types of problems (e.g. with or without saturation, particle diffusion, reflecting cell walls, etc.) are explained in detail. The last part of the book describes the applications of these methods to a variety of practical problems like cross-section measurements or the design of discharge lamps.Atoms can both absorb and emit electromagnetic radiation like visible light In an assembly of many atoms, e.g., in a vapour or in a gas, radiation emitted by one atom may be reabsorbed by one of its neighbours, just to be reemitted a little later. The game can go on for quite some time—until the photon manages somehow to escape from this prison. At first glance, quite easy to understand. On the other hand, there must be some reason for this voluminous book full of sums, integrals and matrices. Our interest in this subject originally stemmed from investigations on atomic line filters we did for the European Space Agency, ESA. We believed that radiation trapping would have some influence on the performance of these filters and were looking for a simple means to take it into account We started out the same way as probably anyone new to the field would have done when faced with the problem of trapping. We read the classical paper of Holstein, and thought that was all there was to it. We soon had to realize, however, that the assumptions made by Holstein were not fulfilled in our problem, and decided to give the whole matter a closer look. That ‘closer look’ obtained a momentum of its own, and trapping became the centre of our own research in the following years. As our overview of the subject increased. we found that trapping plays a role in a staggering variety of situations. Trapping appears to be important in most experimental setups and in most engineering applications where atomic vapours are involved.
So far we have treated the energy levels of an atomic system as stable states with infinite lifetimes. The presence of an electromagnetic field changes this picture. Absorption of photons will excite atoms and ions to higher levels, while stimulated emission will make excited ones decay. Einstein (1917) showed, using purely statistical arguments, that an excited ion will decay through spontaneous emission in the absence of an electromagnetic field. This process can also be derived by using a rigorous quantum electrodynamic treatment, where the field is quantized. In this chapter we start by discussing transitions between atomic levels in a general sense, postulating the operators responsible for the decay. After the first few sections we will concentrate on the most important few multipoles or terms in the expansion of the electromagnetic field. We will introduce a number of different properties describing the transition, and eventually arrive at the measurable transition rate and, directly linked to it, the lifetime of an excited state. We will start, however, with the most basic property, the component strength. Our aim is to arrive at computationally useful expressions as soon as possible. For a more thorough treatment of the theory of radiative transitions we refer to the book by Sobelman (1972). For a brief review of the many factors affecting spectra of atoms, see Martin and Wiese (1996) .
All optical oscillators and amplifiers can be analyzed as an electromagnetic structure, such as a cavity or a transmission line, which contains an amplifying medium. The operating characteristics of lasers are governed by both the electromagnetic properties of the structures and the properties of the amplifying medium. Stimulated emission and absorption of radiation from energy states are the physical basis of amplification in all laser materials. In order to study lasers, it is necessary to understand the energy levels of the amplifying medium and the stimulated transitions involving them. Quantum mechanical analysis of the energy states and the stimulated emission and absorption is presented in most books on lasers. However, quantum mechanical analyses cover only the analysis of individual atoms. We need to relate the effects of the quantum mechanical interactions to the macroscopic properties of the materials so that properties of the lasers may be analyzed. Therefore, the macroscopic susceptibility of materials related to stimulated emission and absorption is the focus of discussion in this chapter. It is not the purpose of this book to teach quantum mechanics. There are already many excellent books on this topic. The readers are assumed to have a fundamental knowledge of quantum mechanics. However, it is necessary first to review some of the major steps in order to understand precisely the notation used and the meaning of the results. This is presented in Section 5.1.
Light absorption Whereas receiving radio waves is a macroscopic process and hence belongs to the area of classical electrodynamics – in a macroscopic antenna an electric voltage is induced whereby a large number of electrons follow the electric field strength of the incident wave, in a kind of collective motion – the detection of light, so far as the elementary process is concerned, takes place in microscopic type objects such as atoms and molecules. As a consequence, the response of an optical detector is determined by the microstructure of matter. In particular, it is impossible – due to the enormously high frequency of light (in the region of 10 15 Hz) – to measure the electric field strength. What is in fact detectable is the energy transfer from the radiation field to the atomic receiver, and this allows us to draw conclusions about the (instantaneous) intensity of light. We might ask what we can say about the above-mentioned absorption process from an experimentalist's point of view. Among the basic experiences that provide an insight into the structure of the micro-cosmos is the resonance character of the interaction between light and an atomic system. The atomic system, when hit by light, behaves like a resonator with certain resonance frequencies; i.e. it becomes excited (takes up energy) only when the light frequency coincides with a value that is characteristic for the particular atom. Hence, an incident light wave with an initial broadband frequency spectrum that has passed through a gas exhibits in its spectrum dark zones, the so-called absorption lines.
Abstract Since the beginning of this century we have a rough understanding about the structure of atoms. They consist of a nucleus and electrons orbiting around this nucleus. We know that electrons occupy only certain discrete energy states. When they decay from a high-energy state to a low-energy state, they emit electromagnetic radiation. Usually, the low-energy state will be the ground state. In that case, the emitted radiation is called resonance radiation.1 Since the resonance photons have an energy that corresponds to the energy of the transition, they can easily be absorbed by other ground-state atoms. A ground-state atom that absorbs the resonance photon is excited to the upper state for some time and will eventually release the photon again. This absorption/reemission process can be repeated many times, until the photon finally escapes from the vapour. This process is called ‘radiation trapping’ (also known as ‘imprisonment of resonance radiation’, ‘radiative transfer of spectral lines’, ‘line transfer’, or ‘radiation diffusion’).
This thesis presents a comparative study of the measured and calculated absolute absorption and dispersion properties of the Rb D lines through a dense thermal vapour in the absence and presence of an applied magnetic field. A detailed theoretical model valid in the weak-probe regime is calculated. The model uses a matrix representation of the atomic Hamiltonian including the magnetic field interaction for Rb in the completely uncoupled basis. Numerical diagonalisation allows the frequency detunings and transition strengths to be calculated. The lineshape of each transition is modelled as a Voigt profile, a convolution of the inhomogeneous and homogeneous profiles. The medium’s susceptibility is found by summing over all the electric-dipole-allowed transitions. For dense thermal vapours a modification to the homogeneous linewidth of each transition, which grows linearly with the number density of atoms, arises due to resonant dipole-dipole interactions between identical atoms in superpositions of the ground and excited terms. In the presence of an applied magnetic field we investigate the Stokes parameters of light propagating through a dense thermal vapour. For fields larger than 0.33 T we enter the hyperfine Paschen-Back regime on the Rb D lines. We present a compact optical isolator based on an atomic vapour, exploiting the spectral region of high transmission and large dispersion where we would normally expect absorption on the Rb D lines. Frequency up-conversion is shown in the fluorescence measurements over the visible and near infra-red regions for strong excitation. Low density transfer arises due to the energy-pooling effect between two identical atoms in their first excited terms. At high densities resonant dipole-dipole interactions give rise to a threshold for the energy transfer. We characterise the threshold behaviour with increasing number density.