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Radiative transitions in atoms

A. M. Fox

Published Apr 27, 2006• 1 citation
Publisher

Abstract

Abstract This chapter gives an overview of the theory of optical absorption and emission in atoms at the level appropriate to introductory quantum and atomic-physics texts. The aim is to provide an introduction to the more advanced treatment of these topics given later in the book, especially in Chapters 9 and 10. It is assumed that the reader is reasonably familiar with the concepts, and so the material is only developed in summary form. Readers who are less well acquainted with these topics may find it helpful to refer to the bibliography for further details.

DOI
10.1093/oso/9780198566724.003.0004

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Abstract This chapter gives an overview of the theory of optical absorption and emission in atoms at the level appropriate to introductory quantum and atomic-physics texts. The aim is to provide an introduction to the more advanced treatment of these topics given later in the book, especially in Chapters 9 and 10. It is assumed that the reader is reasonably familiar with the concepts, and so the material is only developed in summary form. Readers who are less well acquainted with these topics may find it helpful to refer to the bibliography for further details.
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Covering a number of important subjects in quantum optics, this textbook is an excellent introduction for advanced undergraduate and beginning graduate students, familiarizing readers with the basic concepts and formalism as well as the most recent advances. The first part of the textbook covers the semi-classical approach where matter is quantized, but light is not. It describes significant phenomena in quantum optics, including the principles of lasers. The second part is devoted to the full quantum description of light and its interaction with matter, covering topics such as spontaneous emission, and classical and non-classical states of light. An overview of photon entanglement and applications to quantum information is also given. In the third part, non-linear optics and laser cooling of atoms are presented, where using both approaches allows for a comprehensive description. Each chapter describes basic concepts in detail, and more specific concepts and phenomena are presented in 'complements'.
This concise and accessible book provides a detailed introduction to the fundamental principles of atomic physics at an undergraduate level. Concepts are explained in an intuitive way and the book assumes only a basic knowledge of quantum mechanics and electromagnetism. With a compact format specifically designed for students, the first part of the book covers the key principles of the subject, including the quantum theory of the hydrogen atom, radiative transitions, the shell model of multi-electron atoms, spin-orbit coupling, and the effects of external fields. The second part provides an introduction to the four key applications of atomic physics: lasers, cold atoms, solid-state spectroscopy and astrophysics. This highly pedagogical text includes worked examples and end of chapter problems to allow students to test their knowledge, as well as numerous diagrams of key concepts, making it perfect for undergraduate students looking for a succinct primer on the concepts and applications of atomic physics.
This book provides a broad introductory survey of this remarkable field, aiming to establish and clearly differentiate its physical principles, and also to provide a snapshot portrait of many of the most prominent current applications. Primary emphasis is placed on developing an understanding of the fundamental photonic origin behind the mechanism that operates in each type of effect. To this end, the first few chapters introduce and develop core theory, focusing on the physical significance and source of the most salient parameters, and revealing the detailed interplay between the key material and optical properties. Where appropriate, both classical and photonic (quantum mechanical) representations are discussed. The number of equations is purposely kept to a minimum, and only a broad background in optical physics is assumed. With copious examples and illustrations, each of the subsequent chapters then sets out to explain and exhibit the main features and uses of the various distinct types of mechanism that can be involved in optical nanomanipulation, including some of the very latest developments. To complete the scene, we also briefly discuss applications to larger, biological particles. Overall, this book aims to deliver to the non-specialist an amenable introduction to the technically more advanced literature on individual manipulation methods. Full references to the original research papers are given throughout, and an up-to-date bibliography is provided for each chapter, which directs the reader to other selected, more specialised sources.
Introduction Until now, our discussion of the interaction between radiation and matter has concentrated only on the spectral aspects of radiation. The results could determine the wavelengths for absorption and emission or the selection rules for such transitions, but could not be used to determine the actual extent of emission or absorption. These too are important considerations which are needed to fully quantify radiative energy transfer. Unfortunately, none of the classical theories can predict the extent of emission from an excited medium, or even the extent of absorption. Although the discussion in Section 4.9 (on the propagation of electromagnetic waves through lossy media) touched briefly on the concept of attenuation by absorption, it failed to show the reasons for the spectral properties of the absorption or to accurately predict its extent. We will see later that the classical results are useful only as a benchmark against which the actual absorber is compared. The objective of this chapter is therefore to present an introduction to quantum mechanical processes that control the emission and absorption by microscopic systems consisting of atoms and molecules. The results will then be used to predict the extent of emission by media when excited by an external energy source and to evaluate the absorption of incident radiation. It is now well recognized that all emission or absorption processes are the result of transitions between quantum mechanical energy levels.