Abstract We have seen in the previous chapters that the concept of the macroscopic wave functionΨ(r), is central to understanding atomic Bose–Einstein condensates (BEC), superfluid He, and even superconductivity within the Ginzburg–Landau (GL) theory. But the connection between these ideas is not at all clear, since the atom condensates and He are bosonic systems, while super-conductivity is associated with the conduction electrons in metals which are fermions. The physical meaning of the GL order parameter was not explained until after 1957 when Bardeen Cooper and Schrieffer (BCS) published the first truly microscopic theory of superconductivity. Soon afterward the connection was finally established by Gor’ kov. He was able to show that, at least in the range of temperatures near Tc, the GL theory can indeed be derived from the BCS theory. Furthermore this provides a physical interpretation of the nature of the order parameter. Essentially it is describing a macroscopic wave function, or condensate, of Cooper pairs.
Abstract We have seen in the previous chapters that the concept of the macroscopic wave functionΨ(r), is central to understanding atomic Bose–Einstein condensates (BEC), superfluid He, and even superconductivity within the Ginzburg–Landau (GL) theory. But the connection between these ideas is not at all clear, since the atom condensates and He are bosonic systems, while super-conductivity is associated with the conduction electrons in metals which are fermions. The physical meaning of the GL order parameter was not explained until after 1957 when Bardeen Cooper and Schrieffer (BCS) published the first truly microscopic theory of superconductivity. Soon afterward the connection was finally established by Gor’ kov. He was able to show that, at least in the range of temperatures near Tc, the GL theory can indeed be derived from the BCS theory. Furthermore this provides a physical interpretation of the nature of the order parameter. Essentially it is describing a macroscopic wave function, or condensate, of Cooper pairs.
Abstract Chapter 13 addresses Bose condensation in superfluids (and superconductors), which involves the field operator ψ having a c-number component (<ψ(x,t)>≠0), challenging number conservation. The nonlinear Gross-Pitaevskii equation is derived for this condensate wave function <ψ>=ψ−ψ˜, facilitating identification of the coherence length and the core region of vortex motion. The noncondensate Green’s function G˜1(1,1′)=−i<(ψ˜(1)ψ˜+(1′))+> and the nonvanishing anomalous correlation function F˜∗(2,1′)=−i<(ψ˜+(2)ψ˜+(1′))+> describe the dynamics and elementary excitations of the non-condensate states and are discussed in conjunction with Landau’s criterion for viscosity. Associated concepts of off-diagonal long-range order and the interpretation of <ψ> as a superfluid order parameter are also introduced. Anderson’s Bose-condensed state, as a phase-coherent wave packet superposition of number states, resolves issues of number conservation. Superconductivity involves bound Cooper pairs of electrons capable of Bose condensation and superfluid behavior. Correspondingly, the two-particle Green’s function has a term involving a product of anomalous bound-Cooper-pair condensate wave functions of the type F(1,2)=−i<(ψ(1)ψ(2))+>≠0, such that G2(1,2;1′,2′)=F(1,2)F+(1′,2′)+G˜2(1,2;1′,2′). Here, G˜2 describes the dynamics/excitations of the non-superfluid-condensate states, while nonvanishing F,F+ represent a phase-coherent wave packet superposition of Cooper-pair number states and off-diagonal long range order. Employing this form of G2 in the G1-equation couples the condensed state with the non-condensate excitations. Taken jointly with the dynamical equation for F(1,2), this leads to the Gorkov equations, encompassing the Bardeen–Cooper–Schrieffer (BCS) energy gap, critical temperature, and Bogoliubov-de Gennes eigenfunction Bogoliubons. Superconductor thermodynamics and critical magnetic field are discussed. For a weak magnetic field, the Gorkov-equations lead to Ginzburg–Landau theory and a nonlinear Schrödinger-like equation for the pair wave function and the associated supercurrent, along with identification of the Cooper pair density. Furthermore, Chapter 13 addresses the apparent lack of gauge invariance of London theory with an elegant variational analysis involving re-gauging the potentials, yielding a manifestly gauge invariant generalization of the London equation. Consistency with the equation of continuity implies the existence of Anderson’s acoustic normal mode, which is supplanted by the plasmon for Coulomb interaction. Type II superconductors and the penetration (and interaction) of quantized magnetic flux lines are also discussed. Finally, Chapter 13 addresses Josephson tunneling between superconductors.
The crucial demonstration that superfluidity was linked to Bose particles and Bose-Einstein condensation came after the discovery of He3 in 1949, which failed to show the characteristic A transition within a reasonable wide temperature interval around the critical temperature for the onset of superfluidity in He4. The idea of the bosonization of electrons due to their pairing, introduced by Ogg (1946) became very attractive as an explanation for superconductivity after Schafroth (1955) showed that a gas of charged bosons with charge 2e would indeed show a Meissner effect, which is one of the most crucial features of superconductors (see Chapter 1). However this phenomenological Bose-gas picture was condemned and later on practically forgotten because it was unable to account quantitatively for the critical parameters of the classical (low-temperature) superconductors. Using for Tc the Bose-Einstein condensation temperature Eq.(l.S) one obtains the utterly meaningless result Tc = lOOOO.R&s; with the atomic density of electron pairs ~ 1022cm~3 and with the effective mass m** = 2me. The failure of the Schafroth picture stems from a very large size £ of pairs in classical superconductors, which can be estimated from the uncertainty principle: The uncertainty of the momentum 8p is estimated from the uncertainty of the kinetic energy 8E ~ vpSp, which should be of the order of Tc, the only characteristic energy of the superconducting state. Therefore and turns out to be more than one micron for simple metals with Tc ~ IK and the Fermi velocity VF — I0scm/s. That means that pairs in classical superconductors overlap strongly and the Shafroth model of real space pairs is wrong. The finally successful theory for classical superconductors was formulated by Bardeen, Cooper and Schrieffer (1957). In this chapter we present the main points of the BCS theory, using the Bogoliubov transformation (1947,1958) for the weak-coupling regime and the Green&s;s function technique for the intermediate coupling in Chapter 3. More details will be found in the excellent books by Schrieffer(1965), De Gennes (1989) and Abrikosov, Gor&s;kov and Dzyaloshinskii (1963).
Superfluidity is one of the most striking manifestations of quantum mechanics at macroscopic scales, characterized by frictionless flow and the emergence of collective quantum phenomena. The theoretical foundation of superfluidity in fermionic systems was revolutionized by the Bardeen-Cooper-Schrieffer (BCS) theory, developed in 1957 to explain superconductivity in metals. This groundbreaking work provided a microscopic description of how attractive interactions between electrons near the Fermi surface can lead to the formation of Cooper pairs-correlated pairs of fermions that condense into a coherent quantum state. The BCS theory not only explained superconductivity but also laid the groundwork for understanding superfluidity in systems like liquid helium-3 and ultracold fermionic gases, becoming a cornerstone of condensed matter physics.
We revisit the quantization of the order parameter, which we refer to as third quantization, from the perspective of the commutation relation between the phase operator of the order parameter and the particle-number operator. We show that this macroscopic commutation relation does not constitute an independent fundamental postulate added to quantum mechanics, but instead emerges naturally from second quantization in the thermodynamic limit for both bosonic and fermionic many-body systems. In this sense, both Bose-Einstein condensates (BECs) and Bardeen-Cooper-Schrieffer (BCS) states can be understood as macroscopic quantum states described by bosonic coherent states: in BEC, bosons condense into a single coherent mode with a well-defined phase, while in BCS systems, collective excitations of Cooper pairs can also acquire an effectively bosonic coherent description. On this basis, we propose a new macroscopic interpretation of the BCS-BEC crossover. To characterize this crossover, we model a conventional superconductor as an assembly of macroscopically separated superconducting segments. As the intra-segment coupling increases, the system evolves from a BCS-like regime toward a BEC-like regime, in which the segments collectively behave as macroscopic coherent states. Inter-segment tunneling then locks their phases, establishes global phase coherence, and gives rise to a bulk Bose-Einstein condensate. The phase diagram of the BCS-BEC crossover can thus be understood as a manifestation of a macroscopic quantum process governed by the coherent-state dynamics of the order parameter. Our results provide a unified perspective on BEC, BCS superconductivity, and the BCS-BEC crossover within the framework of third quantization.
Abstract The book covers three main strands, Bose-Einstein condensates (BEC), superfluid and superconductivity. The subjects are developed in a way which gradually builds up the key concepts and the necessary mathematical machinery. The book begins with the simplest of the three topics, BEC, and first thoroughly reviews the basics of the Bose-Einstein ideal gas before going into the techniques of magnetic trapping and cooling of atoms and the discovery of BEC in dilute atomic gases. Superfluidity in helium-4 is more difficult to understand, because it is a strongly interacting quantum liquid. The book introduces the main physical phenomena of superfluidity, and how it follows from the key concept of macroscopic quantum coherence and off-diagonal long ranged order. The theory of superconductivity is developed in stages, starting with the simpler London and Ginzburg Landau theories and their main applications, before developing the mathematical concepts of a quantum coherent state and the Bardeen Cooper Schrieffer (BCS) theory. The final chapter deals with the more advanced topics, including superfluid helium-3 and evidence for unconventional Cooper pairing in exotic superconductors. No prior knowledge of quantum many-body theory is assumed, and the necessary mathematical concepts are introduced in a self-contained manner where needed.