Abstract We next discuss certain general results in quaternionic quantum mechanics, which can be formulated independently of the detailed structure of the Hamiltonian H Our emphasis in this chapter will be on topics connected with symmetry generators. We introduce quaternion anti-self-adjoint space translation generators and use them to construct the momentum representation. Corresponding to these generators, we introduce several possible definitions for the self adjoint momentum operators and show that none of them possesses all the properties of the momentum in complex quantum mechanics. A closely analogous discussion is given for the rotation generators and angular momentum.
Abstract We next discuss certain general results in quaternionic quantum mechanics, which can be formulated independently of the detailed structure of the Hamiltonian H Our emphasis in this chapter will be on topics connected with symmetry generators. We introduce quaternion anti-self-adjoint space translation generators and use them to construct the momentum representation. Corresponding to these generators, we introduce several possible definitions for the self adjoint momentum operators and show that none of them possesses all the properties of the momentum in complex quantum mechanics. A closely analogous discussion is given for the rotation generators and angular momentum.
As earlier conjectured by several authors and much later established by Solèr, from the lattice-theory point of view, Quantum Mechanics may be formulated in real, complex or quaternionic Hilbert spaces only. On the other hand, no quantum systems seem to exist that are naturally described in a real or quaternionic Hilbert space. In a previous paper [23], we showed that any quantum system which is elementary from the viewpoint of the Poincaré symmetry group and it is initially described in a real Hilbert space, it can also be described within the standard complex Hilbert space framework. This complex description is unique and more precise than the real one as, for instance, in the complex description, all self-adjoint operators represent observables defined by the symmetry group. The complex picture fulfils the thesis of Solér’s theorem and permits the standard formulation of the quantum Noether’s theorem. The present work is devoted to investigate the remaining case, namely, the possibility of a description of a relativistic elementary quantum system in a quaternionic Hilbert space. Everything is done exploiting recent results of the quaternionic spectral theory that were independently developed. In the initial part of this work, we extend some results of group representation theory and von Neumann algebra theory from the real and complex cases to the quaternionic Hilbert space case. We prove the double commutant theorem also for quaternionic von Neumann algebras (whose proof requires a different procedure with respect to the real and complex cases) and we extend to the quaternionic case a result established in the previous paper concerning the classification of irreducible von Neumann algebras into three categories. In the second part of the paper, we consider an elementary relativistic system within Wigner’s approach defined as a locally-faithful irreducible strongly-continuous unitary representation of the Poincaré group in a quaternionic Hilbert space. We prove that, if the squared-mass operator is non-negative, the system admits a natural, Poincaré invariant and unique up to sign, complex structure which commutes with the whole algebra of observables generated by the representation itself. This complex structure leads to a physically equivalent reformulation of the theory in a complex Hilbert space. Within this complex formulation, differently from what happens in the quaternionic one, all self-adjoint operators represent observables in agreement with Solèr’s thesis, the standard quantum version of Noether theorem may be formulated and the notion of composite system may be given in terms of tensor product of elementary systems. In the third part of the paper, we focus on the physical hypotheses adopted to define a quantum elementary relativistic system relaxing them on the one hand, and making our model physically more general on the other hand. We use a physically more accurate notion of irreducibility regarding the algebra of observables only, we describe the symmetries in terms of automorphisms of the restricted lattice of elementary propositions of the quantum system and we adopt a notion of continuity referred to the states viewed as probability measures on the elementary propositions. Also in this case, the final result proves that there exists a unique (up to sign) Poincaré invariant complex structure making the theory complex and completely fitting into Solèr’s picture. The overall conclusion is that relativistic elementary systems are naturally and better described in complex Hilbert spaces even if starting from a real or quaternionic Hilbert space formulation and this complex description is uniquely fixed by physics.
The commutator of position and momentum operators is first considered in the coordinate and momentum representations, and then in an abstract Hilbert space. The reader is then introduced to canonical operators with the associated canonical quantization of commutation rules, which consists of maps defined on a symplectic space and taking values in the set of unitary operators on a Hilbert space. If the symplectic space is finite-dimensional, all of its irreducible representations are unitarily equivalent. The Weyl exponentiated form of the commutation relations is described and investigated. One then arrives at the definition of Weyl systems, and it is shown how to recover from them the formulation in terms of self-adjoint operators which satisfy a generalized form of commutation relations. Further topics are the Heisenberg representation for temporal evolution and the generalized uncertainty relations. Unitary operators associated with symplectic linear transformations are then considered, and, within this framework, translations, rotations and the harmonic oscillator are considered. The Weyl programme is then reassessed. Lastly, the basic postulates of modern quantum theory are eventually studied: the probabilistic nature of the predictions of results of measurements; the correspondence between observables and self-adjoint operators on Hilbert spaces; the expected result of measuring an observable quantity; and the evolution of the state vector in systems which are not affected by any external influence. The chapter ends with an outline of rigged Hilbert space formalism and its applications. The commutator in wave mechanics In the first part of this book we studied wave mechanics within the framework of the Schrödinger equation.
In principle, the lattice of elementary propositions of a generic quantum system admits a representation in real, complex or quaternionic Hilbert spaces as established by Solèr’s theorem (1995) closing a long standing problem that can be traced back to von Neumann’s mathematical formulation of quantum mechanics. However up to now there are no examples of quantum systems described in Hilbert spaces whose scalar field is different from the set of complex numbers. We show that elementary relativistic systems cannot be described by irreducible strongly-continuous unitary representations of SL(2, C) on real or quaternionic Hilbert spaces as a consequence of some peculiarity of the generators related with the theory of polar decomposition of operators. Indeed such a ”naive” attempt leads necessarily to an equivalent formulation on a complex Hilbert space. Although this conclusion seems to give a definitive answer to the real/quaternionic-quantum-mechanics issue, it lacks consistency since it does not derive from more general physical hypotheses as the complex one does. Trying a more solid approach, in both situations we end up with three possibilities: an equivalent description in terms of a Wigner unitary representation in a real, complex or quaternionic Hilbert space. At this point the ”naive” result turns out to be a definitely important technical lemma, for it forbids the two extreme possibilities. \nIn conclusion, the real/quaternionic theory is actually complex. This improved approach is based upon the concept of von Neumann algebra of observables. Unfortunately, while \nthere exists a thorough literature about these algebras on real and complex Hilbert spaces, an analysis on the notion of von Neumann algebra over a quaternionic Hilbert space is \ncompletely absent to our knowledge. There are several issues in trying to define such a mathematical object, first of all the inability to construct linear combination of operators \nwith quaternionic coeffients. Restricting ourselves to unital real *-algebras of operators we are able to prove the von Neumann Double Commutant Theorem also on quaternionc \nHilbert spaces. Clearly, this property turns out to be crucial.
Operators represent physically observable quantities, as discussed in Section 2.5. The structure and property of operators depend on the nature of the degree of freedom; operators act on the state space and in particular on the state vector of a given degree of freedom. The significance of operators in the interpretation of quantum mechanics has been discussed in Baaquie (2013e). The operators discussed in this chapter are mostly based on the continuous degree of freedom, which is analyzed in Section 3.1. Hermitian operators represent physically observable properties of a degree of freedom and their mathematical properties are defined in Section 3.3. The coordinate and momentum operators are the leading exemplar of a pair of noncommuting Hermitian operators and these are studied in some detail in Section 3.4. The Weyl operators yield, as in Section 3.5, a finite-dimensional example of the shift and scaling operators; Section 3.8 provides a unitary representation of the coordinate and momentum operators. The term self-adjoint operator is used for Hermitian operators when there is a need to emphasize the importance of the domain of the Hilbert space on which the operators act – a topic not usually discussed in most books on quantum mechanics. Sections 3.10 and 3.11 discuss the concept of self-adjoint operators, in particular the crucial role played by the domain for realizing the property of self-adjointness. It is shown in Section 3.12 how the requirement of self-adjointness yields a non-trivial extension of Hamiltonians that include singular interactions.
In this second chapter we will review the basic mathematical and physical facts about quantum mechanics and establish physical units and notation. Those readers already familiar with the subject can safely jump to the next chapter. An attempt has been made to make the presentation in this chapter as elementary as possible, and yet present the basic facts that will be needed later. There are many beautiful and important topics which will not be touched upon such as self-adjointness of Schrödinger operators, the general mathematical structure of quantum mechanics and the like. These topics are well described in other works, e.g.. Much of the following can be done in a Euclidean space of arbitrary dimension, but in this chapter the dimension of the Euclidean space is taken to be three-which is the physical case-unless otherwise stated. We do this to avoid confusion and, occasionally, complications that arise in the computation of mathematical constants. The interested reader can easily generalize what is done here to the R d , d > 3 case. Likewise, in the next chapters we mostly consider N particles, with spatial coordinates in R 3 , so that the total spatial dimension is 3 N . A Brief Review of the Connection Between Classical and Quantum Mechanics Considering the range of validity of quantum mechanics, it is not surprising that its formulation is more complicated and abstract than classical mechanics. Nevertheless, classical mechanics is a basic ingredient for quantum mechanics. One still talks about position, momentum and energy which are notions from Newtonian mechanics.
The observable algebra O of SO_q(3)-symmetric quantum mechanics is generated by the coordinates of momentum and position spaces (which are both isomorphic to the SO_q(3)-covariant real quantum space R_q^3). Their interrelations are determined with the quantum group covariant differential calculus. For a quantum mechanical representation of O on a Hilbert space essential self- adjointness of specified observables and compatibility of the covariance of the observable algebra with the action of the unitary continuous corepresent- ation operator of the compact quantum matrix group SO_q(3) are required. It is shown that each such quantum mechanical representation extends uniquely to a self-adjoint representation of O. All these self-adjoint representations are constructed. As an example an SO_q(3)-invariant Coulomb potential is intro- duced, the corresponding Hamiltonian proved to be essentially self-adjoint and its negative eigenvalues calculated with the help of a q-deformed Lenz-vector.