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QUANTUM MECHANICS FOR MATHEMATICIANS

Alberto S. Cattaneo

Published Jan 1, 2011• 5 citations
OpenAlex

Abstract

Programm (1) Classical mechanics: Principle of the least action. Lagrangian mechanics. Symmetries and Noether’s theorem. The Kepler problem. The Legendre transform. Hamiltonian mechanics. The classical action. Poisson brackets. Canonical transformations and generating functions. Symplectic manifolds. Hamilton’s and Liouville’s representations. [1][Chapter 1] (2) Hilbert spaces: Basic denitions. Bounded operators. Compact operators. The spectral theorem for self-adjoint compact operators. Trace-class and HilbertSchmidt operators. Closed operators. Symmetric and self-adjoint operators. Resolvent and spectrum. The spectrum of self-adjoint operators. The spectral theorem for (bounded and unbounded) self-adjoint operators. Stone’s theorem. [2, 3] (3) Basic principles of quantum mechanics: Observables, states, and dy

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Programm (1) Classical mechanics: Principle of the least action. Lagrangian mechanics. Symmetries and Noether’s theorem. The Kepler problem. The Legendre transform. Hamiltonian mechanics. The classical action. Poisson brackets. Canonical transformations and generating functions. Symplectic manifolds. Hamilton’s and Liouville’s representations. [1][Chapter 1] (2) Hilbert spaces: Basic denitions. Bounded operators. Compact operators. The spectral theorem for self-adjoint compact operators. Trace-class and HilbertSchmidt operators. Closed operators. Symmetric and self-adjoint operators. Resolvent and spectrum. The spectrum of self-adjoint operators. The spectral theorem for (bounded and unbounded) self-adjoint operators. Stone’s theorem. [2, 3] (3) Basic principles of quantum mechanics: Observables, states, and dy
This chapter provides a self-contained introduction to the basic aspects of Quantum Mechanics, focusing on what is must for Quantum Field Theory. The notions of state space, unitary operators, self-adjoint operators, and projective representation are covered as well as Heisenberg’s uncertainty principle. A complete proof of Stone’s theorem is given, but the spectral theory is covered only at the heuristic level. We provide an introduction to Dirac’s formalism, which is almost universally used in physics literature. The time-evolution is described in both the Schrödinger and the Heisenberg picture. A complete treatment of the harmonic oscillator, providing an introduction to the fundamental idea of creation and annihilation operators concludes the chapter.
In this chapter, we present the basic principles of the quantum mechanics of particle systems from a modern mathematical perspective. The proper study of quantum mechanics brings together several interesting mathematical ideas, ranging from group representations to the spectral theory of unbounded self-adjoint operators in Hilbert spaces and the theory of C * algebras. The facts from analysis of operators in Hilbert spaces and C * algebras needed in this chapter are presented in detail in the appendices at the end of the book. More on the mathematical foundations of quantum mechanics can be found in the books by L. Fadeev and O. Yakubovskii [FY], G. Mackey [M], and F. Strocchi [Str] listed in the bibliography. The birth of quantum theory The origins of quantum theory can be traced back to M. Planck's study, published in 1900, of so-called black-body radiation. It is well known that matter glows when heated, going from red-hot to white-hot as the temperature rises. The color (or frequency of radiation) of the radiating body is independent of its surface, and for a black body it is found to be a function of temperature alone. The behavior of the radiation energy as a function of temperature seemed quite different at high temperatures and low temperatures. In a desperate attempt to fit these different behaviors into a single law, Planck introduced the hypothesis that energy was not continuous, but came in discrete packets or quanta . At the beginning of the twentieth century, a number of experiments pointed to a breakdown of the laws of classical mechanics at very small (subatomic) scales.
In single Hilbert space, Pauli's well–known theorem implies that the existence of a self–adjoint time operator canonically conjugate to a given Hamiltonian requires the Hamiltonian to possess completely continuous spectra spanning the entire real line. Thus the conclusion that there exists no self–adjoint time operator conjugate to a semibounded or discrete Hamiltonian despite some well–known illustrative, implicit counterexamples. In this paper we evaluate Pauli's theorem against the single Hilbert space formulation of quantum mechanics, and consequently show the consistency of assuming a bounded, self–adjoint time operator canonically conjugate to a Hamiltonian with an unbounded, or semibounded, or finite point spectrum. We point out Pauli's implicit assumptions and show that they are not consistent. We demonstrate our analysis by giving two explicit examples. Moreover, we clarify issues surrounding the different solutions to the canonical commutation relations, and, consequently, expand the class of acceptable canonical pairs beyond the solutions required by Pauli's theorem.
Using Stone's formula for finding the spectral resolution of an, either bounded or unbounded, self-adjoint operator on a Hilbert space, we compute the vacuum characteristic function (quantum Fourier transform) of the anti-commutator XP + P X and of the Hamiltonian 1 2 (X 2 + P 2 ) quantum random variables .We also show how Stone's formula is applied to the computation of the vacuum characteristic function of finite dimensional quantum random variables.The method is proposed as an analytical alternative to the algebraic (or Heisenberg) approach relying on the associated Lie algebra commutation relations.