Abstract A distinguishing feature of quantum mechanics, as compared with classical mechanics, is the phenomenon of matter exhibiting wave-like properties. A direct consequence of this wave property of particles is the tunneling of particles through potential energy barriers.-3 The classical particle is forbidden from penetrating the barrier region. In this chapter, the problem of one-dimensional (1D) quantum mechanical tunneling of particles through potential barriers of arbitrary shape is treated. We show that tunneling is a mixed boundary value problem, and obtain the action integral that leads to Schrodinger’s equation and at the same time gives the equations defining the boundary conditions (BCs).
Abstract A distinguishing feature of quantum mechanics, as compared with classical mechanics, is the phenomenon of matter exhibiting wave-like properties. A direct consequence of this wave property of particles is the tunneling of particles through potential energy barriers.-3 The classical particle is forbidden from penetrating the barrier region. In this chapter, the problem of one-dimensional (1D) quantum mechanical tunneling of particles through potential barriers of arbitrary shape is treated. We show that tunneling is a mixed boundary value problem, and obtain the action integral that leads to Schrodinger’s equation and at the same time gives the equations defining the boundary conditions (BCs).
It is possible in quantum mechanics to sneak quickly across a region which is illegal energetically. Richard Feynman Barrier penetration One of the most startling consequences of de Broglie's wave hypothesis and Schrödinger's equation was the discovery that quantum objects can ‘tunnel’ through potential energy barriers that classical particles are forbidden to penetrate. To gain some idea of what we mean by an energy barrier, let us go back to our roller coaster and look at a larger section of track, as shown in Fig. 5.1. If we start the carriage from rest, high up on the left, at A, and ignore any small frictional energy losses, we know from the conservation of energy that we shall arrive on the other side at the same height we started from, at C. As we went over the little hill B, at the bottom of the valley, the car slowed down as some of our kinetic energy was changed to potential energy in climbing the hill, but because we started much higher up, we had plenty of energy to spare to get us over the top. However, if we started the carriage from rest at A, we do not have enough energy to climb over the hill D and get to E. This is an example of an ‘energy barrier’, and we can say that the region from C to E is ‘classically forbidden’. What is remarkable about quantum ‘particles’ is that they do not behave like these classical objects.
At the turn of the twentieth century, the establishment of quantum theory propelled rapid advancements, particularly in the understanding of quantum tunnelling—a fundamental phenomenon in quantum mechanics crucial for various physical processes. The quantum phenomenon of particle passes through potential barriers is of great importance. In classical physics, when the energy of a particle is less than the height of a double barrier structure, it is impossible for it to pass through. However, quantum mechanics allows a particle to penetrate the barrier and emerge on the other side. This paper explores the quantum tunnelling effect, focusing on the single potential barrier model in one dimension and subsequently extending to the double potential barrier model. The Schrödinger equation provides the foundational framework for elucidating the motion of microscopic particles, emphasizing wave-particle duality inherent in quantum mechanics. The analysis of the single potential barrier model involves solving the Schrödinger equation in different regions, determining wave functions and coefficients through boundary conditions. The transmission coefficient is derived, representing the probability of a particle passing through a barrier. In the case of a “thick” barrier, an approximate form for transmission coefficient is provided, demonstrating the exponential decrease in transmission probability with increasing barrier thickness.
The wave nature of particles plays an important role in their physical properties that, for example, particles confined into a small bounded area can have only particular discrete energies. This chapter explains how to solve the time-independent Schrodinger equation. It considers four cases of a one-dimensional motion of particles confined in potentials rapidly changing with x : infinite potential quantum well; a potential step; square-well potential; and tunneling through a potential barrier. The chapter helps to learn the characteristic properties of solutions to this equation. It shows the differences between the predictions of quantum mechanics and classical physics. Quantum tunneling is important in the understanding of a number of physical phenomena such as thermonuclear reactions and conduction in metals and semiconductors. The most advanced application of quantum tunneling is the scanning tunneling microscope. The details of the calculations are left for the readers as a tutorial problem.
This article provides a comprehensive review of the quantum tunneling effect, one of the most important phenomena in quantum mechanics. According to the laws of classical physics, a particle cannot overcome a potential barrier if it has insufficient energy. However, in quantum mechanics, due to the wave nature of the particle, the probability of penetrating the barrier is non-zero. This work analyzes in detail the theoretical foundations of the tunneling effect, its description via the Schrödinger equation, probability amplitudes, boundary conditions for wave functions, and their physical meaning. Furthermore, the application of this effect in semiconductor physics, nuclear physics, scanning tunneling microscopy, and nanotechnology is discussed. Based on the work of Kazakh scientists, the place and significance of the tunneling effect in modern physics are determined. The research results provide a deeper understanding of quantum phenomena and promote the development of their practical applications.
In this chapter, the Schrödinger equation is “derived” for particles that can be described by de Broglie waves. The Schrödinger equation is very different from the corresponding equation of motion in classical mechanics. In order to illustrate the fundamental differences between the two theories, one of the simplest problems of particle dynamics is solved in both Newtonian and quantum mechanics. This simple example also helps to show that quantum mechanics is the fundamental theory and classical mechanics is an approximation, a remarkably good approximation, when considering macroscopic objects. The solution of the Schrödinger equation is presented for a particle inside a box and the quantization condition is derived. The amazing possibility of quantum tunneling when a particle is incident on a barrier of height larger than the energy of the incident particle is also discussed. Finally the three-dimensional Schrödinger equation is solved for the hydrogen atom.
The Schrödinger equation assumes that a particle behaves as a wave and yields a solution in terms of wave function and the energy of the particle under consideration. Once the wave function is known, then everything about the particle can be deduced from the wave function. This chapter covers the development of the Schrödinger wave equation and its applications to one-dimensional systems. Time-dependent and time-independent Schrödinger equations, bound and scattering states, probability density, probability current and expectation values, the solution of the time-independent 1D-Schrödinger equation for a free particle, infinite as well as finite potential wells, potential steps, and the finite potential barrier are discussed in detail in the chapter. The phenomenon of tunneling, relevance and the importance of the free particle, potential wells and potential barriers to contemporary fields of physics and chemistry, periodic solids and their band structures, the Kronig-Penney model, confined states in quantum wells, and wires and dots are other topics presented in innovative manners in the chapter. The importance of the topics presented here is demonstrated through carefully chosen solved examples and unsolved exercises from contemporary fields of sciences.