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Quadratic and linear potentials

Keith Hannabuss

Published Mar 20, 1997• 0 citations
Publisher

Abstract

Abstract Although the classical examples of harmonic oscillators such as springs or the simple pendulum are of limited use in the submicroscopic world of quantum mechanics, there are plenty of other applications that make the oscillator worth studying. Atoms in a crystal, for instance, oscillate about their mean positions and it is their vibrations that carry sound and heat through the material. Indeed, we know from classical theory that by using normal coordinates we may regard any system performing small oscillations about a point of stable equilibrium as a collection of harmonic oscillators. This extends even to the normal modes of vibration of a string or of the electromagnetic field. The harmonic oscillator thus provides the key to understanding how wave phenomena such as light can be quantized, and lies at the heart of Einstein’s idea of the photon and of Planck’s quantum.

DOI
10.1093/oso/9780198537946.003.0003

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Abstract Although the classical examples of harmonic oscillators such as springs or the simple pendulum are of limited use in the submicroscopic world of quantum mechanics, there are plenty of other applications that make the oscillator worth studying. Atoms in a crystal, for instance, oscillate about their mean positions and it is their vibrations that carry sound and heat through the material. Indeed, we know from classical theory that by using normal coordinates we may regard any system performing small oscillations about a point of stable equilibrium as a collection of harmonic oscillators. This extends even to the normal modes of vibration of a string or of the electromagnetic field. The harmonic oscillator thus provides the key to understanding how wave phenomena such as light can be quantized, and lies at the heart of Einstein’s idea of the photon and of Planck’s quantum.
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The first application of quantum ideas to a system with a nonuniform potential energy is to the harmonic oscillator: a pendulum, or a mass on a spring. The result is a quantization of energy with equally spaced energy levels. The wave function is localized in the potential well but can do quantum tunneling beyond the turning points into classically forbidden regions. A wave function can be a negative quantity, but the related position probability is always positive. The wave function shows the particle is not in any single place; in a sense it is in many places simultaneously. The fact that the lowest energy quantum state does not vanish is an example of zero-point energy. States of very high energy show a strong analogy to classical oscillator behavior, an example of the Bohr correspondence principle.
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The harmonic oscillator is a useful model for the interpretation of many physical phenomena. It is used as a first approximation to the vibration of molecules and crystal lattices and for the quantization of electromagnetic fields, among other applications. One can solve the time-independent Schrodinger equation for the harmonic oscillator in many different ways; operator methods give rise to recurrence relations and generating functions for the stationary states. The coordinate representation renders the coordinate operator diagonal. In this particular representation the eigenvectors of the harmonic oscillator are functions of the coordinate that are commonly expressed in terms of Hermite polynomials. The chapter shows that calculation with the eigenfunctions of the harmonic oscillator is remarkably simple in the realm of the Lie algebras. The application of the bosonic algebra in theoretical physics and chemistry is so vast that it is impossible even to give a reasonable summary. An important application of the bosonic algebra is the modeling of simple quantum-mechanical systems.
Mechanical motions of atoms near their equilibrium geometry are approximated by a universal mapping on a collection of independent harmonic oscillators. The respective frequencies are characteristic to the material, for example, lattice phonons or molecular vibrations. The quantum description of atomic motions involves the solution of the Schrödinger equation for the harmonic oscillator in the space of proper wave functions. The energy levels obtained are shown to be equally spaced where the level spacing is proportional to the oscillator frequency. The stationary solutions are identified in terms of Hermite polynomials, demonstrating remarkable differences from the classical harmonic oscillator. The importance of the zero-point energy is emphasized in the context of the stability of chemical bonds, where the Harmonic approximation is shown to be reasonably valid for typical interatomic bonds in standard thermal conditions. This explains the relevance of the harmonic approximation for analyzing the absorption spectrum of infrared radiation by molecules.