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Einstein as a Transitional Figure: The Birth of Wave Mechanics

A. Pais

Published Aug 25, 2005• 0 citations
Publisher

Abstract

Abstract We now leave the period of the old quantum theory and turn to the time of transition, during which matter waves were being discussed by a tiny group of physicists at a time when matter wave mechanics had not yet been discovered. This period begins in September 1923 with two brief communications by Louis de Broglie to the French Academy of Sciences [Bl, B2]. It ends in January 1926 with Schroedinger’s first paper on wave mechanics [S1). The main purpose of this chapter is to stress Einstein’s key role in these developments, his influence on de Broglie, de Broglie’s subsequent influence on him, and, finally, the influence of both on Schroedinger. Neither directly nor indirectly did Einstein contribute to an equally fundamental development that preceded Schroedinger’s discovery of wave mechanics: the discovery of matrix mechanics by Heisenberg [H1]. Therefore, I shall have no occasion in this book to comment in any detail on Heisenberg’s major achievements.

DOI
10.1093/oso/9780192806727.003.0024

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Abstract We now leave the period of the old quantum theory and turn to the time of transition, during which matter waves were being discussed by a tiny group of physicists at a time when matter wave mechanics had not yet been discovered. This period begins in September 1923 with two brief communications by Louis de Broglie to the French Academy of Sciences [Bl, B2]. It ends in January 1926 with Schroedinger’s first paper on wave mechanics [S1). The main purpose of this chapter is to stress Einstein’s key role in these developments, his influence on de Broglie, de Broglie’s subsequent influence on him, and, finally, the influence of both on Schroedinger. Neither directly nor indirectly did Einstein contribute to an equally fundamental development that preceded Schroedinger’s discovery of wave mechanics: the discovery of matrix mechanics by Heisenberg [H1]. Therefore, I shall have no occasion in this book to comment in any detail on Heisenberg’s major achievements.
Schrödinger's work on wave mechanics in 1926 appears to have been driven by the idea that one could give a purely wave-theoretical description of matter. Key elements in this picture were the idea of particles as wave packets (Section 4.3) and the possible implications for the problem of radiation (Section 4.4). This pure wave theory, in contrast to de Broglie's work, did away with the idea of particle trajectories altogether (Section 4.5). The main conflict, however, was between Schrödinger and the proponents of quantum mechanics (in particular Heisenberg, Section 4.6), both in its form at the time of Schrödinger's papers and in its further developments as sketched in the previous chapter. For reference, we provide a brief chronology of Schrödinger's writings relating to wave mechanics up to the Solvay conference: Paper on Einstein's gas theory, submitted 15 December 1925, published 1 March 1926 (Schrödinger 1926a). First paper on quantisation, submitted 27 January 1926, addendum in proof 28 February 1926, published 13 March 1926 (Schrödinger 1926b). Second paper on quantisation, submitted 23 February 1926, published 6 April 1926 (Schrödinger 1926c). Paper on the relation between wave and matrix mechanics (‘equivalence paper’), submitted 18 March 1926, published 4 May 1926 (Schrödinger 1926d). Paper on micro- and macromechanics (coherent states for the harmonic oscillator), published 9 July 1926 (Schrödinger 1926e). […]
In 1923, in three articles published in the Comptes Rendus of the Académie des Sciences , Louis de Broglie proposed the concept of wave–particle duality. Physicists from many countries seized upon this idea. In particular, Schrödinger developed de Broglie's qualitative idea by writing down the equation that the wave must satisfy in the non-relativistic approximation. A relativistic version of this equation was proposed in 1926 by several scientists, and other ones found a solution to the Schrödinger equation as an expansion in powers of the Planck constant.
Elements of quantum mechanics Quantum mechanics was discovered in 1925 through groping efforts to compromise two apparently contradictory pictures on the fundamental entities in nature. One was the wave picture for light which was later extended to matter by de Broglie, another was the corpuscular picture of matter which was later extended to light by Einstein. Schrödinger's wave equation came as a natural development of the first stream, while Heisenberg's matrix mechanics was presented as a unique proposal from the second stream. In spite of completely different appearances, the two theories proved, within a couple of years after their discoveries, to be equivalent. This is a most beautiful example that the physical reality exists independent of the mathematical framework formulated for its description. In this chapter, we will give a very brief review of the principles of quantum mechanics, 1–3 mainly with the harmonic oscillator as a model system for the following reasons. The first is historical: the electromagnetic wave, whose interaction with matter is the subject of this book, is a harmonic oscillator, a system which was for the first time subject to “quantization”, thus opening a way to the discovery of quantum mechanics. The second is technical: the harmonic oscillator is one of very few examples of analytically soluble problems in quantum mechanics. The third is pedagogical: the harmonic oscillator is a system best suited for realization of the equivalence of the two different pictures mentioned above and hence for a deeper understanding of the principles of quantum mechanics.
In 1923 Louis de Broglie (1892-1987) discovered the material waves and six years later received the Nobel price for this discovery. Apart these well known facts this French physicist nevertheless seems to be forgotten. Details of his life are as unknown as his efforts to describe quantum mechanics in a deterministic and objective way. Especially the actual discussion concerning the interpretation of quantum mechanics seems to justify a deeper occupation with the scientific work of Louis de Broglie. In this context the important influence of Albert Einstein is of special interest; for his photons announce the existence of material waves and it may surprise that Einstein himself did not postulate them. The basis of this short scientific biography are the publications of de Broglie (a complete bibliography is given at the end), some more or less short memories of his students and some unpublished documents found in the "Archives de l'Academie des Sciences" at Paris. The original text of the correspondence between de Broglie and Einstein is enclosed in German translation in the appendix.