Employing currently available quantum technology, we design and implement a nonclassically correlated SWAP heat engine that allows to achieve an efficiency above the standard Carnot limit. Such an engine also boosts the amount of extractable work, in a wider parameter window, with respect to engine's cycle in the absence of initial quantum correlations in the working substance. The boosted efficiency arises from a trade-off between the entropy production and the consumption of quantum correlations during the full thermodynamic cycle. We derive a generalized second-law limit for the correlated cycle and implement a proof-of-principle demonstration of the engine efficiency enhancement by effectively tailoring the thermal engine on a cloud quantum processor.
Employing currently available quantum technology, we design and implement a nonclassically correlated SWAP heat engine that allows to achieve an efficiency above the standard Carnot limit. Such an engine also boosts the amount of extractable work, in a wider parameter window, with respect to engine's cycle in the absence of initial quantum correlations in the working substance. The boosted efficiency arises from a trade-off between the entropy production and the consumption of quantum correlations during the full thermodynamic cycle. We derive a generalized second-law limit for the correlated cycle and implement a proof-of-principle demonstration of the engine efficiency enhancement by effectively tailoring the thermal engine on a cloud quantum processor.
Employing currently available quantum technology, we design and implement a non-classically correlated SWAP heat engine that allows to achieve an efficiency above the standard Carnot limit. Such an engine also boosts the amount of extractable work, in a wider parameter window, with respect to engine's cycle in the absence of initial quantum correlations in the working substance. The boosted efficiency arises from a trade-off between the entropy production and the consumption of quantum correlations during the full thermodynamic cycle. We derive a generalized second-law limit for the correlated cycle and implement a proof-of-principle demonstration of the engine efficiency enhancement by effectively tailoring the thermal engine on a cloud quantum processor.
The working substance fueling a quantum heat engine may contain prominent quantum properties such as coherence and nonclassical correlations. In particular, coherence has been somewhat related to quantum friction, whose origin has been mostly associated with the noncommutativity of a driven Hamiltonian at different times. Here, we consider a quantum Otto heat engine operated at finite time and undergoing incomplete thermalization with a heat source. We introduce analytical expressions relating the engine efficiency and extractable power to the coherence measured in the energy basis of the working substance during the engine cycle. We show that coherence, which has been related to an increase in entropy production and irreversibility, can in also be employed to improve the quantum engine performance, mitigating quantum friction. Such an improvement may be achieved by carefully tuning cycle parameters. To illustrate this coherent improvement we performed a numerical analysis in an experimentally feasible example.
Squeezed thermal reservoirs have been proposed as a route to boosting the efficiency and power of quantum heat engines beyond the standard Carnot bound, since squeezing injects an effective negative entropy that can, in principle, be converted into extra work. What remains poorly quantified is the entropy-production cost that driving a working qubit against a squeezed bath actually incurs once finite-time operation and reservoir decoherence are taken into account. We simulate a quantum Otto-cycle heat engine built from a two-level working system coupled alternately to a hot reservoir at temperature 4.2 K, squeezed with squeezing parameter r ranging from 0 to 1.2, and an unsqueezed cold reservoir at 0.8 K, integrating the Lindblad master equation across 42 combinations of squeezing parameter and cycle duration between 0.05 and 2.0 (in units of the inverse qubit gap). At r = 0, mean entropy production per cycle was 0.223 k_B, consistent with standard finite-time Otto-cycle behaviour, but rose to 0.361 k_B at r = 1.2, a 62% increase, even as extractable work per cycle increased by 41%, from 0.184 to 0.259 (in units of the qubit gap). The ratio of work output to entropy production, an effective thermodynamic figure of merit, was therefore not monotonic in squeezing: it peaked at r = 0.6, where work per unit entropy produced reached 0.98, 15% above the unsqueezed value of 0.85, before declining at higher squeezing as entropy production began to outpace the marginal work gain. Power output at the maximum-power cycle duration increased with squeezing across the full range tested, from 0.31 (gap units) at r = 0 to 0.52 at r = 1.2, a 68% gain, but efficiency at maximum power fell from 0.41 to 0.33 over the same range, a trade-off traced out in detail in Table 1. A decomposition of total entropy production attributed 58-71% to hot-bath coupling across all squeezing values, with the squeezed-bath contribution alone rising from undefined at r = 0 to 34% of hot-bath entropy production at r = 1.2, while coherence generated during the unitary strokes accounted for a comparatively stable 12-18% regardless of squeezing strength. These results indicate that reservoir squeezing in quantum heat engines delivers a genuine power and work advantage but at a non-negligible and squeezing-dependent entropy cost, with an intermediate squeezing level offering the best entropy-normalized performance rather than the strongest squeezing tested, a finding directly relevant to the design of squeezed-bath quantum thermal devices operating under realistic decoherence.
The laws of thermodynamics strongly restrict the performance of thermal machines. Standard thermodynamics, initially developed for uncorrelated macroscopic systems, does not hold for microscopic systems correlated with their environments. We here derive an exact formula for the efficiency of any cyclically driven quantum engine by using generalized laws of quantum thermodynamics that account for all possible correlations between all involved parties, including initial correlations. Furthermore, we demonstrate the existence of two basic modes of engine operation: the usual thermal case, where heat is converted into work, and an athermal regime, where work is extracted from entropic resources, such as system-bath correlations. In the latter regime, the efficiency is not bounded by the usual Carnot formula. Our results provide a unified formalism to determine the efficiency of correlated microscopic quantum machines.
We evaluate the role of quantum coherence as a thermodynamic resource in a noisy, Markovian, one-qubit heat engine. By consuming the coherence of noisy quantum states, we demonstrate that the engine can surpass the classical efficiency limit when operating according to a quantum Otto cycle. The engine's non-classical nature is demonstrated by its violation of the Leggett-Garg's temporal correlations inequality. Amplitude damping increases the extractable work under partial thermalization, thereby increasing the efficiency. In contrast, phase damping increases the extractable work under partial thermalization but reduces the efficiency. We implement the entire Otto cycle in a quantum circuit, simulating realistic amplitude and phase damping channels, as well as gate-level noise. We introduce an operational measure of the circuit's thermodynamic cost to establish a direct link between energy consumption and information processing in quantum heat engines.
Heat engines constitute the major building blocks of modern technologies. However, conventional heat engines with higher power yield lesser efficiency and vice versa and respect various power-efficiency trade-off relations. This is also assumed to be true for the engines operating in the quantum regime. Here we show that these relations are not fundamental. We introduce quantum heat engines that deliver maximum power with Carnot efficiency in the one-shot finite-size regime. These engines are composed of working systems with a finite number of quantum particles and are restricted to one-shot measurements. The engines operate in a one-step cycle by letting the working system simultaneously interact with hot and cold baths via semilocal thermal operations. By allowing quantum entanglement between its constituents and, thereby, a coherent transfer of heat from hot to cold baths, the engine implements the fastest possible reversible state transformation in each cycle, resulting in maximum power and Carnot efficiency. Finally, we propose a physically realizable engine using quantum optical systems.