In a previous note (1) we considered a free particle entropy based on the real part of the wavefunction exp(ipx) i.e. |cos(px)|. |cos(px|) may be normalized over a certain length, just as exp(ipx) is. The idea is that there exists an uncertainty in space within a wavelength which should be reflected in an entropy expression. As p becomes very large, cos(px) becomes very narrow and has many peaks in L. Thus probability →0 so p ln(p)--> 0 using l’Hopital’s rule. This coincides with a free classical particle having zero entropy. In this note, we revisit arguments presented previously, suggesting that A= -Et+px, a Lorentz invariant and also the free particle classical relativistic and nonrelativistic action for v=x/t We suggested in the past that A is responsible for both the wavelength hbar/p and the time period hbar/E. Here we suggest uncertainty within a time period should be considered together with uncertainty within a wavelength. For instance, recent experiments (2) have shown that one may have quantum interference in time as well as space. Thus there is uncertainty for a free particle in both space and time. We add the entropies for these two. Next, we consider the case of a bound system. Such a system creates a crest-trough pattern (with different heights and widths) for its spatial wavefunction, but E, average energy is constant and there is the free particle type exp(-iEnt). We suggest that the system is characterized by uncertainty in space and time with En being a known constant at each x. This suggests that various free particle p (momentum) values combine to create the wavefunction such that -1/2m d/dx d/dx W/W is average kinetic energy which in turn adds to V(x) to create a constant En. We are thus concerned with uncertainty in time and space and not in momentum. In the limit of high energy values, a crest fits within a tiny dx and prms is essentially the classical p value which is considered certain, even though in quantum mechanics the range of a(p) weights hold for all n (W(x)=Sum over p a(p)exp(ipx)). Thus we treat a high n limit as being completely certain and not having entropy. This differs from the approach of using C/v(x), where v(x) is velocity given by .5mv(x)v(x)+V(x)=En, as a probability and calculating Shannon’s entropy using this.
In a previous note (1) we considered a free particle entropy based on the real part of the wavefunction exp(ipx) i.e. |cos(px)|. |cos(px|) may be normalized over a certain length, just as exp(ipx) is. The idea is that there exists an uncertainty in space within a wavelength which should be reflected in an entropy expression. As p becomes very large, cos(px) becomes very narrow and has many peaks in L. Thus probability →0 so p ln(p)--> 0 using l’Hopital’s rule. This coincides with a free classical particle having zero entropy. In this note, we revisit arguments presented previously, suggesting that A= -Et+px, a Lorentz invariant and also the free particle classical relativistic and nonrelativistic action for v=x/t We suggested in the past that A is responsible for both the wavelength hbar/p and the time period hbar/E. Here we suggest uncertainty within a time period should be considered together with uncertainty within a wavelength. For instance, recent experiments (2) have shown that one may have quantum interference in time as well as space. Thus there is uncertainty for a free particle in both space and time. We add the entropies for these two. Next, we consider the case of a bound system. Such a system creates a crest-trough pattern (with different heights and widths) for its spatial wavefunction, but E, average energy is constant and there is the free particle type exp(-iEnt). We suggest that the system is characterized by uncertainty in space and time with En being a known constant at each x. This suggests that various free particle p (momentum) values combine to create the wavefunction such that -1/2m d/dx d/dx W/W is average kinetic energy which in turn adds to V(x) to create a constant En. We are thus concerned with uncertainty in time and space and not in momentum. In the limit of high energy values, a crest fits within a tiny dx and prms is essentially the classical p value which is considered certain, even though in quantum mechanics the range of a(p) weights hold for all n (W(x)=Sum over p a(p)exp(ipx)). Thus we treat a high n limit as being completely certain and not having entropy. This differs from the approach of using C/v(x), where v(x) is velocity given by .5mv(x)v(x)+V(x)=En, as a probability and calculating Shannon’s entropy using this.
The notion of entropy originates historically in classical physics and is intertwined with thermodynamics. Shannon’s entropy: - Sum over i P(i) ln(P(i)), where P(i) is the probability for i, however, seems to apply to any probability, but in quantum mechanics appears to be particularly linked to spatial and momentum entropy (1) i.e. - Integral dx W*(x)W(x) ln[ W*(x)W(x)] and - Sum over p a*(p)a(p) ln[ a*(p)a(p) ] where W(x)= wavefunction = Sum over p a(p) exp(ipx). In this note we speculate that one may create an entropy from the real part of exp(ipx) i.e. cos(px) as this term is associated with probability within a wavelength even though the “center of mass” of the particle may be moving uniformly at v=x/t=constant and W*(x)W(x)=1 or a constant. The latter implies an entropy independent of p but there is uncertainty in a free particle due to its wavelength which is experimentally manifested. We argue there is no reason to limit entropy to x or p considerations. For a bound state, a pattern of crests and troughs of different lengths and heights may be produced and so again there is a pattern of unnormalized probability distributions with different weights. The absolute value may be taken so negative wavefunction values are not an issue. For both the free particle and the bound state two features emerge. First the shape of the distributions is linked to the curvature which in turn is associated with the kinetic energy. Thus the probability distributions which describe the quantum system are governed by kinetic energy. Secondly, a pattern of distributions, both negative and positive, ensures that exp(ipx) is perpendicular to other exp(ip1 x) functions and Wn(x) is perpendicular to other Wn1(x)’s. In other words energy identifies the statistical state which exists throughout space and one cannot confuse the identity of one state with another. Thus they are orthogonal throughout space and probability distributions (linked to entropy) seem to enforce this. The inner product of W*(x) and W(x) is like an inner product of a product probability of a state and its time reversed state. We suggest one should be able to define a Shannon’s entropy expression for both |cos(px)|/C1 from exp(ipx) over a half wavelength where C1 is a normalization factor and |W(x)|/C2 roughly over the length over which it has humps i.e. roughly the classical turning points for an oscillator for example. This entropy is not additive and does not map to classical entropy in the large n (energy level) limit. Furthermore it may not be linked to thermodynamics because it is not linked to x or p. Nevertheless, it might be used to describe uncertainty within the quantity system and equilibrium/stable scenarios which are observed in nature. For example, different Wn(x) states are statistically stable states, but one may knock out the particle and it will be in an exp(ipx) state which is also stable. Furthermore, a photon may excite Wn1(x) to Wn2(x), thus this new entropy seems to be linked to stable states allowed in nature. The “price to pay”, however, seems to be uncertainty in wavelength regions for a free particle and the crest/trough regions for a bound state. We also consider some properties of a similar entropy for bound states.
In a classical bound state, conservation of energy: p(x)p(x)/2m + V(x) = E holds for all x. Examined in a statistical sense, one may consider each constant dx to have a probability density proportional to dt(x) where v(x)=velocity =dx/ dt(x). Thus the particle is followed in time. In quantum mechanics, even for a free particle exp(ipx), there exists a wavelength hbar/p. Within this region one cannot follow the particle in time. In fact, there are two probability distributions cos(px) and the shifted sin(px). The two dimensional nature of exp(ipx) is required to describe the direction of motion. There exists a mathematical abstraction or average which holds for any x within the wavelength and yields the classical x= p/m t. Thus there is a duality, but within a wavelength one cannot follow the particle exactly using x=p/m t. Rather there is no time and one thinks of probabilities to be at one x or another. The operator -id/dx yields the abstracted or average momentum at any x and (-id/dx)(-id/dx) average pp if one divides by probability. In other words: (-id/dx) exp(ipx)/ exp(ipx) = p and (-id/dx) (-id/dx) exp(ipx) / exp(ipx) = pp. These then apply to any x point. For a bound state, exp(ipx) is replaced with W(x)= Sum over p a(p)exp(ipx). Thus p and -p are included together. From a statistical point of view this is fine because a quantum bound state is described in terms of energy conservation (time-independent Schrodinger equation). Unlike the classical case, the probabilities of p and -p differ, i.e. exp(ipx) and exp(-ipx). The sum exp(ipx)+exp(-ipx) yields cos(px) which is the resolution probability distribution. Taking -d/dx d/dx of W(x) and then dividing by W(x) yields the average kinetic energy at any x within the wavelength. In other words this is the average kinetic energy which matches the classical result for any energy level. As a result, prms(x)prms(x)/2m + V(x) = En holds for any quantum level, but prms(x) is an rms average value which bypasses wave structure. That is why the exp(ipx) for p,-p and -id/dx must be used to calculate average quantities within a wavelength. Many different p,-p combinations are needed so that at each x within a wavelength the correct average kinetic energy value appears. Now consider a high energy level and choose a fixed dx length to represent a tiny region in the system, a cutoff for which there is no further resolution. p(x) is constant within this region. If hbar/ prms(x) <= dx, the wave structure of quantum mechanics does not play a role. (Note that for an oscillator, W(x) is a set of crests and troughs with different heights and widths.) As a result, there is no need for d/dx acting on W(x) to describe average kinetic energy within dx. The average kinetic energy is prms(x)prms(x)/2m and dx is treated like a point. Only if exp(ipx) is used does -id/dx yield the proper classical result. (An alternative scenario is that d/dx acting on a function divided by the function yields the same result as acting on exp(ipx) divided by exp(ipx) e.g. -d/dx d/dx cos(px)/cos(px) = -d/dx d/dx exp(ipx) / exp(ipx). If one has the quantum kinetic energy expression -1/2m d/dx dW/dx / W ((1)) and considers one momentum, namely prms(x), and uses W(x)= cos( prms(x) x), then with prms(x) constant at x, ((1)) yields prms(x) prms(x)/ 2m. Thus d/dx has not broken down even though it does not describe motion within dx which is now a point. A problem arises, however, if one considers Wn(x)= Wn1(x)Wn2(x) as this yields an equation containing dW1/dx dW2/dx/ (W1W2). Then the above procedure yields: dW1/dx/W1 (prms(x) sin(prms(x) x) / cos(prms(x) x). This does not match the classical value. Furthermore, dW2/dx/ W2 contains +prms(x) and -prms(x) with different weights while a classical scenario is -pP(-p,x) + pP(p,x) = 0 because P(-p,x)=P(p,x) while quantum mechanically it doesn’t. We analyze this situation and conclude that d/dx breaks down/ does not apply in the classical limit because it is used to calculate average values within a wavelength only. It only “works” if the effect of the derivative(s) on a function divided by the function is the same as the effect on exp(ipx) divided by exp(ipx). If a wavelength fits within dx, there is no need to calculate values at any lower x level and d/dx is not needed. In fact, there is a single prms(x) value in dx and the average time links different dx’s so that one follows the particle (on average in the sense that one ignores structure within each x) by x(t). As a practical consequence, using -id/dx together with the wavefunction W(x) can lead to problems in the classical limit because d/dx does apply. In short, using -id/dx operating on Wn(x) divided by Wn(x) leads to issues unless it produces the same effect as acting on exp(ipx) divided by exp(ipx).
In (1) the Wigner transform of an oscillator is calculated and the high n energy level limit taken using the WKB approximation yielding a result proportional to delta(p - p(x)) + delta(p+p(x)) where p(x) = sqrt(2m(E-.5kxx)). The Wigner transform involves quantum wavefunctions which for bound systems include +/- p components which interfere i.e. a(p)(exp(ipx) + exp(-ipx) for a(p)=a(-p). Classically, a bound particle moves to the right during one time interval and to the left during the other so there is no interference of +/-p. The quantum wavefunction retains +/-p interference for all energy levels and so does not portray the full physical information of the bound system i.e. leads to the two delta functions. For high n (energy level), crests and troughs are very narrow compared to the length of the system, approximating dx units of length. Thus, uncertainty in time is only within these tiny crests/troughs, otherwise there is a distinct time position relationship as in classical physics, but the wavefunction W(x) does not show it. How then may the wavefunction be interpreted? We argue the time independent wavefunction, say for a bound state, represents an averaged steady stream picture which is often not the physical picture. For example, a bound particle is not a steady stream average nor is a finite number of photons hitting an interface of media with different indices of refraction/reflection. Nevertheless, the steady stream approach with time removed may be used to solve the problem i.e. ultimately find a one dimensional spatial density (which averages out the original two dimensional probability of exp(ipx), energy levels etc. For instance, the energy levels of a bound system do not depend on following the particle in time. We raise this issue because we think it may have implications on the calculation of entropy in bound single particle quantum systems. In general, a spatial Shannon’s entropy is defined as: - W(x)W(x) ln[W(x)W(x)] (one dimensional problem). W(x) (wavefunction) is real because p/-p pieces interfere in a steady stream picture. A single bound particle, however, is not a steady stream picture. exp(ipx) is a dynamic probability equal to cos(px)+i sin(px) to indicate the direction of motion. Simply because exp(ipx)+exp(-px) removes the complex portion (i.e. for a steady state picture with a(p)=a(-p)) does not mean that this represents the full physical picture especially as energy levels become high and crests/troughs become narrower with respect to the overall system length it seems there is no justification for the steady stream interference picture.. In other words, using a real W(x) in a Shannon’s entropy expression treats one dimensional probability W(x) = bound wavefunction, but this is not the full probability in the picture, we argue. Full probability is two dimensional and demonstrates direction for many energy levels (especially high ones). For a free particle exp(ipx), cos(px) and sin(px) are essentially the same distribution. Thus cos(px)cos(px) describes the probability distribution in x. For W1(x)=Sum p>0 a(p)exp(ipx), Real(W1(x)) is not equal to Imaginary(W1(x)) because one does not have a simple shift of the real distribution to obtain the imaginary one. The real distribution is chosen to represent probability because the interference of exp(ipx), exp(-ipx) terms removes the imaginary piece, but it is removed only on average. If physically exp(ipx) and exp(-ipx) should not interfere, then one may need to take some kind of average of Real(W1(x))Real(W1(x)) and Imaginary(W1(x))Imaginary(W1(x)) and use this in Shannon’s entropy.
Quantum mechanics is concerned with measurement and we suggest that in a bound problem impulses due to momentum are the form of measurement which occurs in x space. The Lorentz invariant A= -Et+px, which is also the free particle relativistic or nonrelativistic action with v=x/t, associates energy = pp/2m with time and p with x. Creating eigenvalue equations yields id/dt exp(-iEt) = E exp(-iEt) and -id/dx exp(ipx) = p exp(ipx). P (momentum) is associated with physical impulses and with its own two dimensional probability distribution exp(ipx). E is associated with t and has its own distribution in time exp(-iEt) which implies that the same E holds for each x point without any notion of x probability associated with it. In classical physics, a momentum p exists in a tiny dx (dx→0). For exp(ipx), a p impulse may occur within hbar/p with different probabilities, so one cannot restrict the measurement of p to a tiny dx unless dx is of the order of hbar/p. Nevertheless energy exists at all x points. Given that p measurements occur through specific impulses at different x points with exp(ipx) probabilities, one must calculate an average energy using {Sum over p pp/2m a(p) exp(ipx)} / {Sum over p a(p)exp(ipx)} using the probability associated with the measurement of p in space i.e. exp(ipx). This adds to V(x) to yield a constant E at each x point. We suggest that weighted exp(ipx)s are used to calculate average energy at each x, because it is through impulse measurements that one determines p at different x values and hence the average energy. One may note that one does not calculate {Sum over p a(p)exp(ipx) p } / {Sum over p a(p)exp(ipx)}. An impulse hit is associated with a certain probability and this measurement in x yields information about the corresponding energy pp/2m. Each impulse hit also yields information about a time probability exp(-i ppt/2m), but only if the particle is knocked out of the bound system i.e. only if pp/2m is the only energy present, which is not the case for a single particle bound system.
The wavefunction for a quantum free particle is exp(-iEt + ipx) In this case, E and p are linked through either E=pp/2m (nonrelativistic case) or EE =pp + momo (relativistic case c=1). We argue that there are different interactions involved with E and p. P (momentum) is energy flow and is involved in impulse type interactions with a potential usually V(x). For V(x,t) matters are more complicated, but will also be discussed. The impulse hits are associated with exp(ipx) and lead to interfering plane waves and an overall crest-trough spatial scenario. There is a kinetic energy (nonrelativistic case) associated with each p, but a new overall energy En (n= eigenlevel) is created which yields the free form exp(-iEnt). This energy is linked to the cycling of exp(ipx)’s. It is also part of the new mass of the bound state system i.e. mo+En. This new system could be considered as an overall free particle and obtain a new overall momentum. (The initial bound state has 0 overall momentum.) Thus, time and space parts of the wavefunction behave in very different manners due to the nature of the interaction even though there is a link between 1/E and cycling of exp(ipx) terms. We call this case an impulse or space based type of interaction. It is also possible to have a time based interaction i.e. the absorption of a photon, phonon etc. In such a case, there is momentum conservation and so the whole system receives a new momentum, but this is usually ignored. The main effect is for the system to move from one bound state E(n1) to another E(n2). This has consequences on the spatial density and cycling of exp(ipx) terms in the wavefunction, but is not an impulse interaction in space. In the case of a system: W(x,t)= Sum over n an(En) exp(-iEnt) Wn(x), one has time based interactions which knock the system from one bound state to another (as in heat bath interaction). Again there are links between each En and the spatial density, but there is an overall spatial density(x,t) and average energy(x,t) which depends on the interference of exp(-iEnt) terms. (This disappears if one integrates over all x.) This is similar to the diffraction/interference spatial pattern, but in time. In the impulse scenario for a(p)=a(-p) one has cross terms in the spatial density of cos( (pi-pj)x) which create the crest/trough pattern seen. For the heat bath time type interaction, there exist cos( (Ei-Ej)t) type terms if an(En)=a*n(En) which are linked to the energy Ei-Ej of the intermediary photon/phonon etc and its time period. Thus in both cases, the quantum crest/trough pattern (in space or time) seems to be linked to the momentum or energy transfer. The energy transfer is known to be linked to periodic objects (photons/phonons) and it seems the momentum transfer pi-pj also has a similar periodicity, but in space. It is almost as if these “entities” are creating the unusual quantum crest/trough patterns.
The uncertainty principle (linked to p,x or E,t) plays an important role in quantum mechanics. For example, an electron with an exact momentum p is described by a wavefunction exp(ipx). This function exists at all x points and so it is suggested in the literature that there is complete uncertainty as to the electron’s position. (More specifically P(x)=exp(-ipx)exp(ipx) normalization constant=constant and so all x points have the same probability.) Thus if p is completely certain, it is said that position x is completely unknown. We note, however, that exp(ipx) consists of cos(px) and sin(px) which are repeated probability distributions (with zero endpoints). Thus even though they exist in all of space, due to repetition which in turn is due to spatial invariance, there is a specific length number, namely the wavelength. Thus we argue that in classical physics there is a set of points (x,p), but in quantum mechanics ( p , x with its dx interval), with the latter being equal to hbar/p. Then the only uncertainty is within the dx interval i.e. the wavelength and spatial density is linked to momentum i.e. there is dynamical probability. In particular, there is a frequency hbar/E and a wavelength hbar/p which define an internal clock and ruler and the two are independent. Thus within a wavelength one has a probabilistic picture (in order to have endpoints defining the dx interval) and no sense of time, yet on average time exists because of hbar/E and the particle moves in space with a constant v. This begs the question: How do time and space x arise in such a scenario? We speculate the following. Assume there exists a property called energy which defines an object. This object, however, may break into two different objects. As a result, one introduces a parameter called time to distinguish between the two systems (E) and (E1,E2). For a certain time range one has a single object, while for a later time interval, one has two objects. Each of the two objects in the second system, however, needs to be distinguished as well and so another parameter, namely space x is used for this. If the two objects existed at the same x and t, how would one know there were two unless another parameter were introduced? We use t and x as the distinguishing parameters and furthermore give these a measure i.e. dt and dx. We then argue that from these ideas one may show the notion of speed and direction (because there are two objects) as well as conservation of momentum arises. Given the notion of an interval, we argue it must be described by a probability distribution and we link this to constant/p and exp(ipx). We finally note that since spatial density is linked to dynamical probability, one must consider motion associated with a density which may lead even to collective motion.