The recent experimental advances in the field of quantum spin materials have led to well-controlled systems which can be used in order to simulate complex quantum models in a clean fashion. Here we discuss how fascinating effects normally known from bosonic systems such as the Bose-Einstein condensation can be investigated with the help of such materials. We discuss as an example how a crossover between an effectively one-dimensional geometry described by a Luttinger liquid to a three-dimensional Bose-Einstein condensation can be induced. Additionally, we point out how more complex phases as the Bose-glass phase could be realized in these quantum magnets. Introduction Although it can seem paradoxical, the quantum magnetic states found in insulators offer an interesting route to study Bose-Einstein condensation (BEC) and more generally phenomena related to itinerant, interacting bosonic systems. In many materials, the repulsion between the electrons causes the ground state to be a Mott insulator with one electron localized per site. In such a case, the charge degrees of freedom are completely locked by large charge gaps (usually of the order of tens of electron volts). However, one can study the fascinating physics of the spin degrees of freedom. As was shown a long time ago, the localized spins are coupled by a so-called superexchange which may be ferro- or antiferromagnetic. The properties of the exchange coupling between the spins depend mainly on the underlying atomic structure of the material. The resulting physics is extremely rich and such materials can have a host of phases ranging from ordered magnetic phases to so-called spin-liquid phases in which spin–spin correlations decay extremely fast with distance. The field of research concerning these materials, dubbed quantum magnetism, is thus an extremely active field in its own right [1]. Additionally, one can exploit the formal mapping that exists between spin operators and bosonic ones, as will be described in the next section, to connect the magnetic materials to itinerant bosonic systems with interactions between the bosons. This opens the way to use such quantum spin systems as quantum simulators. A quantum simulator means that the experimental system can be employed in order to “solve” in a controlled way a problem/Hamiltonian known from a different less controlled physical realization, e.g., inspired by fundamental many-body physics, quantum information or computational applications.
The recent experimental advances in the field of quantum spin materials have led to well-controlled systems which can be used in order to simulate complex quantum models in a clean fashion. Here we discuss how fascinating effects normally known from bosonic systems such as the Bose-Einstein condensation can be investigated with the help of such materials. We discuss as an example how a crossover between an effectively one-dimensional geometry described by a Luttinger liquid to a three-dimensional Bose-Einstein condensation can be induced. Additionally, we point out how more complex phases as the Bose-glass phase could be realized in these quantum magnets. Introduction Although it can seem paradoxical, the quantum magnetic states found in insulators offer an interesting route to study Bose-Einstein condensation (BEC) and more generally phenomena related to itinerant, interacting bosonic systems. In many materials, the repulsion between the electrons causes the ground state to be a Mott insulator with one electron localized per site. In such a case, the charge degrees of freedom are completely locked by large charge gaps (usually of the order of tens of electron volts). However, one can study the fascinating physics of the spin degrees of freedom. As was shown a long time ago, the localized spins are coupled by a so-called superexchange which may be ferro- or antiferromagnetic. The properties of the exchange coupling between the spins depend mainly on the underlying atomic structure of the material. The resulting physics is extremely rich and such materials can have a host of phases ranging from ordered magnetic phases to so-called spin-liquid phases in which spin–spin correlations decay extremely fast with distance. The field of research concerning these materials, dubbed quantum magnetism, is thus an extremely active field in its own right [1]. Additionally, one can exploit the formal mapping that exists between spin operators and bosonic ones, as will be described in the next section, to connect the magnetic materials to itinerant bosonic systems with interactions between the bosons. This opens the way to use such quantum spin systems as quantum simulators. A quantum simulator means that the experimental system can be employed in order to “solve” in a controlled way a problem/Hamiltonian known from a different less controlled physical realization, e.g., inspired by fundamental many-body physics, quantum information or computational applications.
Just a couple decades ago bosonic low-temperature physics was synonymous with one particular liquid at a temperature of several degrees Kelvin. This liquid, helium-4, and its famous Helium-II phase, has revealed remarkable quantum properties such as quantized vortices and second sound. Yet, despite many things learned by investigating helium, its study has certain limitations. On the one hand, helium is a strongly interacting liquid, which makes first-principles theoretical research challenging. To name one example, establishing a connection between the non-interacting condensate state described by Bose and Einstein, and the helium properties observed in the lab took decades. Furthermore, helium is a specific chemical element, and hence there is no surprise that its physical properties are fixed by nature. However, every particular chemical element has particular physical properties, so for a long time it seemed that it was as good as it gets. The picture has changed drastically when the first Bose-Einstein condensate (BEC) was observed in an ultracold atomic gas. “Low temperature” has become synonymous with “ultracold”, and the latter implies temperatures on the order of nanokelvins. Most strikingly, the relationship between what is fixed by nature and what is experimentally changeable has evolved. In particular, systems of different particle statistics, spin, and interactions have been engineered using ultracold vapours of various alkali atoms. This versatile manipulation not only makes emulating various condensed-matter physics models in a controlled system without impurities possible, but also opens a path towards novel phenomena that are at present not achievable in any other manner. In this thesis, we have explored some of the novel phenomena that arise in systems of bosonic particles with internal degrees of freedom, such as (pseudo)spin and electric dipole moment. In the introduction, we describe a ferromagnetically coupled spin-1/2 Bose gas with contact interactions in the mean- field approximation. In particular, we compute and discuss the phase diagram of this gas, since it is a simple system which nevertheless has two order parameters. In the chapters that follow, the ideas touched upon in the introduction are developed in more detail. In Chapter 2 we develop a hydrodynamic description of the ferromagnetic spin-1/2 Bose gas at arbitrary temperatures. We study magnetization relaxation and geometric forces. In particular, we consider the topological Hall effect due to the presence of a skyrmion. In Chapter 3 we investigate the miscible (non-ferromagnetic) spin-1/2 Bose gas at arbitrary temperatures, construct its hydrodynamic description, calculate the thermodynamic properties, and study the collective modes of this system. In Chapter 4 we discuss the influence of the off-diagonal Berry curvature on the Bose-Einstein condensation temperature. Finally, in Chapter 5 we study a Bose-Einstein condensate of dipolar molecules in a weak electric field and find it to be described by a quantum rotor model. Moreover, we show that the molecular Bose-Einstein condensate is a ferroelectric material that is fully disordered by quantum fluctuations.
At the time of the first workshop in this series in 1993, the only experimentally realized Bose condensate (at least in the simple sense conjectured by Einstein) was liquid 4 He. In the intervening twenty-plus years, much has happened in the world of Bose-Einstein condensation (BEC). Probably the most exciting development has been the attainment of condensation in ultracold bosonic atomic gases such as 87 Rb and 23 Na in 1995, followed a few years later by the achievement of degeneracy and eventually Bardeen-Cooper-Schrieffer (BCS) pairing in their fermionic counterparts, and the experimental realization of the theoretically long-anticipated “BEC-BCS crossover” by using the magnetic field degree of freedom to tune the system through a Feshbach resonance. One particularly fascinating aspect of the latter has been the realization of a “unitary gas” at the resonance itself – a system which prima facie has no characteristic length scale other than the interparticle separation, and is therefore a major challenge to theorists. Other systems in which BEC has been realized, sometimes transiently, include exciton-polariton complexes in semiconducting microcavities and, at least in a formal sense, the magnons in a magnetic insulator, as well as ultracold gases with a nontrivial and sometimes large “spin” degree of freedom. As compared with our “traditional” Bose condensate, liquid 4 He, these new systems typically have many more (and more rapidly adjustable) control parameters, and have therefore permitted qualitatively new types of experiment. One particularly fascinating development has been the use of optical techniques to generate “synthetic gauge fields” and thus mimic some of the topologically nontrivial systems which have recently been of such intense interest in a condensed-matter setting. At the same time, there remain long-standing issues from helium physics, such as the nature and consequences of “spontaneously broken U(1) symmetry,” the “Kibble-Zurek” mechanism, and more generally the relaxation of strongly nonequilibrium states to equilibrium; in some cases, the new systems have been used to address these more quantitatively than was possible with 4 He. The chapters in this volume address all of these questions and more, and should be of intense interest to both the experimental and the theoretical sides of the BEC community.
Bose-Einstein condensates (BECs) are a recent addition to the portfolio of quantum materials some of which have profound commercial and military applications e.g., superconductors, superfluids and light emitting diodes. BECs exist in the lowest motional modes of a trap and have the lowest temperatures achieved by mankind. With full control over the shape of the trap the experimentalist may explore an extremely diverse set of Hamiltonians which may be altered mid-experiment. These properties are particularly suited for realizing novel quantum systems. This thesis explores interaction-driven domain formation and the subsequent domain coarsening for two immiscible BEC components. Because quantum coherences associated with interactions in BECs can be derived from low energy scattering theory we compare our experimental results to both a careful simulation (performed by Brandon Anderson) and an analytical prediction. This result very carefully explores the question of how a metastable system relaxes at the extreme limit of low temperature. We also explore spin-orbit coupling (SOC) of a BEC which links the linear and discrete momentum transferable by two counterpropagating ``Raman'' lasers that resonantly couple the ground electronic states of our BECs. SOC is used similarly in condensed matter systems to describe coupling between charge carrier spin and crystal momentum and is a necessary component of the quantum spin Hall effect and topological insulators. SOC links the linear and discrete momentum transferable by two counterpropagating ``Raman'' lasers and a subset of the ground electronic states of our BEC. The phases of an effective 2-spin component spin-orbit coupling (SOC) in a spin-1 BEC are described in Lin et al. (2011). We measure the phase transition between two phases of a spin-1 BEC with SOC which cannot be mimicked by a spin-1/2 system. The order parameter that describes transitions between these two phases is insensitive to magnetic field fluctuations. I also describe a realistic implementation of Rashba SOC. This type of SOC is expected to exhibit novel many-body phases [Stanescu et al. 2008, Sedrakyan et al. 2012, Hu et al. 2011].
This thesis investigates the plausibility of producing a quantum spin liquid (QSL) with ultracold bosonic atoms optically confined to the Mott insulating state. QSLs have received a great deal of attention for being an antiferromagnetic groundstate with many exotic properties, including the absence of local order, long-range entanglement, and fractionalized excitations. However, the identification and characterization of these phases in solid state systems remains a great challenge. Here we outline an alternate route to uncovering the QSL phase, which from the nature of spin angular momentum for ultracold atoms encounters many properties unique to these systems along the way. This proposal is possible because the magnetic exchange interactions for Mott insulating ultracold atoms are mediated by the hopping of whole atoms. Whole-atom exchange—a unique property of cold atoms—allows large fluctuations between the quantized Zeeman sublevels of each atomic spin. As we demonstrate, these fluctuations increase when large-spin atoms are used, or when interactions are tuned via optical Feshbach resonance (OFR). These strong quantum spin fluctuations inhibit classical magnetic ordering, and lead to a QSL ground state. To illustrate the relationship between the spin magnitude, interaction strength, and QSL ground state, we present two distinct approaches to solving the relevant Hamiltonian. With mean field theory we find that for large spin (f > 2), and strong scattering through the spin-singlet channel, that magnetically-ordered Bose-Einstein condensates are unstable to the formation of a QSL. We then utilize Rayleigh-Schodinger perturbation theory to derive an effective Hamiltonian for our system in the Hilbert space of nearest-neighbor singlet coverings. At large spin this Hamiltonian produces a type of quantum dimer model (QDM), which are known to possess QSL phases. We derive the QDM parameters t, t′ and V as a function of spin on several lattices, finding they scale with the inverse number of Zeeman sublevels. We then determine the proximity of the physically accessible states to the QSL phase, and discuss how other regions of the phase diagram may be accessed. We then conclude by highlighting several advantages to studying QSLs and QDMs with ultracold bosons.
Bose–Einstein condensation is a quantum statistical phase transition that occurs in a system consisting of bosons when a single-particle quantum state becomes macroscopically occupied. This peculiar state of matter was first predicted in 1925 and finally realized seventy years later in vapours of weakly-interacting alkali-metal atoms. Since then, Bose–Einstein condensates have been one of the most fascinating research fields in modern physics. \n \nThe gaseous condensates offer a robust platform to accurately study interacting many-particle systems from the first principles. Experimentally, the possibility to precisely control a condensate with external fields and directly image its order parameter provides unforeseen opportunities to obtain deep insight into phenomena across different subfields of physics. In particular, gaseous condensates can emulate complicated models that arise in atomic, condensed-matter, and even particle physics, allowing realizations of exotic phenomena that are elusive in their original contexts. An outstanding example is the existence of various topological defects in ultacold quantum gases with internal degrees of freedom. \n \nIn this thesis, we investigate the creation, stability, and dynamical properties of various topological defects in spinor Bose–Einstein condensates. The majority of the theoretical results is obtained by numerically solving the dynamics using Gross–Pitaevskii equations for spin-1 condensates. Many theoretical predictions are confirmed by the very good agreement with experiments. \n \nThe first experimental observations of a topological point defect in an order parameter describing the quantum gas are presented. Such a point defect is reminiscent to the magnetic monopole particle appearing in grand unified theories. Therefore, the discovery of monopoles in quantum gases further encourages the quest for finding magnetic monopoles in natural electromagnetic fields, a search largely initiated by Paul Dirac almost a century ago. \n \nSubsequently, the fine structure and decay dynamics of the point defect are studied numerically and verified in experiments. The created monopole is gradually destroyed during the polar-to-ferromagnetic quantum phase transition, which results in the spontaneous emergence of a Dirac monopole in synthetic magnetic field. In addition to the singular point defect, the first experimental realization of a knot soliton in the context of quantum field is reported. This thesis lays the foundation for studies of the dynamics and stability of three-dimensional topological structures in quantum systems.
Quantum mechanically, static or applied gauge fields manifest themselves by directly coupling to a system's phase. Artificial gauge field techniques manipulate the phase of a Bose-Einstein condensate's order parameter, yielding effects present in condensed matter systems subject to magnetic fields, electric fields, or spin-orbit coupling. In this chapter, we explore the impact of these artificial gauge fields on Bose- Einstein condensates and explain the consequences. Several analogues to traditional condensed matter systems are enabled by these techniques, including the Hall effect, superfluid vortex nucleation in systems with artificial magnetic fields, and magnetic-like phase transitions in systems with spin-orbit coupling. Introduction Since the first experiments with Bose-Einstein condensates (BECs), researchers have exploited the universality of physical laws to draw analogies between the behavior of ultracold quantum gases and systems ranging from material to astrophysical. These analogous situations are deliberately engineered, giving cold-atom “quantum simulators” [1] that exhibit behavior either observed or predicted in analogous quantum systems. Superfluidity was one of the first many-body quantum phenomena demonstrated in BECs. For example, several experiments showed superfluid behavior by rapidly rotating the condensates and observing the formation of vortices [2, 3, 4, 5] – quantized point-defects in the BEC's order parameter. In the rotating frame of these experiments, this nucleation of vortices could be understood as the consequence of an artificial magnetic field [6] that arises via the formal equivalence of the rotating-frame Coriolis force and the Lorentz force, which we describe in Section 15.4.1. Together with other measurements, these results proved to be in excellent agreement with the predictions of the Gross-Pitaevskii equation (GPE) [7], a decades-old idealization of superfluid helium. Buoyed by the prospect for studying magnetic field–driven strongly correlated systems using these nearly ideal quantum gases, proposals for alternate techniques to simulate gauge fields were developed. These methods primarily employ an internal state–selective atom–light coupling, where the photon momentum provides the forces necessary to mimic a Lorentz force [8, 9, 10, 11, 12, 13, 14, 15, 16]. The first demonstration of this type of technique used a spatially dependent Ramantransition scheme to effect a magnetic field [17], and experiments demonstrating artificial electric fields [18] and spin-orbit coupling [19, 20, 21, 22, 23, 24] soon followed.