The Influence of Coherence on the First Law of Quantum Thermodynamics

Ji‐Yong Sung, Jae‐Ho Cheong

Mario Reis, Maron F. Anka, Vinicius Gomes de Paula +1 more

In quantum thermodynamics, the decomposition of energy exchanges into heat and work remains an open problem beyond weak-coupling and slow-driving regimes. Recent formulations have shown that quantum coherence introduces additional energy contributions whose thermodynamic interpretation is still under debate, raising fundamental questions about the structure of the quantum first law. In this work, we investigate this problem through a time-dependent perturbative framework applied to the first law of quantum thermodynamics. By expanding the thermodynamic quantities up to second order, we derive explicit perturbative corrections for work, heat, and coherence contributions. Our results show that the coherence term can be consistently decomposed into coherent heat and coherent work, demonstrating that quantum coherence does not require the introduction of an independent energetic contribution beyond heat and work. The formalism resolves inconsistencies associated with previous formulations of the quantum first law, including the interpretation of coherence contributions and their connection with entropy fluxes. At second order, the perturbative corrections become directly connected to transition rates governed by Fermi's golden rule, establishing a bridge between microscopic quantum transitions and macroscopic thermodynamic quantities. These results provide a physically transparent framework to investigate coherence-driven thermodynamic processes and offer new perspectives for the analysis of driven quantum systems and nonequilibrium quantum technologies.

Marino P. Lenzarini, Diogo O. Soares-Pinto

How quantum coherence influences thermodynamic behavior remains an open question in quantum thermodynamics. Here we investigate this relation within the pure dephasing framework, where a central qubit interacts with a finite Ising-like spin environment. Although the system's internal energy remains constant, the interaction induces decoherence and gives rise to nontrivial thermodynamic features. Within the two-point measurement approach, we show that the heat dissipated into the environment matches the coherent energy contribution appearing in a reformulated first law of quantum thermodynamics. Numerical calculations reveal oscillatory coherence dynamics, with revivals associated with information backflow and non-Markovian effects, as quantified by the Breuer-Laine-Piilo measure. We find that heat and coherence exhibit intertwined temporal behavior, with enhanced heat dissipation during coherence decay and reduced heat during revivals. These results suggest a connection between coherence dynamics and thermodynamic quantities in finite, closed composite systems undergoing pure dephasing.

Aslı Tuncer, Özgür Esat Müstecaplıoğlu

Ian T. Durham

Bertúlio de Lima Bernardo

One of the fundamental questions in the emerging field of quantum thermodynamics is the role played by coherence in energetic processes that occur at the quantum level. Here we address this issue by investigating two different quantum versions of the first law of thermodynamics, derived from the classical definitions of work and heat. By doing so, we find out that there exists a mathematical inconsistency between both scenarios. We further show that the energetic contribution of the dynamics of coherence is the key ingredient to establish the consistency. Some examples involving two-level atomic systems are discussed in order to illustrate our findings.