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Thermal properties and quantum information theory with the shifted Morse potential

M. E. Udoh, P. O. Amadi, U. S. Okorie, Akaninyene Daniel Antia, Lewis F. Obagboye, R. Horchani, Nidhal Sulaiman, A. N. Ikot

Published Nov 18, 2022• 11 citations
Publisher

Abstract

By employing the Nikiforov–Uvarov functional analysis (NUFA) method, we solved the radial Schrödinger equation with the shifted Morse potential model. The analytical expressions of the energy eigenvalues, eigenfunctions and numerical results were determined for selected values of the potential parameters. Variations of different thermodynamic functions with temperature were discussed extensively. Different quantum information-theoretic measures, including Shannon entropy, Fisher information and Fisher–Shannon product of the shifted Morse potential, were investigated numerically and graphically in position and momentum spaces for the ground and the first excited states. The quantum information theories considered satisfied their corresponding inequalities, including Bialynicki–Birula–Mycielski, Stam–Cramer–Rao inequalities and the Fisher–Shannon product relation.

DOI
10.1007/s12043-022-02463-3

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In this research, the radial Schrödinger equation for a newly proposed screened Kratzer–Hellmann potential model was studied via the conventional Nikiforov–Uvarov method. The approximate bound state solution of the Schrödinger equation was obtained using the Greene–Aldrich approximation in addition to the normalized eigenfunction for the new potential model, both analytically and numerically. These results were employed to evaluate the rotational–vibrational partition function and other thermodynamic properties for the screened Kratzer–Hellmann potential. The results obtained have been graphically discussed. Also, the normalized eigenfunction has been used to calculate some information-theoretic measures including Shannon entropy and Fisher information for low-lying states in both position and momentum spaces numerically. The Shannon entropy results obtained agreed with the Bialynicki-Birula and Mycielski inequality, while the Fisher information results obtained agreed with the Stam, Cramér–Rao inequality. Also, alternating increasing and decreasing localization across the screening parameter for both eigenstates was observed.
The approximate solutions of the Schrödinger equation with the central generalized Hulthén and Yukawa potential are investigated within the framework of the functional method. The obtained wave function and the energy levels are used to study the Shannon entropy, Renyi entropy, Fisher information, Shannon Fisher complexity, Shannon power and Fisher-Shannon product in both position and momentum spaces for the ground and first excited states. The theoretic information theories such as Shannon entropies Sr,Sp, Fisher information Ip,Ip and Renyi entropies Rβ as well as the information entropy probability densities ρ(r),ϕ(p) are illustrated graphically. The Bialynicki-Birula – Mycielski (BBM) inequality for the Shannon entropies and the Cramer-Rao inequality for the Fisher information are satisfied for the potential model.
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Abstract The Shannon entropy (S) and the Fisher Information (I) entropies are investigated for a generalized hyperbolic potential in position and momentum spaces. First, the Schrodinger equation is solved exactly using the Nikiforov‐Uvarov‐Functional Analysis method to obtain the energy spectra and the corresponding wave function. By Fourier transforming the position space wave function, the corresponding momentum wave function was obtained for the low‐lying states corresponding to the ground and first excited states. The positions and momentum of Shannon entropy and Fisher Information entropies were calculated numerically. Finally, the Bialynicki‐Birula and Mycielski and the Stam‐Cramer‐Rao inequalities for the Shannon entropy and Fisher Information entropies, respectively, were tested and were found to be satisfied for all cases considered.
A Schrödinger equation is solved for a cotangent hyperbolic potential using the elegant parametric Nikiforov–Uvarov method. The results obtained are used to calculate the Fisher information for position space and momentum space as well as the Shannon entropy for position space and momentum space at the ground state. The energies of the cotangent potential are observed to be fully bounded for different quantum states. The Fisher information satisfied the Fisher relation known as Cramer–Rao inequality for the Fisher product. Its result also obeyed the Heisenberg principle as its alternative for uncertainty measurement. However, the Shannon entropy only satisfied the Bialynick-Birula, Mycielski inequality for higher values of the screening parameter. Its relation to the Heisenberg principle failed as both the position space and the momentum space are parallel with high entropy squeezing. This potential has not been reported for any system to the best of our understanding.
This study presents a comprehensive investigation of quantum information measures for the one-dimensional Ultra Generalized Exponential–Hyperbolic Potential (UGEHP) within the framework of the Schrödinger equation. Analytical solutions for the energy eigenvalues and corresponding wave functions are obtained using the Nikiforov–Uvarov method. These solutions serve as the basis for evaluating Shannon entropy and Fisher information in both position and momentum spaces. The numerical results show that the total Shannon entropy satisfies the Beckner–Białynicki-Birula–Mycielski (BBM) inequality, while the Fisher information adheres to the Stam–Cramér–Rao bounds, thereby confirming consistency with fundamental quantum uncertainty principles. In addition, the energy spectrum exhibits a pronounced dependence on the screening parameter and quantum numbers, indicating the tunable confinement properties of the potential. The combined analysis establishes a clear connection between energy quantization, wavefunction localization, and information-theoretic measures, offering deeper insight into the effectiveness of the UGEHP model in describing complex quantum systems.