Newtonian mechanics or classical mechanics in its simplest form, known as the laws of mechanics is written in terms of particle trajectories. The trajectory underlies the structure of classical physics and the particle underlies the model of physical reality. Newtonian mechanics has taken such strong roots and everybody believed that everything in this universe can be explained on the basis of these laws. In 1897, the British Physicist J. J. Thompson demonstrated that the beam that leaves the cathode, the so-called cathode rays, consists of a beam of negatively charged discrete particles. Wien equation gives excellent agreement with experiment in the region of short wavelengths and the Rayleigh-Jeans equation appears to be asymptotically correct at long wavelengths. In 1887, Hertz observed photoelectric effect and the first outstanding application of quantum theory was in its explanation by Albert Einstein in 1905.
Newtonian mechanics or classical mechanics in its simplest form, known as the laws of mechanics is written in terms of particle trajectories. The trajectory underlies the structure of classical physics and the particle underlies the model of physical reality. Newtonian mechanics has taken such strong roots and everybody believed that everything in this universe can be explained on the basis of these laws. In 1897, the British Physicist J. J. Thompson demonstrated that the beam that leaves the cathode, the so-called cathode rays, consists of a beam of negatively charged discrete particles. Wien equation gives excellent agreement with experiment in the region of short wavelengths and the Rayleigh-Jeans equation appears to be asymptotically correct at long wavelengths. In 1887, Hertz observed photoelectric effect and the first outstanding application of quantum theory was in its explanation by Albert Einstein in 1905.
Newtonian mechanics is the foundation of Classical Physics. Newton’s mechanics, Thermodynamics, Wave theory of Optics and Maxwell’s electromagnetic theory belong to regime of Classical Physics and can be used to explain a wide range of phenomena in the Universe at macroscopic scale. These theories fail spectacularly when applied to phenomenain the atomic and nuclear regime, for example, proton-atom scattering or the flow of electrons in a semiconductor. Quantum mechanics is the most successful scientific theory that has ever been created and it has completely changed our view of the world. The failure of Classical Physics was highlighted by black body radiation and photoelectric effect. Max Planck and Albert Einstein provided explanations of both phenomena based on quantum hypothesis and are thus considered founders of Quantum Physics. The origin of quantum mechanics goes back to the mid-1920s.It was formulated first as matrix mechanics by Werner Heisenberg, Max Born and Pascual Jordan; then as wave mechanics by Louis de Broglie and Erwin Schrödinger; and later on asquantum statistics of subatomic particles by Fermi-Dirac and Bose-Einstein. Combining relativistic mechanics with quantum mechanics, Dirac formulated his relativistic quantum mechanics during 1930s. Uncertainty Principle is thecornerstone of Quantum Physics. The role of randomness in microscopic physical processes shatters the myth that the universe is deterministic. Quantum world is unpredictable in the classical sense and demolishes the idea of an objective universe. The Copenhagen interpretation remains the quantum mechanical formalism that is currently most widely accepted amongst physicists.Quantum theories support cosmic spirit pervading the cosmos and inter – relationship of individuals in the world society. Quantum philosophy is holistic and is going to revolutionize our world-view.
By the end of the nineteenth century all the important elements of classical physics were fully mature. Newton's Laws had been applied with success to everything from industrial machines to planetary orbits. Classical thermodynamics had extended energy conservation arguments into thermal processes, and scientists including J. Willard Gibbs and Ludwig Boltzmann had developed the statistical interpretation of entropy. James Clerk Maxwell had explained all electromagnetic phenomena, from AC generators/motors to light, with the four Maxwell's equations and three material-dependent constitutive relations. There was serious discussion that physics was on the verge of being “finished” – becoming a closed system of knowledge like classical geometry with only essentially routine tasks left of determining how the known laws could be applied to engineering problems. Yet by 1930 the foundations of mechanics, electromagnetics, and atomic-scale systems had been shaken to the core by the new revolutions in the Theory of Relativity, the photon picture of light, and quantum physics. We are still reaping the benefits of the application of these new scientific paradigms in our technology today, including semiconductor electronic devices, lasers, and GPS systems. But the description of reality that these theories provide is still deeply anti-intuitive and disturbing. Nevertheless, quantum physics is one of the most extensively experimentally verified theories that we know. Even when quantum theory and common sense seem to diverge, quantum theory gives the right answers when tested by experiment. In the next chapter we will develop the framework of quantum theory that has been so successful when people “shut up and calculate,” as one scientist suggested as the way through the philosophical thicket of quantum physics. But in this chapter, we will spend a brief time considering the historical development and continuing paradoxical implications of quantum theory. The photoelectric effect and photons In 1905, Albert Einstein, who was a key figure in the revolution of modern physics, was working as a clerk in the patent office in Zurich, Switzerland. Einstein had finished his studies in physics, but had not obtained a coveted position as a university professor. He was intensely interested in the latest developments in classical physics and was aware of a few of the remaining loose ends that were resisting explanation in the classical model.
Science has developed through a variety of investigations more or less over the time scale of human existence. On this scale, quantum mechanics is an extremely young field, existing essentially for only just over a century. Even our understanding of classical mechanics has existed for a comparatively long period—roughly having been formalized with Newton's equations published in his Principia Mathematica , in April 1686 (1687). Up until the very end of the nineteenth century, mechanics in the form of Newton's laws were comfortable, being understood and accepted by all who dealt with the motion of reasonable bodies. With the turn of the new century, however, mechanics would be shaken to its roots. The change began already on December 14, 1900, when Planck (1900) presented his new theory of black-body radiation to the German Physical Society, and this change would affect mechanics in physically small structures (and lead to quantum mechanics). Mechanics of large bodies would similarly be changed in 1905 with the arrival of Albert Einstein's (1905a) relativity theory. In this book, we will deal with only the first of these two great breakthroughs.
Introduction It is believed that the basic physical building blocks forming the world we live in may be categorized into particles of matter and carriers of force between matter. All known elementary constituents of matter and transmitters of force are quantized. For example, energy, momentum, and angular momentum take on discrete quantized values. The electron is an example of an elementary particle of matter, and the photon is an example of a transmitter of force. Neutrons, protons, and atoms are composite particles made up of elementary particles of matter and transmitters of force. These composite particles are also quantized. Because classical mechanics is unable to explain quantization, we must learn quantum mechanics in order to understand the microscopic properties of atoms – which, for example, make up solids such as crystalline semiconductors. Historically, the laws of quantum mechanics have been established by experiment. The most important early experiments involved light. Long before it was realized that light waves are quantized into particles called photons, key experiments on the wave properties of light were performed. For example, it was established that the color of visible light is associated with different wavelengths of light. Table 2.1 shows the range of wavelengths corresponding to different colors. The connection between optical and electrical phenomena was established by Maxwell in 1864. This extended the concept of light to include the complete electromagnetic spectrum. A great deal of effort was, and continues to be, spent gathering information on the behavior of light.
We tried to introduce the idea of quantization in Chapter 9 as a completion of a one semester course. However, we skipped over some really interesting events in the history of Science between 1900 and 1913 when Bohr derived the quantized energy of the H atom. First we want to carry out the 1901 Planck derivation of the formula for blackbody radiation [1]. Many texts just show the curve, write e¼ hn, and move on. As a student, this author found that limited explanation very frustrating since energy quantization is a fundamental concept. Even among graduate texts in quantum mechanics, we are aware of only one that does the complete treatment which we will draw upon for the mathematics [2] but supplement with a narrative that we have found helpful to students over the years. Then in 1905, Albert Einstein (1879-1955), one of the most influential scientists of all time, gave an explanation of the photoelectric effect [3] for which he received the Nobel Prize in 1921. Even reducing our list to essential topics, we need to discuss the Davisson-Germer experiment [4]. The photoelectric effect introduces the idea that light waves can act as particles while the Davisson-Germer experiment showed that particles can act like waves and confirmed the De Broglie equation [5]. However, you can be assured that it will not be as difficult as you might have anticipated and if you can absorb the meaning of just these three key experiments you should be able to begin thinking in terms of quantum mechanics! Despite our slow historical development, this is 2010 and we have to get to the twenty-first century somehow!
This chapter deals with the important experimental studies on black-body radiation, Wein’s law, Rayleigh–Jeans law, Planck’s distribution law, etc. The black-body radiation studies reveal that the maximum wavelength of radiation 1 is inversely proportional to temperature T . The expression for Wein’s law has been deduced on the basis of thermodynamic considerations. The law gives a clue to understand that it holds true only at low temperatures and short wavelengths. The Rayleigh–Jeans law is based on the general theorem of elasticity and is in excellent quantitative agreement with experimental observations for large wavelengths and high temperatures, leading to ultraviolet ‘catastrophe’. Actually, Max Planck enunciated the correct form of the temperature–radiation law based on some assumptions and finally proposed Planck’s quantum theory. This chapter also explains the photoelectric effect and important conclusions drawn on the basis of experimental facts. Einstein applied the quantum theory to explain the photoelectric effect and to define threshold frequency. On the basis of plot of frequency of radiation versus voltage applied, a linear graph was obtained, which enabled finding the value of Planck’s constant h. The Compton effect has also been written in a lucid manner involving the mathematical formulation from which the Compton shift can easily be obtained. This chapter also details the atomic hydrogen spectrum including Bohr’s model of an atom, energy of electron revolving around the nucleus, radius of an orbit and expression for velocity of electron. It also mentions the drawbacks of Bohr’s theory. References, problems, and questions on this concept are provided at the end of the chapter.