We tried to introduce the idea of quantization in Chapter 9 as a completion of a one semester course. However, we skipped over some really interesting events in the history of Science between 1900 and 1913 when Bohr derived the quantized energy of the H atom. First we want to carry out the 1901 Planck derivation of the formula for blackbody radiation [1]. Many texts just show the curve, write e¼ hn, and move on. As a student, this author found that limited explanation very frustrating since energy quantization is a fundamental concept. Even among graduate texts in quantum mechanics, we are aware of only one that does the complete treatment which we will draw upon for the mathematics [2] but supplement with a narrative that we have found helpful to students over the years. Then in 1905, Albert Einstein (1879-1955), one of the most influential scientists of all time, gave an explanation of the photoelectric effect [3] for which he received the Nobel Prize in 1921. Even reducing our list to essential topics, we need to discuss the Davisson-Germer experiment [4]. The photoelectric effect introduces the idea that light waves can act as particles while the Davisson-Germer experiment showed that particles can act like waves and confirmed the De Broglie equation [5]. However, you can be assured that it will not be as difficult as you might have anticipated and if you can absorb the meaning of just these three key experiments you should be able to begin thinking in terms of quantum mechanics! Despite our slow historical development, this is 2010 and we have to get to the twenty-first century somehow!
We tried to introduce the idea of quantization in Chapter 9 as a completion of a one semester course. However, we skipped over some really interesting events in the history of Science between 1900 and 1913 when Bohr derived the quantized energy of the H atom. First we want to carry out the 1901 Planck derivation of the formula for blackbody radiation [1]. Many texts just show the curve, write e¼ hn, and move on. As a student, this author found that limited explanation very frustrating since energy quantization is a fundamental concept. Even among graduate texts in quantum mechanics, we are aware of only one that does the complete treatment which we will draw upon for the mathematics [2] but supplement with a narrative that we have found helpful to students over the years. Then in 1905, Albert Einstein (1879-1955), one of the most influential scientists of all time, gave an explanation of the photoelectric effect [3] for which he received the Nobel Prize in 1921. Even reducing our list to essential topics, we need to discuss the Davisson-Germer experiment [4]. The photoelectric effect introduces the idea that light waves can act as particles while the Davisson-Germer experiment showed that particles can act like waves and confirmed the De Broglie equation [5]. However, you can be assured that it will not be as difficult as you might have anticipated and if you can absorb the meaning of just these three key experiments you should be able to begin thinking in terms of quantum mechanics! Despite our slow historical development, this is 2010 and we have to get to the twenty-first century somehow!
The important discoveries and events that occurred in the development of quantum mechanics may be ordered as follows: Blackbody radiation formulated by Max Planck in 1901. Photoelectric effect interpreted by Albert Einstein in 1905. Model of the atom proposed by Ernest Rutherford in 1911. Quantum theory of atomic spectra developed by Niels Bohr in 1913. Photon–electron scattering experiments done by Arthor Holly Compton in 1922. Exclusion principle proposed by Wolfgang Pauli in 1925. Matter waves proposed by Prince Louis Victor de Broglie in 1925. Wave equation proposed by Erwin Shrödinger in 1926. Electron diffraction experiments done by Clinton Joseph Davisson and L.H. Germer in 1927. Uncertainty principle proposed by Werner Karl Heisenberg in 1927. Interpretation of the wave function done by Max Born in 1927. Relativistic wave equation proposed by Paul A. M. Dirac in 1928.
This chapter starts with the historical development of quantum mechanics and explanations of key concepts behind fundamental discoveries such as Planck's hypothesis, the photoelectric effect, Bohr's atomic model, Compton scattering, the de Broglie hypothesis, the Pauli exclusion principle, the Schrödinger equation, Heisenberg quantum mechanics and the uncertainty principle, the Born interpretation of wave function, the Davisson and Germer experiment, and Dirac relativistic quantum mechanics, which made important contributions to the foundation of modern quantum mechanics. Concepts like the particle properties of radiation, the wave properties of matter, quantized energy and momentum, and the idea that one can no longer know exactly where a single particle like an electron is at any instant of time are brought out clearly through this chapter. A list of important quantum mechanical parameters along with solved examples and unsolved exercises on the key concepts are included towards the end.
Einstein’s 1905 paper on the photoelectric effect, in which he considered Planck’s idea of quanta of energy to be a universal characteristic of light, marks the beginning of quantum theory. For over ten years Einstein stood alone on the issue of energy quantization of light; and although in 1915 experimental conrmation of his photoelectric effect came from painstaking experiments performed by Millikan, acceptance of the idea that light was composed of particles was far from universal. Millikan himself wrote in 1915: “Despite … the apparent complete success of the Einstein equation, the physical theory of which it was designed to be the symbolic expression is found so untenable that Einstein himself, I believe, no longer holds to it.” Einstein did hold to it. It was only in the mid 1920s, when Heisenberg, Schrödinger, Dirac, and others developed the rst forms of quantum theory, that serious discussions concerning the particle nature of light and the meaning of the new theory began. Discussions about the meaning of quantum theory continue today.
The first objective of this chapter is to briefly review some of the basic ideas about the structure of matter, in particular the concepts of microscopic physics, in order to recall the knowledge gained in previous physics (and chemistry) courses and make it more precise. Our review will be very concise, and most statements will be made without any proof or detailed discussion. A second objective is to give a brief description of some of the crucial stages in the early development of quantum physics. We shall not follow the strict historical order of this development or present the arguments used at the beginning of the last century by the founding fathers of quantum mechanics; rather, we shall stress the concepts which we shall find useful later on. Our last objective is to give an elementary introduction to some of the basic ideas, like those of a quantum particle or energy level, that will reappear throughout this text. We shall base our review on the Bohr theory, which provides a simple, though far from convincing, explanation of how energy levels are quantized and how the spectrum of the hydrogen atom arises. This chapter should be reread later on, once the basic ideas of quantum mechanics have been made explicit and illustrated by examples. From the practical point of view, it is possible to skip the general considerations of Sections 1.1 and 1.2 at the first reading and begin with Section 1.3, returning to those two sections later on as needed.
The behavior of light and its interaction with matter is certainly one of the most interesting phenomena of physics. It has puzzled thinkers and scientists in ancient Greece (Archimedes) and through the Middle Ages, at least since the times of Robert Grosseteste (1168–1235), right up to the theories of Galileo Galilei and Isaac Newton. The classical electromagnetic theory of light (see Tab. 13.1) was beautifully established in the second half of the nineteenth century with the Maxwell equations. Quantum optics is nothing other than the quantum theory of light. It finds its roots in Planck's discovery (1900) that the assumption of energy quantization for a harmonic oscillator allowed us to solve the black-body problem (see Subsec. 1.5.1). The successive early steps that led to the quantization of the electromagnetic field include Einstein's explanation of the photoelectric effect with the introduction of the quantum of light (see Subsec. 1.2.1) and the interpretation of atomic spectra (see Subsec. 1.5.4). Quantum optics is usually not covered by conventional textbooks on quantum mechanics. We include its discussion here for two main reasons: first, because it is a fundamental and advanced application of the basic framework of quantum mechanics, and, second, because in the last 30 years quantum optics has played (and is still playing) a major role in the advancement and understanding of quantum mechanics.
Toward the end of the nineteenth century, it became clear that some experiments cannot be explained on the basis of known physics, now referred to as classical physics. In 1900, Max Planck was able to correctly describe the distribution of blackbody radiation energy as a function of wavelength λ or frequency ν = c/λ. He had to accept the existence of energy packets (quanta) with energy E = hν. A few years later, Albert Einstein found that this unexpected relation between energy and frequency is also necessary in order to understand photoemission from metallic surfaces. A decade later, Niels Bohr arrived at the correct equation for the electronic spectrum of the hydrogen atom by applying “quantum conditions” on the motion of the electron around the nucleus and the Planck’s relation E = hν on the energy difference between the energy levels (1916). A decade later, Heisenberg, Born, and Jordan introduced “quantum mechanics” and de Broglie and Schrödinger (1925-1926) introduced “wave mechanics.”