At the beginning of the twentieth century, it became clear that microscopic particles do not obey Newton's laws of classical mechanics. The idea of light quanta was at odds with the established wisdom that light is a wave phenomenon, of course, but no other explanation of the photoelectric effect seemed possible. The next step in the development of quantum mechanics was taken by Niels Bohr, who introduced postulates about the discreteness of the energy of the bound electrons in an atom similar to the discreteness of the energy of light quanta. Modern quantum mechanics was founded by Werner Heisenberg, Max Born, Erwin Schroedinger, Paul Adrian Maurice Dirac, Wolfgang Pauli, Enrico Fermi, and others. In quantum mechanics, it is in general fundamentally impossible to determine the exact outcome of an experiment; one can only determine the probability of any given outcome.
At the beginning of the twentieth century, it became clear that microscopic particles do not obey Newton's laws of classical mechanics. The idea of light quanta was at odds with the established wisdom that light is a wave phenomenon, of course, but no other explanation of the photoelectric effect seemed possible. The next step in the development of quantum mechanics was taken by Niels Bohr, who introduced postulates about the discreteness of the energy of the bound electrons in an atom similar to the discreteness of the energy of light quanta. Modern quantum mechanics was founded by Werner Heisenberg, Max Born, Erwin Schroedinger, Paul Adrian Maurice Dirac, Wolfgang Pauli, Enrico Fermi, and others. In quantum mechanics, it is in general fundamentally impossible to determine the exact outcome of an experiment; one can only determine the probability of any given outcome.
Toward the end of the nineteenth century, it became clear that some experiments cannot be explained on the basis of known physics, now referred to as classical physics. In 1900, Max Planck was able to correctly describe the distribution of blackbody radiation energy as a function of wavelength λ or frequency ν = c/λ. He had to accept the existence of energy packets (quanta) with energy E = hν. A few years later, Albert Einstein found that this unexpected relation between energy and frequency is also necessary in order to understand photoemission from metallic surfaces. A decade later, Niels Bohr arrived at the correct equation for the electronic spectrum of the hydrogen atom by applying “quantum conditions” on the motion of the electron around the nucleus and the Planck’s relation E = hν on the energy difference between the energy levels (1916). A decade later, Heisenberg, Born, and Jordan introduced “quantum mechanics” and de Broglie and Schrödinger (1925-1926) introduced “wave mechanics.”
The founding fathers of quantum mechanics had already perceived the essence of the difficulties of quantum mechanics; today, after almost a century, the discussions are still lively and, if some very interesting new aspects have emerged, at a deeper level the questions have not changed so much. What is more recent, nevertheless, is a general change of attitude among physicists: until about 1970 or 1980, most physicists thought that the essential questions had been settled, and that “Bohr was right and proved his opponents to be wrong”. This was probably a consequence of the famous discussions between Bohr, Einstein, Schrödinger, Heisenberg, Pauli, de Broglie, and others (in particular at the Solvay meetings [1–3], where Bohr's point of view had successfully resisted Einstein's extremely clever attacks). The majority of physicists did not know the details of the arguments. They nevertheless thought that the standard “Copenhagen interpretation” had clearly emerged from the infancy of quantum mechanics as the only sensible attitude for good scientists. This interpretation includes the idea that modern physics must contain indeterminacy as an essential ingredient: it is fundamentally impossible to predict the outcome of single microscopical events; it is impossible to go beyond the formalism of the wave function (or its generalization, the state vector ∣ψ) and complete it.
Abstract The events that led to the formulation of the laws of quantum mechanics are presented. Quantum revolution took place in two phases. In the first phase, three important developments took place. Max Planck explained the radiation emitted by heated objects via a quantum postulate, Albert Einstein explained the emission of electrons when light shines on metals by treating light as consisting of photons, and Niels Bohr developed a model for the hydrogen atom by invoking a quantum postulate. In the second phase, Heisenberg and Schrödinger formulated the laws of quantum mechanics that could not only explain all the known phenomena but predict many others.
Einstein’s 1905 paper on the photoelectric effect, in which he considered Planck’s idea of quanta of energy to be a universal characteristic of light, marks the beginning of quantum theory. For over ten years Einstein stood alone on the issue of energy quantization of light; and although in 1915 experimental conrmation of his photoelectric effect came from painstaking experiments performed by Millikan, acceptance of the idea that light was composed of particles was far from universal. Millikan himself wrote in 1915: “Despite … the apparent complete success of the Einstein equation, the physical theory of which it was designed to be the symbolic expression is found so untenable that Einstein himself, I believe, no longer holds to it.” Einstein did hold to it. It was only in the mid 1920s, when Heisenberg, Schrödinger, Dirac, and others developed the rst forms of quantum theory, that serious discussions concerning the particle nature of light and the meaning of the new theory began. Discussions about the meaning of quantum theory continue today.
[I] think I can safely say that nobody understands quantum mechanics. Richard Feynman, The Character of Physical Law Quantum mechanics [is] that mysterious, confusing discipline, which none of us really understands but which we know how to use. It works perfectly, as far as we can tell, in describing physical reality, but it is a ‘counter-intuitive discipline’… Murray Gell-Mann, Questions for the Future [The quantum] postulate implies a renunciation as regards the causal space-time co-ordination of atomic processes. Niels Bohr, Atomic Theory and the Description of Nature It should be emphasized, however, that the probability function does not in itself represent a course of events in the course of time. It represents a tendency for events and our knowledge of events. The probability function can be connected with reality only if one essential condition is fulfilled: if a new measurement is made to determine a certain property of the system. [T]he idea of an objective real world whose smallest parts exist objectively in the same sense as stones or trees exist, independently of whether or not we observe them…is impossible … Werner Heisenberg, Physics and Philosophy [In] quantum theory it is the principle of causality , or more accurately that of determinism , which must be dropped and replaced by something else.… We now have a new form of the law of causality.… It is as follows: if in a certain process the initial conditions are determined as accurately as the uncertainty relations permit, then the probabilities of all possible subsequent states are governed by exact laws. Max Born, The Restless Universe
The development of quantum mechanics in the early twentieth century marked one of the most profound conceptual revolutions in physics. Beginning with Planck's quantization of radiation and Einstein's interpretation of the photoelectric effect, followed by Bohr's atomic model, and later formalized by Heisenberg and Schrödinger, the theory provided a new description of nature—one in which probability amplitudes replaced deterministic trajectories. Within this framework, microscopic systems such as atoms, electrons, and photons are characterized by wavefunctions and operators rather than by points in phase space.