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Journal of Mathematical Chemistry

Laplace transform method in one dimensional quantum mechanics on the semi infinite axis

Won-Sang Chung, Yeounju Kim, Jeongmin Kwon

Published Apr 23, 2022• 1 citation
Publisher
DOI
10.1007/s10910-022-01348-5

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Journal of Mathematical Physics•May 1, 1980•1 citation
Abstract The Laplace transform is a valuable tool in physics, particularly in solving differential equations with initial or boundary conditions. A 2014 study by Tsaur and Wang (2014 Eur. J. Phys. 35 015006) introduced a Laplace-transform-based method to solve the stationary Schrödinger equation for various potentials. However, their approach contains critical methodological flaws: the authors disregard essential boundary conditions and apply the residue theorem incorrectly in the inverse transformation process. These errors ultimately cancel out, leading to correct results despite a flawed derivation. In this paper, we revisit the use of the Laplace transform for the one-dimensional Schrödinger equation, clarifying correct practices in handling boundary conditions and singularities. This analysis offers a sound and consistent framework for the application of Laplace transforms in stationary quantum mechanics, underscoring their educational utility in quantum mechanics coursework.
The continuum calculus, proposed earlier [J. Math. Phys. 17, 1988 (1976)], is here applied to the development of a functional version of Laplace transform and a method for the evaluation of path integrals containing a Gaussian-like measure. Two methods in functional integration are proposed. First, the Gaussian integral for polynomial functionals and consequently functionals that can be expanded in Taylor series are examined. Formula (2.12) is derived. Next, we define the Laplace transform in the function space through the weak distribution formulation of Skorohod. Comparison of both approaches enables us to determine the expression of the functional integeral through a series of Laplace transformations. The second formula is given in Eq. (4.5). The latter formula is applicable to all Laplace transformable functionals. As an illustration of the utility of the formulas derived, we evaluate the integral of a cosine functional by methods 1 and 2, and obtain consistent results. Further applications to quantum mechanics are also presented. We examine the cases of a free particle,the quantum harmonic oscillator, the forced oscillator, and charged particle in a magnetic field. In all cases, we obtain correct results in comparison with known expressions. A numerical procedure is employed in the calculation of infinite products. The usefulness of the p-integral method is stressed.