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arXiv:2411.08915 · European Journal of Physics

Revisiting the Laplace transform in quantum mechanics: correcting a flawed approach for the stationary Schrödinger equation

Luis M Báez, Andrés Santos

Published Jan 29, 2025• 0 citations
arXivHTMLPDF

Abstract

Abstract The Laplace transform is a valuable tool in physics, particularly in solving differential equations with initial or boundary conditions. A 2014 study by Tsaur and Wang (2014 Eur. J. Phys. 35 015006) introduced a Laplace-transform-based method to solve the stationary Schrödinger equation for various potentials. However, their approach contains critical methodological flaws: the authors disregard essential boundary conditions and apply the residue theorem incorrectly in the inverse transformation process. These errors ultimately cancel out, leading to correct results despite a flawed derivation. In this paper, we revisit the use of the Laplace transform for the one-dimensional Schrödinger equation, clarifying correct practices in handling boundary conditions and singularities. This analysis offers a sound and consistent framework for the application of Laplace transforms in stationary quantum mechanics, underscoring their educational utility in quantum mechanics coursework.

DOI
10.1088/1361-6404/adafed

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Laplace transform techniques for solving differential equations do not seem to have been directly applied to the Schrödinger equation in quantum mechanics. This may be because the Laplace transform of a wave function, in contrast to the Fourier transform, has no direct physical significance. However, this paper will show that scattering phase shifts and bound state energies can be determined from the singularities of the Laplace transform of the wave function. The Laplace transform method can thereby simplify calculations if the potential allows a straightforward solution of the transformed Schrödinger equation. Suitable cases are the Coulomb, oscillator and exponential potentials and the Yamaguchi separable non-local potential.
In a recent paper diffused in the literature, the quantum problem of a particle in a infinite square well potential was claimed to be solved via Laplace transform. Surprisingly, the correct solutions were found for an eigenvalue problem with variable defined on a finite range. As a matter of fact, the authors have misused the Laplace transform of the time-independent Schrödinger equation, and they have also used incorrectly the inversion process. In the present paper it is pointed out carefully and clearly those mistakes that might occur with the use of inappropriate methods for a given eigenvalue problem.
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