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AIMS Materials Science

Quantumness of correlations in nanomaterials—experimental evidence and unconventional effects

C. A. Chatzidimitriou‐Dreismann

Published Jan 1, 2022• 0 citations
Publisher

Abstract

Quantum correlations phenomena, such as entanglement, quantum discord and quantum coherence, are ubiquitous effects caused by interactions between physical systems—such as electrons and ions in a piece of metal, or H atoms/molecules adsorbed in nanoporous materials. Here, we address time-asymmetric quantumness of correlations (QoC), with particular emphasis on their energetic consequences for dynamics and non-equilibrium thermodynamics in condensed matter and/or many-body systems. Some known theoretical models—for example, the quantum Zeno effect and GKSL-type Markovian equations-of-motion, all of them being time-asymmetric—are shortly considered, with emphasis on the general character of one of their common and most intriguing result. Namely, that in clear contradistinction to conventional expectations, degradation (or destruction, decoherence, consumption, smearing out, coarse-graining) of quantum correlations can be a source of work (instead of heat production). The experimental relevance of the theoretical considerations is shown with the aid of a recent scattering experiment exploring the impulsively driven (by neutron collisions) translational dynamics of H$ _2 $ molecules in carbon nanotubes and other nanostructured materials—a topic of immediate relevance for material sciences and related technologies.

DOI
10.3934/matersci.2022023

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At low enough temperatures and at microscopic length scales the laws of quantum mechanics become apparent. The underlying superposition principle leads to interference phenomena for one degree of freedom and to the concept of entanglement for two and more. Entangled degrees of freedom are often correlated beyond their classically allowed correlation. These quantum correlations also appear in very large systems and are caused by strong interactions between the constituents. Strongly correlated forms of quantum matter became ubiquitous in condensed matter physics, with the discovery of heavy fermion materials, cuprates and other unconventional superconductors. Here the main players are electrons embedded in solid matter. But they also can be found in interacting quantum gases, where the main players are atoms. In the latter case the required temperatures for quantum correlations to appear are much lower. 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Quantum correlations and associated quantum information concepts (e. g. quantum discord, entanglement, quantum Maxwell’s demon) provide novel insights in various quantum-information processing tasks, quantum-thermodynamics processes, open-system dynamics, quantum molecular dynamics, and general many-body physics. We investigate a new effect of correlations accompanying collision of two quantum systems A and B, the latter being part of a larger (interacting) system B+D. In contrast to the usual case of a classical ‘environment’ or ‘demon’ (which can have only classical correlations with A+B during and after the collision), the quantum case exhibits striking new features. Here, in the frame of incoherent inelastic neutron scattering (INS) and vibrational dynamics of molecules, we report experimental evidence of a new phenomenon: quantum deficit of momentum transfer in an elementary neutron-molecule collision, in particular, in INS from single H2O molecules confined in channels with sub-nanometer diameter. The INS findings are in clear contrast to conventional theoretical expectations, but are naturally (albeit qualitative) interpreted in the frame of modern theory of quantumness of correlations, thus also proposing a new operational meaning of quantum discord and related measures.

Zeitschrift für Naturforschung A•Jun 2, 2014•1 citation
Quantum correlations phenomena, such as entanglement, quantum discord and quantum coherence, are ubiquitous effects caused by interactions between physical systems—such as electrons and ions in a piece of metal, or H atoms/molecules adsorbed in nanoporous materials. Here, we address time-asymmetric quantumness of correlations (QoC), with particular emphasis on their energetic consequences for dynamics and non-equilibrium thermodynamics in condensed matter and/or many-body systems. Some known theoretical models—for example, the quantum Zeno effect and GKSL-type Markovian equations-of-motion, all of them being time-asymmetric—are shortly considered, with emphasis on the general character of one of their common and most intriguing result. Namely, that in clear contradistinction to conventional expectations, degradation (or destruction, decoherence, consumption, smearing out, coarse-graining) of quantum correlations can be a source of work (instead of heat production). The experimental relevance of the theoretical considerations is shown with the aid of a recent scattering experiment exploring the impulsively driven (by neutron collisions) translational dynamics of H2_22​ molecules in carbon nanotubes and other nanostructured materials—a topic of immediate relevance for material sciences and related technologies.
The interactions between physical systems generally lead to the formation of correlations. In this paper we consider the phenomena of entanglement and "quantumness of correlations", such as quantum discord, with particular emphasis on their energetic consequences for the participating systems. We describe a number of theoretical models that are commonly employed in this context, highlighting the general character of one of their most intriguing results: In contradiction to conventional expectations, erasure (decay, consumption) of quantum correlations may be a source of work, i.e. may have "negative energetic costs". We report experimental evidence of this surprising effect obtained within the framework of an elementary scattering experiment, namely ultrafast neutron Compton scattering from normal-state liquid 4 He. The general theory of quantumness of correlations provides a natural way of interpreting the reported results, which stand in blatant contrast to the conventional theory of scattering, where neutron-atom-environment quantum correlations and decoherence play no role. Moreover, they provide a new operational meaning of discord and related measures of quantumness.
Current developments of non-relativistic quantum mechanics appear to predict, and reveal, counter-intuitive dynamical effects of hydrogen in nanostructured materials that are of considerable importance for basic research as well as for technological applications. In this review, the experimental focus is on H2O and H molecules in carbon nanotubes and other nanocavities that have been experimentally investigated using the well-established technique of incoherent inelastic neutron scattering (INS). For instance, the momentum and energy transfers, as obtained from the commonly used standard data analysis techniques, from a (I) H2 molecule in a C-nanotube resulting in a roto-translational motion along the nanotube axis seems to (1) either violate the standard conservation laws or (2) to attribute to the H molecule undergoing translation the effective mass a.m.u. (atomic mass units) instead of the expected 2 a.m.u. A similar striking anomalous effect has been found in the neutron-H scattering from the (II) H2O molecules in nano-channels of some solid materials, in which O-H stretching vibrations along the channel axis are created. The results of this scattering process seem to once again either violate the standard conservation laws or to attribute to the effective mass of the struck H2 molecule as a.m.u. instead of the expected value of 1 a.m.u. We show that these counterintuitive observations from the INS studies have no conventional interpretation within the standard non-relativistic scattering theory. However, they can be qualitatively interpreted "from first principles" within the framework of modern theories of (III) time-symmetric quantum dynamics, as provided by the weak values (WV) and two-state- vector formalism (TSVF), and/or (IV) quantum correlations, especially quantum discord (QD) and quantum thermodynamics (QTD). The theoretical analysis provides an intuitive understanding of the experimental results, gives strong evidence that the nano-structured cavities do represent quantum systems which participate significantly in the dynamics of the neutron-H scattering, and, surprisingly, shows that new physical information can be derived from the experimental data. This latter point may also have far-reaching consequences for technology and material sciences (e.g., fuel cells, H storage materials, etc.). Moreover, novel insights into the short-lived quantum dynamics and/or quantum information theory can be gained.
During the last few decades, considerable advances in quantum information theory have shown deep existing connections between quantum correlation effects (like entanglement and quantum discord) and thermodynamics. Here the concept of conditional entropy plays a considerable role. In contrast to the classical case, quantum conditional entropy can take negative values. This counter-intuitive feature, already well understood in the context of information theory, was recently shown theoretically to also have a physical meaning in quantum thermodynamics [del Rio et al. Nature 2011, 474, 61]. Extending this existing work, here we provide evidence of the significance of negative conditional entropy in a concrete experimental context: Incoherent Neutron Scattering (INS) from protons of H2 in nano-scale environments; e.g., in INS from H2 in C-nanotubes, the data of the H2 translational motion along the nanotube axis seems to show that the neutron apparently scatters from a fictitious particle with mass of 0.64 atomic mass units (a.m.u.)—instead of the value of 2 a.m.u. as conventionally expected. An independent second experiment confirms this finding. However, taking into account the possible negativity of conditional entropy, we explain that this effect has a natural interpretation in terms of quantum thermodynamics. Moreover, it is intrinsically related to the number of qubits capturing the interaction of the two quantum systems H2 and C-nanotube. The considered effect may have technological applications (e.g., in H-storage materials and fuel cells).
Abstract The detection and certification of entanglement and quantum correlations in materials is of fundamental and far‐reaching importance, and has seen significant recent progress. It impacts both the understanding of the basic science of quantum many‐body phenomena as well as the identification of systems suitable for novel technologies. Frameworks suitable to condensed matter that connect measurements to entanglement and coherence have been developed in the context of quantum information theory. These take the form of entanglement witnesses and quantum correlation measures. The underlying theory of these quantities, their relation to condensed matter experimental techniques, and their application to real materials are comprehensively reviewed. In addition, their usage in, e.g., protocols, the relative advantages and disadvantages of witnesses and measures, and future prospects in, e.g., correlated electrons, entanglement dynamics, and entangled spectroscopic probes, are presented. Consideration is given to the interdisciplinary nature of this emerging research and substantial ongoing progress by providing an accessible and practical treatment from fundamentals to application. Particular emphasis is placed on quantities accessible to collective measurements, including by susceptibility and spectroscopic techniques. This includes the magnetic susceptibility witness, one‐tangle, concurrence and two‐tangle, two‐site quantum discord, and quantum coherence measures such as the quantum Fisher information.
At low enough temperatures and at microscopic length scales the laws of quantum mechanics become apparent. The underlying superposition principle leads to interference phenomena for one degree of freedom and to the concept of entanglement for two and more. Entangled degrees of freedom are often correlated beyond their classically allowed correlation. These quantum correlations also appear in very large systems and are caused by strong interactions between the constituents. Strongly correlated forms of quantum matter became ubiquitous in condensed matter physics, with the discovery of heavy fermion materials, cuprates and other unconventional superconductors. Here the main players are electrons embedded in solid matter. But they also can be found in interacting quantum gases, where the main players are atoms. In the latter case the required temperatures for quantum correlations to appear are much lower. But in turn the length scales are larger and they can be embedded in well controlled potentials. A fascinating possibility offered by present day technologies is to tailor matter in order to induce the emergence of new phenomena by controlling quantum correlations. One of the routes leading to spectacular advances is the configuration of nanomaterials like quantum dots or quantum wires on the basis of semiconducting substrates that allow, e.g., to manipulate the Kondo effect or Luttinger liquids affecting transport properties through such nanostructures. Another quite different route with at the moment unlimited potential is offered by quantum optics and atomic physics, when implemented to bring quantum gases into the strongly interacting regime. This can be achieved by optical lattices leading to Mott-insulators, or to two dimensional systems displaying Kosterlitz–Thouless behavior in bosonic gases, or by Feshbach resonances, leading to fermionic systems with unconventional superfluid states like the Fulde–Ferrel–Larkin–Ovchinnikov (FFLO) one. In spite of the very different experimental realizations leading to the two routes mentioned above, they share a common goal, namely achieving a deep understanding of quantum correlations that will ultimately allow to control them and possibly realize new forms of matter. They also share the flexibility that allows to increase the complexity in quantum correlations by joining in a controlled manner well understood building units and/or by regulating their coupling to the environment. It is under the common goal of understanding and controlling quantum correlations that we see the topics presented in this focus issue of New Journal of Physics , where both lines of development, that is on solid-state substrates or with quantum gases, give a timely view of the advances towards the above mentioned common goal. Focus on Quantum Correlations in Tailored Matter Contents Temperature changes when adiabatically ramping up an optical lattice Lode Pollet, Corinna Kollath, Kris Van Houcke and Matthias Troyer Numerical study of two-body correlation in a 1D lattice with perfect blockade B Sun and F Robicheaux Kinetic Monte Carlo modeling of dipole blockade in Rydberg excitation experiment Amodsen Chotia, Matthieu Viteau, Thibault Vogt, Daniel Comparat and Pierre Pillet Motion of Rydberg atoms induced by resonant dipole–dipole interactions C Ates, A Eisfeld and J M Rost Quantum coherence due to Bose–Einstein condensation of parametrically driven magnons S O Demokritov, V E Demidov, O Dzyapko, G A Melkov and A N Slavin Chaotic dynamics in spinor Bose–Einstein condensates J Kronjäger, K Sengstock and K Bongs Damped Bloch oscillations of Bose–Einstein condensates in disordered potential gradients S Drenkelforth, G Kleine Büning, J Will, T Schulte, N Murray, W Ertmer, L Santos and J J Arlt Rabi oscillations between ground and Rydberg states and van der Waals blockade in a mesoscopic frozen Rydberg gas M Reetz-Lamour, J Deiglmayr, T Amthor and M Weidemüller Excitations in two-component Bose gases A Kleine, C Kollath, I P McCulloch, T Giamarchi and U Schollwöck Exploring the growth of correlations in a quasi one-dimensional trapped Bose gas M Eckart, R Walser and W P Schleich How to fix a broken symmetry: quantum dynamics of symmetry restoration in a ferromagnetic Bose–Einstein condensate Bogdan Damski and Wojciech H Zurek Landau levels of cold atoms in non-Abelian gauge fields A Jacob, P Öhberg, G Juzeliunas and L Santos Atomic four-wave mixing via condensate collisions A Perrin, C M Savage, D Boiron, V Krachmalnicoff, C I Westbrook and K V Kheruntsyan Semifluxons in superconductivity and cold atomic gases R Walser, E Goldobin, O Crasser, D Koelle, R Kleiner and W P Schleich Disorder-induced trapping versus Anderson localization in Bose–Einstein condensates expanding in disordered potentials L Sanchez-Palencia, D Clément, P Lugan, P Bouyer and A Aspect Critical tunneling currents in the regime of bilayer excitons L Tiemann, W Dietsche, M Hauser and K von Klitzing Quantum phases of trapped ions in an optical lattice R Schmied, T Roscilde, V Murg, D Porras and J I Cirac Generation and detection of a spin entanglement in nonequilibrium quantum dots Stefan Legel, Jürgen König and Gerd Schön Slow light in inhomogeneous and transverse fields Leon Karpa and Martin Weitz FFLO state in 1-, 2- and 3-dimensional optical lattices combined with a non-uniform background potential T K Koponen, T Paananen, J-P Martikainen, M R Bakhtiari and P Törmä Geometry-dependent interplay of long- and short-range interactions in ultracold fermionic gases: models for condensed matter and astrophysics B Deb, G Kurizki and I E Mazets Fermionic renormalization group methods for transport through inhomogeneous Luttinger liquids V Meden, S Andergassen, T Enss, H Schoeller and K Schönhammer Luttinger hydrodynamics of confined one-dimensional Bose gases with dipolar interactions R Citro, S De Palo, E Orignac, P Pedri and M-L Chiofalo Towards deterministically controlled InGaAs/GaAs lateral quantum dot molecules L Wang, A Rastelli, S Kiravittaya, P Atkinson, F Ding, C C Bof Bufon, C Hermannstädter, M Witzany, G J Beirne, P Michler and O G Schmidt Effective parameters for weakly coupled Bose–Einstein condensates S Giovanazzi, J Esteve and M K Oberthaler Current statistics of correlated charge tunnelling through an impurity in a 1D wire Alexander Herzog and Ulrich Weiss Sideband cooling and coherent dynamics in a microchip multi-segmented ion trap Stephan A Schulz, Ulrich Poschinger, Frank Ziesel and Ferdinand Schmidt-Kaler The trapped two-dimensional Bose gas: from Bose–Einstein condensation to Berezinskii–Kosterlitz–Thouless physics Z Hadzibabic, P Krüger, M Cheneau, S P Rath and J Dalibard Dynamical protection of quantum computation from decoherence in laser-driven cold-ion and cold-atom systems Goren Gordon and Gershon Kurizki Spin-flip and spin-conserving optical transitions of the nitrogen-vacancy centre in diamond Ph Tamarat, N B Manson, J P Harrison, R L McMurtrie, A Nizovtsev, C Santori, R G Beausoleil, P Neumann, T Gaebel, F Jelezko, P Hemmer and J Wrachtrup Superconductivity in the attractive Hubbard model: functional renormalization group analysis R Gersch, C Honerkamp and W Metzner Quantum stability of Mott-insulator states of ultracold atoms in optical resonators Jonas Larson, Sonia Fernández-Vidal, Giovanna Morigi and Maciej Lewenstein
Quantum correlations and associated quantum information concepts (e. g. quantum discord, entanglement, quantum Maxwell’s demon) provide novel insights in various quantum-information processing tasks, quantum-thermodynamics processes, open-system dynamics, quantum molecular dynamics, and general many-body physics. We investigate a new effect of correlations accompanying collision of two quantum systems A and B, the latter being part of a larger (interacting) system B+D. In contrast to the usual case of a classical ‘environment’ or ‘demon’ (which can have only classical correlations with A+B during and after the collision), the quantum case exhibits striking new features. Here, in the frame of incoherent inelastic neutron scattering (INS) and vibrational dynamics of molecules, we report experimental evidence of a new phenomenon: quantum deficit of momentum transfer in an elementary neutron-molecule collision, in particular, in INS from single H2O molecules confined in channels with sub-nanometer diameter. The INS findings are in clear contrast to conventional theoretical expectations, but are naturally (albeit qualitative) interpreted in the frame of modern theory of quantumness of correlations, thus also proposing a new operational meaning of quantum discord and related measures.